Environmental Chemistry Letters, Journal Year: 2022, Volume and Issue: 21(1), P. 183 - 230
Published: Oct. 3, 2022
Language: Английский
Chemical Reviews, Journal Year: 2020, Volume and Issue: 121(3), P. 1232 - 1285
Published: Dec. 14, 2020
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by significant depressions in melting points compared to those the neat constituent components. These materials promising for applications as inexpensive "designer" exhibiting a host tunable physicochemical properties. A detailed review current literature reveals lack predictive understanding microscopic mechanisms that govern structure–property relationships this solvents. Complex hydrogen bonding is postulated root cause their point and properties; understand these bonded networks, it imperative study systems dynamic entities using both simulations experiments. This emphasizes recent research efforts order elucidate next steps needed develop fundamental framework deeper DESs. It covers developments DES research, frames outstanding scientific questions, identifies thrusts aligned with advancement field toward models
Language: Английский
Citations
2192
Biotechnology Advances, Journal Year: 2018, Volume and Issue: 36(8), P. 2032 - 2050
Published: Sept. 5, 2018
Language: Английский
Citations
440
Green Energy & Environment, Journal Year: 2019, Volume and Issue: 4(2), P. 95 - 115
Published: Feb. 5, 2019
Biomass is renewable, abundant, cheap, biocompatible, and biodegradable materials has been used to produce chemicals, materials, energy, fuels. However, most of the biomass, especially biomass polymers are not soluble in common solvents, which hinders their pretreatment conversion. Deep eutectic solvents (DESs) environmental-friendly, highly tunable, with high solubility, renders them potential applications They could be as or catalysts so on. This paper intends review application DESs for conversion value-added products. We focus on following topics related DESs: (1) biomass; (2) dissolution separation extraction chemicals from (3) conversion; (4) Drawbacks, recyclability biomass.
Language: Английский
Citations
377
Carbohydrate Polymers, Journal Year: 2018, Volume and Issue: 200, P. 361 - 380
Published: July 29, 2018
Language: Английский
Citations
341
Bioresource Technology, Journal Year: 2021, Volume and Issue: 339, P. 125587 - 125587
Published: July 18, 2021
Language: Английский
Citations
286
Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(15), P. 8596 - 8638
Published: Jan. 1, 2021
Various eutectic systems have been proposed and studied over the past few decades. Most of studies focused on three typical types eutectics: metals, salts, deep solvents. On one hand, they are all systems, their principle is same. other representative inorganic organic substances, respectively. They applications in almost fields related to chemistry. Their different but overlapping stem from very properties. In addition, proposal new has greatly boosted development cross-field research involving chemistry, materials, engineering, energy. The goal this review provide a comprehensive overview these eutectics describe task-specific strategies address growing demands.
Language: Английский
Citations
269
Beilstein Journal of Nanotechnology, Journal Year: 2018, Volume and Issue: 9, P. 2479 - 2498
Published: Sept. 19, 2018
Among many other sustainable functional nanomaterials, nanocellulose is drawing increasing interest for use in environmental remediation technologies due to its numerous unique properties and functionalities. Nanocellulose usually derived from the disintegration of naturally occurring polymers or produced by action bacteria. In this review, some invigorating perspectives on challenges, future direction, updates most relevant uses are discussed. The reported applications as an adsorbent, photocatalyst, flocculant, membrane reviewed particular. However, additional effort will be required implement commercialize a viable nanomaterial technologies. regard, main challenges limitations working with nanocellulose-based materials identified improve development efficient remediation.
Language: Английский
Citations
252
Green Chemistry, Journal Year: 2020, Volume and Issue: 22(21), P. 7219 - 7232
Published: Jan. 1, 2020
The effect of the structure and properties DESs on lignin extraction chemical transformations.
Language: Английский
Citations
228
Green Chemistry, Journal Year: 2019, Volume and Issue: 21(11), P. 3099 - 3108
Published: Jan. 1, 2019
In the present study, two kinds of deep eutectic solvents (DESs) were facilely prepared and adopted to drastically disturb recalcitrance corncobs for further boosting sugar yields obtaining valorized lignin by-products while reducing treatment times.
Language: Английский
Citations
213
Current Research in Green and Sustainable Chemistry, Journal Year: 2020, Volume and Issue: 3, P. 100035 - 100035
Published: June 1, 2020
The successful conversion of lignocellulose into value-added products depends on overcoming the recalcitrance its structure towards enzymatic digestion. highly crosslinked lignin, crystallinity cellulose, and low digestibility hemicellulose create recalcitrance. Many studies have proved that an appropriate pretreatment method could enhance lignocellulosic biomass by weakening strong network chemical bonds among hemicellulose, lignin. There are several conventional ways to separate components from each other, but requirements high temperature pressure, use acids bases, expensive instrumentation make methods difficult use. Greener solvents, e.g. supercritical fluid, ionic liquid, deep eutectic solvent (DES)-based techniques can overcome difficulties. Although a lot pilot scale rigorous required launch greener technologies commercially, they already shown promise in field pretreatments. Among DESs cheaper, easily recyclable, environmentally benign, efficiency DES-based be enhanced manifold applying microwave ultrasound. Therefore, one most popular future.
Language: Английский
Citations
208