Precise Synthesis of High-Strength Chiral Au Nanomaterials: From Chiral Au Nanoclusters to Chiral Au Nanoparticles DOI Creative Commons
H. Luo, Chuan Shi,

Z. Zhang

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(3), P. 72 - 72

Published: Feb. 27, 2025

Chiral gold nanomaterials have promising applications in biomedicine, catalysis, optics and other fields. However, the complexity of their chiral sources has led to many challenges terms functional design controlled synthesis. In this paper, we systematically review development history Au nanomaterials; deeply analyze synthesis strategy, construction mechanism, performance optimization pathway; discuss formation mechanism light progress cutting-edge research look into future direction development. The aim is provide theoretical methodological support for controllable nanomaterials.

Language: Английский

The first chiral cerium halide towards circularly-polarized luminescence in the UV region DOI
Xinyi Niu, Zhichao Zeng, Zhaoyu Wang

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(6), P. 1961 - 1968

Published: Feb. 7, 2024

Language: Английский

Citations

32

Expanding the Horizons of Machine Learning in Nanomaterials to Chiral Nanostructures DOI Creative Commons
Vera Kuznetsova, Áine Coogan,

Dmitry Botov

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(18)

Published: Jan. 19, 2024

Abstract Machine learning holds significant research potential in the field of nanotechnology, enabling nanomaterial structure and property predictions, facilitating materials design discovery, reducing need for time‐consuming labor‐intensive experiments simulations. In contrast to their achiral counterparts, application machine chiral nanomaterials is still its infancy, with a limited number publications date. This despite great advance development new sustainable high values optical activity, circularly polarized luminescence, enantioselectivity, as well analysis structural chirality by electron microscopy. this review, an methods used studying provided, subsequently offering guidance on adapting extending work nanomaterials. An overview within framework synthesis–structure–property–application relationships presented insights how leverage study these highly complex are provided. Some key recent reviewed discussed Finally, review captures achievements, ongoing challenges, prospective outlook very important field.

Language: Английский

Citations

25

Chiral organic nanoparticles based photodynamic antibacterial films for food preservation DOI
Yanchao Liu, Min Zheng, Zhigang Xie

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 486, P. 150361 - 150361

Published: March 12, 2024

Language: Английский

Citations

24

Fabrication and applications of surface micro/nanostructures by femtosecond laser DOI Creative Commons
Di Zhu, Pei Zuo, Fang Li

et al.

Colloids and Interface Science Communications, Journal Year: 2024, Volume and Issue: 59, P. 100770 - 100770

Published: Feb. 7, 2024

With the ongoing advancement of processing technology, one hottest subjects is manufacturing materials with distinctive surface micro/nanostructures. Among these, femtosecond laser has been widely adopted as a high-precision and high-efficiency fabricating technology. When compared to other traditional methods, some advantages in controllable micro/nanostructures can fabricate wide range structures, including periodic microporous array structure, three-dimensional composite so on. They have many applications, optical anti-counterfeiting, anti-reflection, superhydrophobic superhydrophilic properties, This article reviews simplified mechanism material, typical fabricated by laser, applications laser-fabricated It proves technical prospect application potential fabrication

Language: Английский

Citations

19

Advances in Enantiomer-Dependent Nanotherapeutics DOI
Yuwen Wang, Andy Tay

ACS Nano, Journal Year: 2023, Volume and Issue: 17(11), P. 9850 - 9869

Published: June 2, 2023

The nanoscale properties of nanomaterials, especially nanoparticles, including size, shape, and surface charge, have been extensively studied for their impact on nanomedicine. Given the inherent chiral nature biological systems high enantiomeric selectivity, there is rising interest to manipulate chirality nanomaterials enhance biomolecular interactions improve nanotherapeutics. Chiral nanostructures are currently more prevalently used in biosensing diagnostic applications owing distinctive physical optical properties, but they hold great promise use In this Review, we first discuss stereospecific between biomolecules before comparing synthesis characterization methods nanoparticles nanoassemblies. Finally, examine nanotherapeutics cancer, immunomodulation, neurodegenerative diseases propose plausible mechanisms which interact with cells manipulation. This Review a timely reminder arsenal modifications boost research

Language: Английский

Citations

28

Chiral CuxOS@Fe‐MOFs for Enhanced Cancer Therapy DOI

Changlong Hao,

Lu Huang,

Hongyu Zhang

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(10)

Published: Nov. 29, 2023

Abstract Here, the development of chiral D ‐/ L ‐Cu x OS nanoparticle‐engineered metal–organic frameworks (Fe‐MIL‐88B‐NH 2 ), denoted as OS@Fe‐MOFs, for cuproptosis and ferroptosis synergistic therapy is described. The OS@Fe‐MOF displayed intense circular dichroism (CD) bands at 488 nm due to chirality transfer from penicillamine ligands. Chiral showed tumor microenvironment‐triggered catalytic therapeutic activity by simultaneously depleting ‐glutathione (GSH) generating potent reactive oxygen species in cancer cells. In vivo experimental results synchronously demonstrated with higher efficiency therapy. findings revealed that copper/iron ions released induced augmented oxidative stress ferroptosis, which synergizes enhanced index determined be 1.94, while D,L 1.75 1.84, respectively. To best knowledge, this first report a nanomaterial capable inducing ferroptosis‐cuproptosis cancers. should invigorate studies pursuing rational design nanomaterials efficacious based on ferroptosis.

Language: Английский

Citations

26

Organic Optoelectronic Synapses for Sound Perception DOI Creative Commons
Yanan Wei, Youxing Liu,

Qijie Lin

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: May 24, 2023

Abstract The neuromorphic systems for sound perception is under highly demanding the future bioinspired electronics and humanoid robots. However, based on volume, tone timbre remains unknown. Herein, organic optoelectronic synapses (OOSs) are constructed unprecedented recognition. of can be regulated appropriately by input signal voltages, frequencies light intensities OOSs, according to amplitude, frequency, waveform sound. quantitative relation between recognition factor ( ζ ) postsynaptic current I = − dark established achieve perception. Interestingly, bell University Chinese Academy Sciences recognized with an accuracy 99.8%. mechanism studies reveal that impedance interfacial layers play a critical role in synaptic performances. This contribution presents artificial at hardware levels.

Language: Английский

Citations

22

Bioinspired chiral nanozymes: Synthesis strategies, classification, biological effects and biomedical applications DOI
Xinyu Zhang,

Ziheng An,

Jie An

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 502, P. 215601 - 215601

Published: Dec. 13, 2023

Language: Английский

Citations

19

Ultraviolet Circularly Polarized Luminescence in Chiral Perovskite Nanoplatelet‐Molecular Hybrids: Direct Binding Versus Efficient Triplet Energy Transfer DOI Creative Commons
Bing Tang, Qi Wei, Shixun Wang

et al.

Small, Journal Year: 2024, Volume and Issue: 20(25)

Published: Jan. 10, 2024

Abstract The development of ultraviolet circularly polarized light (UVCPL) sources has the potential to benefit plenty practical applications but remains a challenge due limitations in available material systems and limited understanding excited state chirality transfer. Herein, by constructing hybrid structures chiral perovskite CsPbBr 3 nanoplatelets organic molecules, transfer is achieved, either via direct binding or triplet energy transfer, leading efficient UVCPL emission. underlying photophysical mechanisms these two scenarios are clarified comprehensive optical studies. Intriguingly, realized triple followed triplet–triplet annihilation upconversion processes, demonstrates 50‐fold enhanced dissymmetry factor g lum . Furthermore, stereoselective photopolymerization diacetylene monomer demonstrated using such UVCPL. This study provides both novel insights approach for realizing UVCPL, which can also be extended other spectral regions, as visible near‐infrared.

Language: Английский

Citations

9

RF advancements enabled by smart shape memory materials in the microwave Regime: A state-of-the-art review DOI
Syed Imran Hussain Shah, Sungjoon Lim

Materials Today Physics, Journal Year: 2024, Volume and Issue: 44, P. 101435 - 101435

Published: April 17, 2024

Language: Английский

Citations

9