Green Chemistry,
Journal Year:
2022,
Volume and Issue:
25(1), P. 59 - 105
Published: Nov. 29, 2022
Comparing
properties
of
ionic
liquids,
(deep)
eutectic
solvents
and
traditional
organic
solvents,
as
well
their
applicability
in
lignocellulosic
biomass
processing.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2021,
Volume and Issue:
9(5), P. 2152 - 2160
Published: Jan. 15, 2021
Hydrophobic
deep
eutectic
solvents
(DESs)
have
attracted
much
attention
as
sustainable
extraction
media
for
various
metals.
However,
in
previously
developed
DESs,
only
one
DES
component
is
involved
metal
complex
formation,
which
has
limited
their
performance
and
selectivity.
Here,
we
propose
a
novel
synergistic
concept
improving
the
of
environmentally
benign
liquid–liquid
lithium
(Li).
Two
different
conventional
extractants,
beta-diketone
neutral
extractant,
were
effective
creating
DESs.
When
two
extractants
mixed,
they
formed
liquid
DES.
DESs
lower
viscosity
than
hydrophobic
ionic
liquids.
The
Conductor-like
Screening
Model
Real
Solvents
method
was
used
to
estimate
formation
with
melting
point
depressed
by
intermolecular
interaction
between
components.
Li
greatly
enhanced
capacity
reached
4.4
g/L
using
optimum
combination
because
it
solvent-free
highly
concentrated.
Using
DES,
selective
recovery
over
Na
K
demonstrated
model
brine
solution.
This
first
report
efficient
DES-based
extraction.
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
34(20)
Published: Dec. 14, 2021
Abstract
Rechargeable
aqueous
zinc
batteries
(AZBs)
are
one
of
the
promising
options
for
large‐scale
electrical
energy
storage
owing
to
their
safety,
affordability
and
environmental
friendliness.
During
past
decade,
there
have
been
remarkable
advancements
in
AZBs
technology,
which
achieved
through
intensive
efforts
not
only
area
electrode
materials
but
also
fundamental
understandings
non‐electrode
components
such
as
electrolytes,
solid
electrolyte
interphase
(SEI),
current
collectors,
binders,
separators.
In
particular,
breakthroughs
should
be
underestimated
having
enabled
attain
a
higher
power
density
beyond
that
conventional
AZBs,
proving
critical
role.
this
article,
recent
research
progress
is
comprehensively
reviewed
with
respect
covering
new‐type
electrolytes
introduced,
attempts
tailoring
SEI,
design
multi‐functional
binders
separators,
along
remaining
challenges
associated
these
components.
Finally,
perspectives
discussed
toward
future
directions
field.
This
extensive
overview
on
expected
guide
spur
further
development
high‐performance
AZBs.
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
25(1), P. 59 - 105
Published: Nov. 29, 2022
Comparing
properties
of
ionic
liquids,
(deep)
eutectic
solvents
and
traditional
organic
solvents,
as
well
their
applicability
in
lignocellulosic
biomass
processing.