ChemNanoMat,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 9, 2024
Abstract
The
modularization
of
metal‐organic‐frameworks
(MOFs)
powders
is
a
crucial
to
bringing
out
the
excellent
properties
MOFs
industrial
applications
in
water
treatment,
gas
adsorption/separation
and
catalytic
fields.
To
improve
their
practical
application
recyclability,
we
propose
hybrid
composite
biocompatible
decorated
on
self‐supported
three‐dimensional
(3D)
printed
polyurethane
acrylate
(PUA)
for
wastewater
treatment.
In
this
study,
select
Bi‐based
with
good
visible‐light
response
chemical
stability
as
photocatalysts,
two
MOFs,
bismuth
gallate
(Bi‐GA)
ellagic
acid
(Bi‐EA),
are
loaded
into
mesh‐like
PUA
template
by
in‐situ
growth
method.
And
then,
these
composites,
PUA/Bi‐GA
PUA/Bi‐EA
used
photocatalytic
treatment
Rhodamine‐B
(RhB)
dye.
results
demonstrate
that
could
reach
highest
removal
rate
98.08
%
under
acidic
conditions
4
hours.
performance
should
be
attributed
unique
structure
endow
high
adsorption
capacity
dyes,
further,
adsorbed
dye
sensitizer
enhances
utilization
sun‐light.
This
study
provides
new
advanced
other
environmental
purification.
Nano-Micro Letters,
Journal Year:
2024,
Volume and Issue:
17(1)
Published: Dec. 11, 2024
Proton-conducting
materials
have
attracted
considerable
interest
because
of
their
extensive
application
in
energy
storage
and
conversion
devices.
Among
them,
metal-organic
frameworks
(MOFs)
present
tremendous
development
potential
possibilities
for
constructing
novel
advanced
proton
conductors
due
to
special
advantages
crystallinity,
designability,
porosity.
In
particular,
several
design
strategies
the
structure
MOFs
opened
new
doors
advancement
MOF
conductors,
such
as
charged
network
construction,
ligand
functionalization,
metal-center
manipulation,
defective
engineering,
guest
molecule
incorporation,
pore-space
manipulation.
With
implementation
these
strategies,
proton-conducting
developed
significantly
profoundly
within
last
decade.
Therefore,
this
review,
we
critically
discuss
analyze
fundamental
principles,
methods
targeted
at
improving
conductivity
through
representative
examples.
Besides,
structural
features,
conduction
mechanism
behavior
are
discussed
thoroughly
meticulously.
Future
endeavors
also
proposed
address
challenges
practical
research.
We
sincerely
expect
that
review
will
bring
guidance
inspiration
further
motivate
research
enthusiasm
materials.
Industrial & Engineering Chemistry Research,
Journal Year:
2025,
Volume and Issue:
64(9), P. 4637 - 4668
Published: Feb. 24, 2025
This
review
discusses
the
transformative
impact
of
convergence
artificial
intelligence
(AI)
and
laboratory
automation
on
discovery
synthesis
metal–organic
frameworks
(MOFs).
MOFs,
known
for
their
tunable
structures
extensive
applications
in
fields
such
as
energy
storage,
drug
delivery,
environmental
remediation,
pose
significant
challenges
due
to
complex
processes
high
structural
diversity.
Laboratory
has
streamlined
repetitive
tasks,
enabled
high-throughput
screening
reaction
conditions,
accelerated
optimization
protocols.
The
integration
AI,
particularly
Transformers
large
language
models
(LLMs),
further
revolutionized
MOF
research
by
analyzing
massive
data
sets,
predicting
material
properties,
guiding
experimental
design.
emergence
self-driving
laboratories
(SDLs),
where
AI-driven
decision-making
is
coupled
with
automated
experimentation,
represents
next
frontier
research.
While
remain
fully
realizing
potential
this
synergistic
approach,
AI
heralds
a
new
era
efficiency
innovation
engineering
materials.
ChemistrySelect,
Journal Year:
2025,
Volume and Issue:
10(12)
Published: March 1, 2025
Abstract
This
study
delves
into
the
innovative
intersection
of
3D
printing
and
metal‐organic
frameworks
(MOFs),
highlighting
their
potential
to
revolutionize
material
science
engineering.
MOFs,
known
for
crystalline
architecture,
high
porosity,
functional
versatility,
have
traditionally
been
synthesized
using
conventional
methods,
which
face
challenges
in
scalability
customization.
work
explores
advantages
fabricating
MOF‐based
materials,
enabling
precise
geometric
tailoring
enhanced
structural
integration.
The
classification
zeolitic
hierarchically
organized
porous
coordination
polymers
underscores
diverse
applications
across
fields
such
as
energy
storage,
gas
separation,
biomedical
Furthermore,
3D‐printed
MOFs
advanced
like
drug
delivery,
environmental
remediation,
electronic
devices
is
thoroughly
analyzed.
comprehensive
review
emphasizes
transformative
role
unlocking
full
providing
a
pathway
novel
innovations
multidisciplinary
applications.
