History repeats itself again: Will the mistakes of the past for ILs be repeated for DESs? From being considered ionic liquids to becoming their alternative: the unbalanced turn of deep eutectic solvents DOI
João Afonso, Andrea Mezzetta, Isabel M. Marrucho

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 25(1), P. 59 - 105

Published: Nov. 29, 2022

Comparing properties of ionic liquids, (deep) eutectic solvents and traditional organic solvents, as well their applicability in lignocellulosic biomass processing.

Language: Английский

Choline chloride-based deep eutectic solvents as potential solvent for extraction of phenolic compounds from olive leaves: Extraction optimization and solvent characterization DOI Creative Commons
Paula Virginia de Almeida Pontes,

Isabella Ayumi Shiwaku,

Guilherme J. Máximo

et al.

Food Chemistry, Journal Year: 2021, Volume and Issue: 352, P. 129346 - 129346

Published: Feb. 21, 2021

Language: Английский

Citations

139

Deep eutectic solvents and their application in electrochemistry DOI
Andrew P. Abbott

Current Opinion in Green and Sustainable Chemistry, Journal Year: 2022, Volume and Issue: 36, P. 100649 - 100649

Published: June 23, 2022

Language: Английский

Citations

134

Synergistic Deep Eutectic Solvents for Lithium Extraction DOI
Takafumi Hanada, Masahiro Goto

ACS Sustainable Chemistry & Engineering, Journal Year: 2021, Volume and Issue: 9(5), P. 2152 - 2160

Published: Jan. 15, 2021

Hydrophobic deep eutectic solvents (DESs) have attracted much attention as sustainable extraction media for various metals. However, in previously developed DESs, only one DES component is involved metal complex formation, which has limited their performance and selectivity. Here, we propose a novel synergistic concept improving the of environmentally benign liquid–liquid lithium (Li). Two different conventional extractants, beta-diketone neutral extractant, were effective creating DESs. When two extractants mixed, they formed liquid DES. DESs lower viscosity than hydrophobic ionic liquids. The Conductor-like Screening Model Real Solvents method was used to estimate formation with melting point depressed by intermolecular interaction between components. Li greatly enhanced capacity reached 4.4 g/L using optimum combination because it solvent-free highly concentrated. Using DES, selective recovery over Na K demonstrated model brine solution. This first report efficient DES-based extraction.

Language: Английский

Citations

117

Non‐Electrode Components for Rechargeable Aqueous Zinc Batteries: Electrolytes, Solid‐Electrolyte‐Interphase, Current Collectors, Binders, and Separators DOI
Qiao Ni, Byung‐Hoon Kim, Chuan Wu

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(20)

Published: Dec. 14, 2021

Abstract Rechargeable aqueous zinc batteries (AZBs) are one of the promising options for large‐scale electrical energy storage owing to their safety, affordability and environmental friendliness. During past decade, there have been remarkable advancements in AZBs technology, which achieved through intensive efforts not only area electrode materials but also fundamental understandings non‐electrode components such as electrolytes, solid electrolyte interphase (SEI), current collectors, binders, separators. In particular, breakthroughs should be underestimated having enabled attain a higher power density beyond that conventional AZBs, proving critical role. this article, recent research progress is comprehensively reviewed with respect covering new‐type electrolytes introduced, attempts tailoring SEI, design multi‐functional binders separators, along remaining challenges associated these components. Finally, perspectives discussed toward future directions field. This extensive overview on expected guide spur further development high‐performance AZBs.

Language: Английский

Citations

107

History repeats itself again: Will the mistakes of the past for ILs be repeated for DESs? From being considered ionic liquids to becoming their alternative: the unbalanced turn of deep eutectic solvents DOI
João Afonso, Andrea Mezzetta, Isabel M. Marrucho

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 25(1), P. 59 - 105

Published: Nov. 29, 2022

Comparing properties of ionic liquids, (deep) eutectic solvents and traditional organic solvents, as well their applicability in lignocellulosic biomass processing.

Language: Английский

Citations

105