Pesticide abatement using environmentally friendly nano zero valent particles as photo-Fenton catalyst DOI Creative Commons
Aida M. Díez, Manuela M. Moreira, Marta Pazos

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 336, P. 126179 - 126179

Published: Jan. 5, 2024

Nano-zero valent iron particles (NZVI) have been used for the pesticide pirimicarb degradation under simulated solar radiation. These synthesized by extracts from agro-industrial residues, namely vineyard and blueberry pruning, black tea algae, so they can be labelled as "green-NZVI". The physico-chemical properties of these green-NZVI were compared to those NZVI with NaBH4. usage residues reducing agent not only provided better performant but also evade harmful reagents. Indeed, this process is within circular economy, environmentally friendly, defeats performance widely reported photo-Fenton Fe2+ catalyst. 96.5 % was achieved radiation 15 min 0.08 mM H2O2 0.16 extract. Further, developed optimized in terms reagents concentration natural antioxidant extract synthesis, which demonstrated a strong effect on due differences phenolic compounds present them. pathway analysed, confirming successful degradation. In concentration, it reduced its sequential addition time. Under optimal conditions, even real effluents successfully degraded.

Language: Английский

A review on selective dye adsorption by different mechanisms DOI
Yawei Shi, Qian Chang, Tongwen Zhang

et al.

Journal of environmental chemical engineering, Journal Year: 2022, Volume and Issue: 10(6), P. 108639 - 108639

Published: Sept. 27, 2022

Language: Английский

Citations

181

Methods to prepare biosorbents and magnetic sorbents for water treatment: a review DOI Creative Commons
Ahmed I. Osman, Eman M. Abd El-Monaem, Ahmed M. Elgarahy

et al.

Environmental Chemistry Letters, Journal Year: 2023, Volume and Issue: 21(4), P. 2337 - 2398

Published: May 4, 2023

Access to drinkable water is becoming more and challenging due worldwide pollution the cost of treatments. Water wastewater treatment by adsorption on solid materials usually cheap effective in removing contaminants, yet classical adsorbents are not sustainable because they derived from fossil fuels, can induce secondary pollution. Therefore, biological sorbents made modern biomass increasingly studied as promising alternatives. Indeed, such biosorbents utilize waste that would otherwise pollute systems, promote circular economy. Here we review biosorbents, magnetic sorbents, other cost-effective with emphasis preparation methods, types, mechanisms, regeneration spent adsorbents. Biosorbents prepared a wide range materials, including wood, bacteria, algae, herbaceous agricultural waste, animal waste. Commonly removed contaminants comprise dyes, heavy metals, radionuclides, pharmaceuticals, personal care products. Preparation methods include coprecipitation, thermal decomposition, microwave irradiation, chemical reduction, micro-emulsion, arc discharge. Adsorbents be classified into activated carbon, biochar, lignocellulosic clays, zeolites, peat, humic soils. We detail isotherms kinetics. Regeneration supercritical fluid desorption. also discuss exhausted adsorbent management disposal. found agro-waste remove up 68–100% while wooden, herbaceous, bacterial, marine-based 55–99% metals. Animal waste-based 1–99% The average removal efficiency modified around 90–95%, but some treatments, cross-linked beads, may negatively affect their efficiency.

Language: Английский

Citations

165

Green synthesis of bimetallic Ag/ZnO@Biohar nanocomposite for photocatalytic degradation of tetracycline, antibacterial and antioxidant activities DOI Creative Commons
Mohamed Hosny, Manal Fawzy, Abdelazeem S. Eltaweil

et al.

Scientific Reports, Journal Year: 2022, Volume and Issue: 12(1)

Published: May 5, 2022

In this work, a simple and green synthesis procedure for phytofabrication Zinc oxide-silver supported biochar nanocomposite (Ag/ZnO@BC) via Persicaria salicifolia biomass is investigated the first time to uphold numerous chemistry such as less hazardous chemical syntheses. XRD technique showed crystal structure of phytosynthesized Ag/ZnO@BC, whereas UV-visible spectroscopy, FT-IR, SEM, EDX, TEM, XPS analyses indicated successful biosynthesis nanocomposite. Testing photocatalytic potential novel in removal TC under different conditions unraveled its powerful photodegradation efficiency that reached 70.3% optimum reaction conditions: concentration; 50 ppm, pH; 6, dose Ag/ZnO@BC; 0.01 g, temperature; 25 °C, H2O2 100 mM. The reusability Ag/ZnO@BC was evident it 53% after six cycles regeneration. also shown be potent antimicrobial agent against Klebsiella pneumonia well promising antioxidant material. Therefore, current work presented could efficiently employed various environmental medical applications.

Language: Английский

Citations

130

Floatable cellulose acetate beads embedded with flower-like zwitterionic binary MOF/PDA for efficient removal of tetracycline DOI
Eman M. Abd El-Monaem, Ahmed M. Omer,

Randa E. Khalifa

et al.

Journal of Colloid and Interface Science, Journal Year: 2022, Volume and Issue: 620, P. 333 - 345

Published: April 7, 2022

Language: Английский

Citations

125

Facile one-pot green synthesis of magnetic separation photocatalyst-adsorbent and its application DOI
Song Cheng,

Saidan Zhao,

Baolin Xing

et al.

Journal of Water Process Engineering, Journal Year: 2022, Volume and Issue: 47, P. 102802 - 102802

Published: May 4, 2022

Language: Английский

Citations

81

Graphene oxide incorporated cellulose acetate beads for efficient removal of methylene blue dye; isotherms, kinetic, mechanism and co-existing ions studies DOI Creative Commons
Abdelazeem S. Eltaweil, Eman M. Abd El-Monaem, Gehan M. El‐Subruiti

et al.

Journal of Porous Materials, Journal Year: 2022, Volume and Issue: 30(2), P. 607 - 618

Published: Oct. 27, 2022

Abstract In this investigation, new porous adsorbent beads were formulated via the incorporation of graphene oxide (GO) into cellulose acetate (CA) for adsorptive removal methylene blue (MB) dye. The experimental results signified that adsorption MB dye increased with increase in GO ratio from 10 to 25%. addition, process obeyed PSO kinetic model and Langmuir isotherm a maximum capacity reaching 369.85 mg/g. More importantly, it was proposed mechanism onto GO@CA proceeded electrostatic interactions, H-bonding, van der Waals forces, n-π π -π interactions. Besides, fabricated exhibited an excellent ability recycle reuse after five successive cycles. there high selectivity towards molecules presence co-existing cations such as Fe 2+ , Zn Cu Ni .

Language: Английский

Citations

80

Phytofabrication of bimetallic silver-copper/biochar nanocomposite for environmental and medical applications DOI
Mohamed Hosny, Manal Fawzy, Abdelazeem S. Eltaweil

et al.

Journal of Environmental Management, Journal Year: 2022, Volume and Issue: 316, P. 115238 - 115238

Published: May 13, 2022

Language: Английский

Citations

76

Recent developments in alginate-based adsorbents for removing phosphate ions from wastewater: a review DOI Creative Commons
Abdelazeem S. Eltaweil, Eman M. Abd El-Monaem,

Hala M. Elshishini

et al.

RSC Advances, Journal Year: 2022, Volume and Issue: 12(13), P. 8228 - 8248

Published: Jan. 1, 2022

The huge development of the industrial sector has resulted in release large quantities phosphate anions which adversely affect environment, human health, and aquatic ecosystems.

Language: Английский

Citations

72

Preparation of pyrolysis products by catalytic pyrolysis of poplar: Application of biochar in antibiotic wastewater treatment DOI

Xiaojing Qin,

Song Cheng, Baolin Xing

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 338, P. 139519 - 139519

Published: July 15, 2023

Language: Английский

Citations

61

Construction of efficient Ni-FeLDH@MWCNT@Cellulose acetate floatable microbeads for Cr(VI) removal: Performance and mechanism DOI
Ahmed M. Omer,

Gehad S. Elgarhy,

Gehan M. El‐Subruiti

et al.

Carbohydrate Polymers, Journal Year: 2023, Volume and Issue: 311, P. 120771 - 120771

Published: March 2, 2023

Language: Английский

Citations

50