Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement DOI
Xiaoqin Ma,

Xin-Jun Zhao,

QinglianT. Zhang

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

The structure of hydroxyborates is optimized by adjusting the number hydroxyl groups and oxygen atoms to enhance their properties.

Language: Английский

Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal DOI
Yang Ning,

Huijian Zhao,

Wenli Zhao

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110825 - 110825

Published: Jan. 1, 2025

Language: Английский

Citations

1
Birefringence Modulation by Phenyl and Acyl Groups in Urea-Based Crystals DOI

Dongling Yang,

Hongyuan Sha, Qinghe Li

et al.

Crystal Growth & Design, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 21, 2025

Language: Английский

Citations

0
The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation DOI

Jialong Wang,

Enshen Wang,

X.Y. Cui

et al.

Chemical Physics Letters, Journal Year: 2025, Volume and Issue: unknown, P. 141987 - 141987

Published: Feb. 1, 2025

Language: Английский

Citations

0
K3[HCO3]2F: a new deep-UV birefringent crystal exhibiting strong optical anisotropy DOI
Wenbin Zhang,

Yabo Wu,

Zhihua Yang

et al.

Science China Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Language: Английский

Citations

0
Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge DOI
Xiaotian Ma, Shaohua Liu,

Xifa Long

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142300 - 142300

Published: April 1, 2025

Language: Английский

Citations

0
Recent progress in structural design strategies of high-birefringence optical crystals DOI
Alan Xu,

Mao‐Yin Ran,

Xintao Wu

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 540, P. 216775 - 216775

Published: May 8, 2025

Language: Английский

Citations

0
Insights into the Defect Structure of NaBa12(BO3)7F4 (NBBF) Crystals Using Raman Spectroscopy: Numerical and Experimental Study DOI
Tatyana B. Bekker, Nursultan E. Sagatov, S. V. Goryaĭnov

et al.

Crystal Growth & Design, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Language: Английский

Citations

0
CsLa(SO4)2: A Lanthanum Sulfate Crystal for Nonlinear Optical Applications DOI
Lehui Liu, Feifei Yuan,

Yisheng Huang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 23, 2025

Nonlinear optical materials with ultraviolet transparency are vital for technologies. A sulfate crystal, CsLa(SO4)2, was synthesized via hydrothermal methods, adopting a noncentrosymmetric structure (Pmn21) asymmetric La[SO4]7 coordination. The material exhibits second-harmonic generation efficiency of 0.6 times KH2PO4 (KDP), birefringence 0.026 at 546 nm, and UV cutoff below 200 nm. Its wide bandgap (5.27 eV) aligns requirements UV/deep-UV applications. Theoretical analysis suggests that La-O S-O bonding interactions enhance performance, providing insights optimizing sulfate-based materials.

Language: Английский

Citations

0
(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy DOI

Yi‐Lei Lv,

Liang Ma, Wenlong Liu

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(32), P. 14821 - 14826

Published: July 31, 2024

Effective design and synthesis of second-order nonlinear optical (NLO) materials hold immense significance in driving modern science technology advancements. In this study, we synthesized a new acentric mercury nitrate, (C5H12N2S)Hg(NO3)2, by regulating the coordination Hg atom through introduction heteroatom. It exhibits an unprecedented [(C5H12N2S)2Hg2(NO3)4]∞ chain composed Hg2+, NO3–, organic molecule C5H12N2S. Notably, (C5H12N2S)Hg(NO3)2 demonstrates HgO3S unit second harmonic generation (SHG) intensity 1.3 × KDP at 1064 nm, presenting nitrate constructed molecule. Theoretical calculations suggest that C5H12N2S significantly contribute to SHG effect. This study incorporation heteroatoms is effective strategy for development NLO materials.

Language: Английский

Citations

3
Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units DOI

Jinbin Fan,

Ziting Yan,

Zilong Chen

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 19, 2024

Language: Английский

Citations

3