Conceptual Process Design, Techno-Economics, and Greenhouse Gas Analysis of Furfuryl Alcohol Production via Transfer Hydrogenation DOI
Gabriel Fraga, Jerome Ramirez, Marguerite Renouf

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10604 - 10614

Published: June 28, 2024

Catalytic transfer hydrogenation (CTH) has gained attention as a potentially more sustainable process than conventional with H 2 gas.In this process, hydrogen is supplied in situ from donor molecule without the need for high-pressure .We developed conceptual commercial of furfural into furfuryl alcohol and performed techno-economic greenhouse gas analyses aiming to identify bottlenecks guide future research field.Two compounds were considered: isopropanol ethanol.Total capital investment varies between US$24.8-33.3 million these processes, minimum selling price (MSP) below market US$1.52/kgonly ethanol donor.The main impact on profitability dehydrogenated co-product.Thus, low-cost donors that generate high-value dehydrogenation products are required be competitive hydrogenation.In addition, utilizing comes free embodied and/or avoids GHG release CTH have lower emissions intensity hydrogenation.

Language: Английский

Tuning metal-support interactions in MOF-derived CoNi@NC supported Pd catalysts for efficient hydrogenation of bicarbonate using glycerol as a hydrogen donor DOI

Xiaojin Dong,

Wenfeng Zhong,

Xuecheng Li

et al.

Physical Chemistry Chemical Physics, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The hydrogenation of bicarbonate, a byproduct CO 2 captured in alkaline solutions, into formic acid (FA) using glycerol (GLY) as hydrogen source offers promising carbon-negative strategy for reducing emissions.

Language: Английский

Citations

0
Boosting the Transfer Hydrogenation of Nitrobenzene to Azobenzene from Glycerol by Tuning the Oxygen-Vacancy Defects over Iron-Based Catalysts DOI
Honghui Gong, Fei Wang,

Qi Li

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Language: Английский

Citations

0
The d-p electron coupling over the unsaturated oxygen coordinated CuCo alloy surface for enhanced N-heteroarenes hydrogenation under mild conditions DOI

Dengqi Zhou,

Ke Zeng, Liqiang Wang

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

0
Upgrading pyrolysis liquid from high-density polyethylene to fuel-like hydrocarbons by catalytic transfer hydrogenation with a NaBH4 hydrogen donor DOI

Kanticha Lomhual,

Worasak Phetwarotai, Neeranuch Phusunti

et al.

Journal of the Energy Institute, Journal Year: 2025, Volume and Issue: unknown, P. 102132 - 102132

Published: May 1, 2025

Language: Английский

Citations

0
Conceptual Process Design, Techno-Economics, and Greenhouse Gas Analysis of Furfuryl Alcohol Production via Transfer Hydrogenation DOI
Gabriel Fraga, Jerome Ramirez, Marguerite Renouf

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10604 - 10614

Published: June 28, 2024

Catalytic transfer hydrogenation (CTH) has gained attention as a potentially more sustainable process than conventional with H 2 gas.In this process, hydrogen is supplied in situ from donor molecule without the need for high-pressure .We developed conceptual commercial of furfural into furfuryl alcohol and performed techno-economic greenhouse gas analyses aiming to identify bottlenecks guide future research field.Two compounds were considered: isopropanol ethanol.Total capital investment varies between US$24.8-33.3 million these processes, minimum selling price (MSP) below market US$1.52/kgonly ethanol donor.The main impact on profitability dehydrogenated co-product.Thus, low-cost donors that generate high-value dehydrogenation products are required be competitive hydrogenation.In addition, utilizing comes free embodied and/or avoids GHG release CTH have lower emissions intensity hydrogenation.

Language: Английский

Citations

0