A Hierarchically Structured Graphene/Ag Nanowires Paper as Thermal Interface Material DOI Creative Commons

Le Lv,

Junfeng Ying, Lu Chen

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(5), P. 793 - 793

Published: Feb. 21, 2023

With the increase in heat power density modern integrating electronics, thermal interface materials (TIM) that can efficiently fill gaps between source and sinks enhance dissipation are urgently needed owing to their high conductivity excellent mechanical durability. Among all emerged TIMs, graphene-based TIMs have attracted increasing attention because of ultrahigh intrinsic graphene nanosheets. Despite extensive efforts, developing high-performance papers with through-plane remains challenging despite in-plane conductivity. In this study, a novel strategy for enhancing by situ depositing AgNWs on sheets (IGAP) was proposed, which could boost paper up 7.48 W m−1 K−1 under packaging conditions. TIM performance test actual simulated operating conditions, our IGAP exhibits strongly enhanced compared commercial pads. We envision as has great potential boosting development next-generation circuit electronics.

Language: Английский

Flexible and Robust Functionalized Boron Nitride/Poly(p-Phenylene Benzobisoxazole) Nanocomposite Paper with High Thermal Conductivity and Outstanding Electrical Insulation DOI Creative Commons
Lin Tang, Kunpeng Ruan, Xi Liu

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)

Published: Nov. 30, 2023

With the rapid development of 5G information technology, thermal conductivity/dissipation problems highly integrated electronic devices and electrical equipment are becoming prominent. In this work, "high-temperature solid-phase & diazonium salt decomposition" method is carried out to prepare benzidine-functionalized boron nitride (m-BN). Subsequently, m-BN/poly(p-phenylene benzobisoxazole) nanofiber (PNF) nanocomposite paper with nacre-mimetic layered structures prepared via sol-gel film transformation approach. The obtained m-BN/PNF 50 wt% m-BN presents excellent conductivity, incredible insulation, outstanding mechanical properties stability, due construction extensive hydrogen bonds π-π interactions between PNF, stable structures. Its λ∥ λ⊥ 9.68 0.84 W m-1 K-1, volume resistivity breakdown strength as high 2.3 × 1015 Ω cm 324.2 kV mm-1, respectively. Besides, it also extremely tensile 193.6 MPa decomposition temperature 640 °C, showing a broad application prospect in high-end management fields such equipment.

Language: Английский

Citations

105

Functional Materials and Innovative Strategies for Wearable Thermal Management Applications DOI Creative Commons

Yeongju Jung,

Minwoo Kim,

Taegyeom Kim

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: June 29, 2023

Thermal management is essential in our body as it affects various bodily functions, ranging from thermal discomfort to serious organ failures, an example of the worst-case scenario. There have been extensive studies about wearable materials and devices that augment thermoregulatory functionalities body, employing diverse systematic approaches attaining homeostasis. This paper reviews recent progress functional contribute wearables, particularly emphasizing strategic methodology regulate temperature. exist several methods promote personal a form. For instance, we can impede heat transfer using thermally insulating material with extremely low conductivity or directly cool skin surface. Thus, classify many into two branches, passive active modes, which are further subdivided specific strategies. Apart discussing strategies their mechanisms, also identify weaknesses each strategy scrutinize its potential direction should follow make substantial contributions future regulatory industries.

Language: Английский

Citations

67

Human Nervous System Inspired Modified Graphene Nanoplatelets/Cellulose Nanofibers‐Based Wearable Sensors with Superior Thermal Management and Electromagnetic Interference Shielding DOI
Z. A. Zhu, Zhongyuan Tian, Yanze Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(28)

Published: March 10, 2024

Abstract Wearable sensing technologies have witnessed rapid development in recent years due to their accessibility, functionality, and affordability. However, heat accumulation electromagnetic interference electronic components adversely affect the performance seriously damage human health. Herein, cellulose nanofibers (CNFs)‐based composites with high thermal conductivity (TC) excellent (EMI) shielding are prepared using CNFs as templates followed by coating tannic acid non‐covalent 3‐aminopropyltriethoxysilane covalent co‐modified graphene nanoplatelets (denoted mGNPs) through a simple electrostatic self‐assembly method. The subsequent hot‐pressing process yield order layer mGNPs CNFs‐based distributed along orientation close contact CNFs, fashion similar nervous system. resulting reveal TC of 136.2 W/(m·K) superior EMI effectiveness 105 dB. Thus, they used wearable sensors based on triboelectric effect monitor health real‐time, well express emotion Morse code. In sum, proposed strategy provides an avenue prolong service life flexible ensure safe use, promising for future wisdom healthcare smart robotics.

Language: Английский

Citations

59

Isomerization Engineering of Oxygen‐Enriched Carbon Quantum Dots for Efficient Electrochemical Hydrogen Peroxide Production DOI

Xie Le-ping,

Caihong Liang,

Yao Wu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: May 7, 2024

Abstract Hydrogen peroxide (H 2 O ) has emerged as a kind of multi‐functional green oxidants with extensive industrial utility. Oxidized carbon materials exhibit promises electrocatalysts in the two‐electron (2e − oxygen reduction reaction (ORR) for H production. However, precise identification and fabrication active sites that selectively yield present serious challenge. Herein, structural engineering strategy is employed to synthesize oxygen‐doped quantum dots (o‐CQD) 2e ORR. The surface electronic structure o‐CQDs systematically modulated by varying isomerization precursors, thereby demonstrating excellent electrocatalyst performance. Notably, o‐CQD‐3 emerges most promising candidate, showcasing remarkable selectivity 96.2% (n = 2.07) at 0.68 V versus RHE, coupled low Tafel diagram 66.95 mV dec −1 . In flow cell configuration, achieves productivity 338.7 mmol g catalyst h , maintaining consistent production stability over an impressive 120‐hour duration. Utilizing situ technology density functional theory calculations, it unveil edge are facilely functionalized C‐O‐C groups under alkaline ORR conditions. This approach advances forefront sustainable catalysis provides profound insight into carbon‐based design environmental‐friendly chemical synthesis processes.

Language: Английский

Citations

33

Dual‐Cooling Textile Enables Vertical Heat Dissipation and Sweat Evaporation For Thermal and Moisture Regulation DOI

Chengfeng Ding,

Yanyan Lin,

Ningbo Cheng

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(34)

Published: May 7, 2024

Abstract Personal thermal management textiles have garnered a lot of attention because they can efficiently preserve the body's and moisture comfort while saving energy consumption. Nonetheless, conduction cooling‐based textile research is scarce frequently encounters obstacles like overlooking through‐plane heat conduction, management, durability assurance. Here, dual‐cooling (DCT) that combines high‐efficiency dissipation sweat evaporation with 3D conductive network Janus wetting structure demonstrated. The DCT achieves notable in‐plane conductivity (8.57 0.70 W m −1 K ), along practical mechanical qualities (tensile fracture strength 65 MPa), under influence multistage network. Additionally, benefits from its structure, exhibiting unidirectional moisture‐wicking capability (transport index 1081%) fast water performance (0.34 g h ). Rapid are advantageous features for cooling human body in both static dynamic situations. Compared to cotton fabric, lower temperature by up 3.7 °C. This strategy provides fresh perspective on development advanced functional personalized savings buildings.

Language: Английский

Citations

18

Cerium Methacrylate Assisted Preparation of Highly Thermally Conductive and Anticorrosive Multifunctional Coatings for Heat Conduction Metals Protection DOI Creative Commons
Fei Xu, Peng Ye, Jianwen Peng

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: Aug. 18, 2023

Preparing polymeric coatings with well corrosion resistance and high thermal conductivity (TC) to prolong operational life ensure service reliability of heat conductive metallic materials has long been a substantive urgent need while difficult task. Here we report multifunctional epoxy composite coating (F-CB/CEP) by synthesizing cerium methacrylate ingeniously using it as novel curing agent inhibit for resin modifier boron nitride through "cation-π" interaction. The prepared F-CB/CEP presents TC 4.29 W m-1 K-1, which is much higher than other reported anti-corrosion polymer thereby endowing metal coated this outstanding management performance compared those pure coating. Meanwhile, the low-frequency impedance remains at 5.1 × 1011 Ω cm2 even after 181 days immersion in 3.5 wt% NaCl solution. Besides, also exhibits hydrophobicity, self-cleaning properties, temperature adhesion. This work provides valuable insights preparation high-performance potential be used advanced materials, especially conduction metals protection.

Language: Английский

Citations

33

Highly thermally conductive composites with boron nitride nanoribbon array DOI

Peng Wei,

Lei Feng, Qiang Chen

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 150915 - 150915

Published: April 1, 2024

Language: Английский

Citations

14

Electric-field-aligned liquid crystal polymer for doubling anisotropic thermal conductivity DOI Creative Commons
Maohua Li, Ping Gong,

Zhenbang Zhang

et al.

Communications Materials, Journal Year: 2024, Volume and Issue: 5(1)

Published: Feb. 21, 2024

Abstract High thermal conductive polymers have become more important because equipment requires high performance, high-energy density, and integration. There are different strategies to make polymers, among which is the synthesis of in liquid crystal phase. However, conductivity such material rarely beyond 1 W m −1 K disordered molecular directionality. The directionality between zones limits a specific direction. Here, we show method for unifying direction by applying an external electric field on monomers. Meanwhile, exposing transparent specially designed photopolymerisable monomer UV light, situ polymerised into polymer with intrinsic 1.02 . alignment was characterised resulted resultant conductivity.

Language: Английский

Citations

12

Thermal conductivity of epoxy composites containing 3D honeycomb boron nitride filler DOI
Guang Liu, Ao Ding, Pingfan Xu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151170 - 151170

Published: April 9, 2024

Language: Английский

Citations

12

Flexible boron nitride-based composite membrane with superhydrophobic/electrothermal synergistic response for enhanced passive anti-icing and active de-icing DOI

Ritong Wang,

Delai Ouyang,

Dongpeng Zhou

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 702, P. 135151 - 135151

Published: Aug. 22, 2024

Language: Английский

Citations

12