Synthesis of Mo 2C MXene with high electrochemical performance by alkali hydrothermal etching DOI Creative Commons

Yitong Guo,

Xin Zhang, Sen Jin

et al.

Journal of Advanced Ceramics, Journal Year: 2023, Volume and Issue: 12(10), P. 1889 - 1901

Published: Aug. 3, 2023

Two-dimensional MXenes are generally prepared by the etching of acid solutions. The as-synthesized terminated group anions (F, Cl, et al.), which affect electrochemical performance MXenes. Here, we report a novel method to prepare Mo2C MXene from Mo2Ga2C hydrothermal alkali Highly pure was successfully synthesized NaOH, while etchings LiOH and KOH were failed. concentration temperature time strongly purity as-prepared MXene. Pure could be 20 M NaOH at 180 °C for 24 h. After intercalation hexadecyl trimethyl ammonium bromide 90 96 h, few-layer obtained. made after exhibited excellent as anode lithium-ion battery, compared with general HF reported in literature. final discharge specific capacity 266.73 mAh·g-1 0.8 A·g-1, is 52% higher than that (175.77 mAh·g-1). This because has lager surface area, lower resistance, O/OH termination without anion termination. first make samples this significantly better etching.

Language: Английский

MXenes for Energy Harvesting DOI
Yizhou Wang,

Tianchao Guo,

Zhengnan Tian

et al.

Advanced Materials, Journal Year: 2022, Volume and Issue: 34(21)

Published: Jan. 20, 2022

Abstract Energy harvesting modules play an increasingly important role in the development of autonomous self‐powered microelectronic devices. MXenes (i.e., 2D transition metal carbide/nitride) have recently emerged as promising candidates for energy applications due to their excellent electronic conductivity, large specific surface area, and tunable properties. Herein, a perspective on using harvest from various sources environment is presented. First, characteristics that facilitate capturing are systematically introduced preparation strategies derived nanostructures tailored toward such summarized. Subsequently, mechanism different (e.g., solar energy, thermoelectric triboelectric piezoelectric salinity‐gradient electrokinetic ultrasound humidity energy) discussed. Then, recent progress MXene‐based harvesting, well applications, introduced. Finally, opinions existing challenges future directions nanostructure

Language: Английский

Citations

242

Porous and Ultra-Flexible Crosslinked MXene/Polyimide Composites for Multifunctional Electromagnetic Interference Shielding DOI Creative Commons
Zhihui Zeng, Na Wu, Jingjiang Wei

et al.

Nano-Micro Letters, Journal Year: 2022, Volume and Issue: 14(1)

Published: Feb. 9, 2022

Abstract Lightweight, ultra-flexible, and robust crosslinked transition metal carbide (Ti 3 C 2 MXene) coated polyimide (PI) (C-MXene@PI) porous composites are manufactured via a scalable dip-coating followed by chemical crosslinking approach. In addition to the hydrophobicity, anti-oxidation extreme-temperature stability, efficient utilization of intrinsic conductivity MXene, interfacial polarization between MXene PI, micrometer-sized pores composite foams achieved. Consequently, show satisfactory X-band electromagnetic interference (EMI) shielding effectiveness 22.5 62.5 dB at density 28.7 48.7 mg cm −3 , leading an excellent surface-specific SE 21,317 g −1 . Moreover, exhibit electrothermal performance as flexible heaters in terms prominent, rapid reproducible, stable effect low voltages superior heat more uniform distribution compared with commercial composed alloy plates. Furthermore, well attached on human body check their electromechanical sensing performance, demonstrating sensitive reliable detection motions wearable sensors. The EMI multifunctionalities, along facile easy-to-scalable manufacturing techniques, imply promising perspectives C-MXene@PI next-generation electronics, aerospace, smart devices.

Language: Английский

Citations

209

Tailoring electromagnetic responses of delaminated Mo2TiC2T MXene through the decoration of Ni particles of different morphologies DOI
Feiyue Hu, Xiaohan Wang,

Shen Bao

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 440, P. 135855 - 135855

Published: March 16, 2022

Language: Английский

Citations

141

Recent status and future perspectives of 2D MXene for micro-supercapacitors and micro-batteries DOI
Yuanyuan Zhu, Sen Wang,

Jiaxin Ma

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 51, P. 500 - 526

Published: July 4, 2022

Language: Английский

Citations

107

MXene supported by cotton fabric as electrode layer of triboelectric nanogenerators for flexible sensors DOI
Jiacheng Fan,

Mengmeng Yuan,

Libo Wang

et al.

Nano Energy, Journal Year: 2022, Volume and Issue: 105, P. 107973 - 107973

Published: Nov. 2, 2022

Language: Английский

Citations

105

Construction and performance of CdS/MoO2@Mo2C-MXene photocatalyst for H2 production DOI Creative Commons
Sen Jin, Huijuan Jing, Libo Wang

et al.

Journal of Advanced Ceramics, Journal Year: 2022, Volume and Issue: 11(9), P. 1431 - 1444

Published: Aug. 4, 2022

Abstract Nowadays, photocatalytic technologies are regarded as promising strategies to solve energy problems, and various photocatalysts have been synthesized explored. In this paper, a novel CdS/MoO 2 @Mo C-MXene photocatalyst for H production was constructed by two-step hydrothermal method, where MoO acted binary co-catalyst. the first step, crystals with an egged shape grew on surface of two-dimensional (2D) Mo C MXene via oxidation process in HCl aqueous solution. second CdS nanorods were uniformly assembled ethylenediamine inorganic cadmium source organic sulfur source. The composite 5 wt% exhibits ultrahigh visible-light activity 22,672 µmol/(g·h), which is ∼21% higher than that CdS/Mo C-MXene. composite, metallic nature separates MXene, acts electron-transport bridge between accelerate photoinduced electron transferring. Moreover, band structure changed suppress recombination photogenerated carriers. This compound delivers upgraded evolution performance new pathway preparing low-cost problems future.

Language: Английский

Citations

91

MXenes with applications in supercapacitors and secondary batteries: A comprehensive review DOI Creative Commons
Xueqin Xu, Yang Li, Weitao Zheng

et al.

Materials Reports Energy, Journal Year: 2022, Volume and Issue: 2(1), P. 100080 - 100080

Published: Feb. 1, 2022

Two-dimensional (2D) materials have received tremendous attention because they possess a set of merits not available in bulk materials, such as large specific surface area, low energy barrier for electron transportation and short ion diffusion path. These advantages are desirable especially the electrodes electrochemical storage devices. MXenes, first synthesized 2011 by etching their MAX phase precursors, plural reasons to represent new family 2D materials. Their rich diversity structure composition together with uncommon combination good electrical conductivity hydrophilicity makes themselves outstand whole world. Based on these advantages, MXenes hold great promise various technologically important applications, particularly developing techniques advanced smart systems, portable flexible electronics. There been remarkable research achievements synthesis application MXene-based While routes being continuously reported, novel also routinely discovered, which will undoubtedly help understand fundamental properties expand scope MXenes. As storage-related cope intrinsic weakness many endeavors made doping, structure-tuning compositing hybrid ingredients. In this review, current status up-to-date progress applications supercapacitors, metal-ion batteries lithium sulfur summarized discussed, typical work aforementioned three categories is respectively tabulated reference comparison.

Language: Английский

Citations

84

MoO3/TiO2/Ti3C2Tx nanocomposite based gas sensors for highly sensitive and selective isopropanol detection at room temperature DOI
Yu Yao, Yutong Han, Ming Zhou

et al.

Journal of Materials Chemistry A, Journal Year: 2022, Volume and Issue: 10(15), P. 8283 - 8292

Published: Jan. 1, 2022

The MoO 3 /TiO 2 /Ti C T x composite was synthesized by a simple one-step hydrothermal method. Due to the formation of more active centers and heterojunctions, sensor has excellent performance for VOCs unique response isopropanol.

Language: Английский

Citations

81

Boosting photocatalytic performance of CdxZn1–xS for H2 production by Mo2C MXene with large interlayer distance DOI
Sen Jin, Jiabin Wu, Jizhou Jiang

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(11), P. 5851 - 5863

Published: Jan. 1, 2023

Cd x Zn 1− S solid solution grow up on the surface of Mo 2 C MXene with in situ intercalation CTA + .

Language: Английский

Citations

69

Progress on high-temperature protective coatings for aero-engines DOI Creative Commons
Lei Guo, Wenting He, Wenbo Chen

et al.

Surface Science and Technology, Journal Year: 2023, Volume and Issue: 1(1)

Published: Sept. 27, 2023

Abstract Aero-engine is a key part of aircraft, the operating temperature which being pushed to unprecedented levels for higher engine efficiency and performance. To accomplish gas-inlet aero-engines, applying thermal barrier coatings (TBCs) on hot-section metallic components, or even replacing some components in aero-engines with ceramic-matrix composites (CMCs) environmental-barrier (EBCs) them, are effective methods have been widely accepted. On other hand, increasing causes aircraft more easily be detected, thus stealth necessary engines. Except hottest parts may not need TBCs EBCs due relatively low temperature, but they still protection from oxidation corrosion. Hence, corrosion-resistant essential. In this paper, latest progress above high-temperature protective coatings, i.e., TBCs, EBCs, reviewed, mainly including their materials, fabrication technologies addition, harsh environment, these face many threats such as calcia-magnesia-aluminosilicates (CMAS) attack, causing premature failure also concerned paper. The work would provide comprehensive understanding guidance developing advanced next-generation aero-engines.

Language: Английский

Citations

61