A variable bidentate traceless directing group for nickel-catalyzed regioselective B–H poly-chalcogenation of o-carboranes

Inorganic Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A nickel-catalyzed direct cage B–H poly-chalcogenation of icosahedral carborane clusters, enabled by a variable bidentate 8-aminoquinoline traceless directing group, has been developed under oxidant-free and weakly basic conditions.

Language: Английский

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Charge-Compensated Derivatives of Nido-Carborane

Inorganics, Journal Year: 2023, Volume and Issue: 11(2), P. 72 - 72

Published: Feb. 2, 2023

This review summarizes data on the main types of charge-compensated nido-carborane derivatives. Compared with organic analogs, onium derivatives have increased stability due to stabilizing electron-donor action boron cage. Charge-compensated are considered according type heteroatom bonded a atom.

Language: Английский

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In Vivo Application of Carboranes for Boron Neutron Capture Therapy (BNCT): Structure, Formulation and Analytical Methods for Detection

Cancers, Journal Year: 2023, Volume and Issue: 15(20), P. 4944 - 4944

Published: Oct. 11, 2023

Carboranes have emerged as one of the most promising boron agents in neutron capture therapy (BNCT). In this context, vivo studies are particularly relevant, since they provide qualitative and quantitative information about biodistribution these molecules, which is utmost importance to determine efficacy BNCT, defining their localization (bio)accumulation, well pharmacokinetics pharmacodynamics. First, we gathered a detailed list carboranes used for studies, considering synthesis carborane derivatives or use delivery system such liposomes, micelles nanoparticles. Then, formulation employed cancer model each were identified. Finally, examined analytical aspects concerning detection, identifying main methodologies applied literature ex analysis. The present work aims identify current strengths weakness establishing bottlenecks best strategies future applications.

Language: Английский

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Regiocontrollable B(2/3)–H Alkenylation of nido-Carboranes

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 18, 2024

Anionic

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Theoretical study of the reaction of 7,8-dicarba-nido-undecaborane with S-nucleophiles in the presence of mercury(ii) chloride

Russian Chemical Bulletin, Journal Year: 2024, Volume and Issue: 73(10), P. 2900 - 2909

Published: Oct. 1, 2024

Language: Английский

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