Recovery of lithium from the desorption solutions of salt lakes using β-diketone synergistic extraction system DOI
Shuang Sun,

Yuefeng Deng,

Ji Chen

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128748 - 128748

Published: July 9, 2024

Language: Английский

Recycling of Lithium‐Ion Batteries—Current State of the Art, Circular Economy, and Next Generation Recycling DOI Creative Commons

Jonas Neumann,

Martina Petraniková,

Marcel Meeus

et al.

Advanced Energy Materials, Journal Year: 2022, Volume and Issue: 12(17)

Published: Jan. 10, 2022

Abstract Being successfully introduced into the market only 30 years ago, lithium‐ion batteries have become state‐of‐the‐art power sources for portable electronic devices and most promising candidate energy storage in stationary or electric vehicle applications. This widespread use a multitude of industrial private applications leads to need recycling reutilization their constituent components. Improving “recycling technology” lithium ion is continuous effort far from maturity today. The complexity with varying active inactive material chemistries interferes desire establish one robust procedure all kinds batteries. Therefore, current state art needs be analyzed, improved, adapted coming cell paper provides an overview regulations new battery directive demands. It covers practices collection, sorting, transportation, handling, recycling. Future generations will further increase diversity chemistry this presents predictions related challenges future regard materials chemical composition, discusses approaches

Language: Английский

Citations

511
Type V deep eutectic solvents: Design and applications DOI Creative Commons
Dinis O. Abranches, João A. P. Coutinho

Current Opinion in Green and Sustainable Chemistry, Journal Year: 2022, Volume and Issue: 35, P. 100612 - 100612

Published: March 18, 2022

Type V deep eutectic solvents are a novel class of sustainable solvents. They prepared by physically mixing solid, non-ionic components and characterized strong negative deviations from thermodynamic ideality. This work provides guidelines for the rational design these reviews some their recent applications. Emphasis is given on choice hydrogen bond donors acceptors to achieve necessary liquid phase non-ideality, namely use pairs molecules with high polarity asymmetry, stresses importance assessing solid–liquid diagrams. Polymorphism cocrystal formation also briefly addressed, together predictive methodologies that have been developed estimate properties.

Language: Английский

Citations

180
Status and advances of deep eutectic solvents for metal separation and recovery DOI Creative Commons
Ziwen Yuan, Huan Liu, Wai Fen Yong

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(5), P. 1895 - 1929

Published: Jan. 1, 2022

Deep eutectic solvents show interesting prospects as more sustainable alternatives for metal separation and recovery.

Language: Английский

Citations

175
Deep eutectic solvents-based adsorbents in environmental analysis DOI

Muhammad Saqaf Jagirani,

Mustafa Soylak

TrAC Trends in Analytical Chemistry, Journal Year: 2022, Volume and Issue: 157, P. 116762 - 116762

Published: Aug. 28, 2022

Language: Английский

Citations

92
Direct lithium extraction: A new paradigm for lithium production and resource utilization DOI
Javad Farahbakhsh,

Faezeh Arshadi,

Zahra Mofidi

et al.

Desalination, Journal Year: 2023, Volume and Issue: 575, P. 117249 - 117249

Published: Dec. 27, 2023

Language: Английский

Citations

81
The recovery and separation of lithium by using solvent extraction methods DOI
Thines Kanagasundaram, Olivia Murphy,

Maha N. Haji

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 509, P. 215727 - 215727

Published: March 23, 2024

Language: Английский

Citations

59
Sustainable Lithium Recovery from Hypersaline Salt-Lakes by Selective Electrodialysis: Transport and Thermodynamics DOI
Zi Hao Foo, John B. Thomas,

Samuel M. Heath

et al.

Environmental Science & Technology, Journal Year: 2023, Volume and Issue: 57(39), P. 14747 - 14759

Published: Sept. 18, 2023

Evaporative technology for lithium mining from salt-lakes exacerbates freshwater scarcity and wetland destruction, suffers protracted production cycles. Electrodialysis (ED) offers an environmentally benign alternative continuous extraction is amenable to renewable energy usage. Salt-lake brines, however, are hypersaline multicomponent mixtures, the impact of complex brine-membrane interactions remains poorly understood. Here, we quantify influence solution composition, salinity, acidity on counterion selectivity thermodynamic efficiency electrodialysis, leveraging 1250 original measurements with salt-lake brines that span four feed salinities, three pH levels, five current densities. Our experiments reveal commonly used binary cation solutions, which neglect Na+ K+ transport, may overestimate Li+/Mg2+ by 250% underpredict specific consumption (SEC) a factor 54.8. As result conditions, exposure brine weakens efficacy Donnan exclusion, amplifying Mg2+ leakage. Higher densities enhance potential across solution-membrane interface ameliorate degradation brines. However, steep trade-off between governs ED's performance: 6.25 times enhancement in accompanied 71.6% increase SEC. Lastly, our analysis suggests industrial-scale ED module can meet existing capacities, while being powered photovoltaic farm utilizes <1% salt-flat area.

Language: Английский

Citations

49
A review of the nanofiltration membrane for magnesium and lithium separation from salt-lake brine DOI
Lei Zhang, Mengyang Hu, Benqiao He

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 129169 - 129169

Published: Aug. 14, 2024

Language: Английский

Citations

35
Challenges and opportunities of recovering lithium from seawater, produced water, geothermal brines, and salt lakes using conventional and emerging technologies DOI Creative Commons
Hasan Nikkhah,

Deniz İpekçi,

Wenjun Xiang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155349 - 155349

Published: Aug. 30, 2024

Energy storage plays a crucial role in the modern energy landscape, with its applications spanning from renewable integration to electrification of transportation and microgrids. Lithium is key component lithium-ion batteries at core technologies. Increasing demand for lithium has challenged supply chains required rethinking how we source it. This comprehensive review presents critical holistic assessment opportunities challenges sourcing diverse feedstocks, such as seawater, geothermal, produced water (oilfield), salt lake brines. We assess various extraction technologies (precipitation, extraction, electrochemical techniques, membrane processes) considering these three feedstocks. A quantitative comparative analysis conducted across all technologies, factors cost, commercial maturity, operation duration, other relevant parameters determine most promising each feedstock while identifying remaining research technological gaps. Our reveals that Direct Extraction (DLE) characterized by higher selectivity lower environmental impact, demonstrate significant promise enhancing yields geothermal In contrast, processes are identified more suited seawater brines, offering cost-effective scalability despite fouling. Ultimately, efficient illustrated harvesting unconventional resource. The shows adsorption chemical precipitation recovery lake, oilfield brine.

Language: Английский

Citations

17
(Deep) eutectic solvents for the separation of platinum group metals and rare earth elements: characteristics, extraction mechanisms and state of the art DOI Creative Commons

Sahar Gholami,

María Pérez-Page, Carmine D’Agostino

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159497 - 159497

Published: Jan. 1, 2025

Language: Английский

Citations

4