Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1003, P. 175553 - 175553
Published: July 14, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1003, P. 175553 - 175553
Published: July 14, 2024
Language: Английский
Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 62, P. 106934 - 106934
Published: March 18, 2023
Language: Английский
Citations
123Small, Journal Year: 2022, Volume and Issue: 18(44)
Published: Sept. 1, 2022
Metal-organic frameworks (MOFs) with diverse composition, tunable structure, and unique physicochemical properties have emerged as promising materials in various fields. The pore abundant active sites, ultrahigh specific surface area can facilitate mass transport provide outstanding capacity, making MOFs an ideal material for electrochemical energy storage conversion. However, the poor electrical conductivity of pristine severely limits their applications electrochemistry. Developing conductive has proved to be effective solution this problem. This review focuses on design synthesis MOF composites judiciously chosen conducting materials, MOFs, assembly methods, well preparation intrinsically based building 2D π-conjugated structures, introducing mixed-valence metal ions/redox-active ligands, designing π-π stacked pathways, constructing infinite metal-sulfur chains (-M-S-)∞ . Furthermore, recent progress challenges conversion (supercapacitors, Li-ion batteries, Li-S water splitting) are summarized.
Language: Английский
Citations
75Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(5), P. 2530 - 2577
Published: Jan. 1, 2024
This review emphasizes the crucial role of chemiresistive gas sensors (CGS) in detection. It underscores porous materials as alternatives, showcasing their exceptional attributes. The explores CGS-based real-life applications.
Language: Английский
Citations
69Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216048 - 216048
Published: July 4, 2024
Language: Английский
Citations
51Results in Engineering, Journal Year: 2024, Volume and Issue: 22, P. 102227 - 102227
Published: May 7, 2024
The rising need for cost-effective, versatile, and durable energy storage devices has propelled progress in electronics associated fields the present era of industrialization. Due to their tactile, structural, aesthetic qualities, two-dimensional (2D) stratified nanomaterials have developed as attractive rivals high-efficiency retention devices. 2D MXenes, a type transition metal carbides/nitrides via thin thickness, adjustable electrochemical characteristics, high conductivity, plentiful supply active edge sites, drawn much attention area material science. For advanced technologies like supercapacitors (SCs), Ti3C2Tx MXenes are particularly well-suited electrode materials. utilization faced inhibitions due aggregation, oxidation, restacking phenomena occurring within layers. To overcome these obstacles, this investigation delves into various categories exhibiting notable activity. These encompass covalent organic frameworks (COFs), chalcogenides (TMCs), layered double hydroxides (LDHs), metal-organic (MOFs), derivatives, which hold promise synergistic coupling with MXenes. Nanoarchitectural engineering structures employed enhance performance nanomaterials, both individually composites metallic conductive SCs. review summarizes developments, challenges, future perspectives applying nanomaterial hybrid composite nanoarchitectures (NAs) SC. This endeavors advance high-performance innovations that meet demands contemporary industrial revolution. It achieves by exploring potential diverse (NAs).
Language: Английский
Citations
23International Materials Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 3, 2025
The extracellular matrix can be replicated by 3D scaffolds, providing a favorable environment for cell growth, proliferation, and differentiation. Despite their biocompatibility, biodegradability, bioactivity, the poor mechanical strength of scaffolds limits use heavy loads. This creates bottleneck in supply with enhanced all previously mentioned characteristics. Conjugated polymers have emerged as promising option scaffold construction due to electrical conductivity, adjustable surface qualities, ability transfer bioactive molecules. Moreover, metal-organic frameworks (MOFs) are rapidly emerging class nanomaterials uniform porosity, excellent surface-to-volume ratio, variable diverse configurations, well tuanble chemical structures. While both conjugated polymer-based MOF-based suffer from drawbacks such low stability possible toxicity, combination is an imperative strategy construct desirable scaffols biomedical applications. Specific examples investigated polymer-MOF provided each area, along explanation synthesis, fabrication method, physicochemical properties. Finally, applications polymers/MOF tissue engineering cancer theragnostic reviewed, current challenges potential future directions discussed.
Language: Английский
Citations
3ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: March 9, 2025
Recently, electrically conductive metal–organic frameworks (EC-MOFs) have emerged as a wealthy library of porous with unique properties, allowing their use in diverse applications energy conversion, including electrocatalysis. In this review, the electron conduction mechanisms EC-MOFs are examined, while electrical conductivities considered. There been various strategies to enhance MOFs ligand modification, incorporation conducting materials, and construction multidimensional architectures. With sufficient being established for EC-MOFs, there extensive pursuits electrocatalysis applications, such hydrogen evolution reaction, oxygen reduction N2 CO2 reaction. addition, computational modeling also exerts an important impact on revealing synthesis–structure–performance relationships. Finally, prospects current challenges discussed provide guidelines designing promising framework materials.
Language: Английский
Citations
3Nano Research, Journal Year: 2022, Volume and Issue: 16(1), P. 1338 - 1361
Published: Sept. 3, 2022
Language: Английский
Citations
66Polymers, Journal Year: 2023, Volume and Issue: 15(3), P. 730 - 730
Published: Jan. 31, 2023
Intrinsically conducting polymers ICPs can be combined with further electrochemically active materials into composites for use as masses in supercapacitor electrodes. Typical examples are inspected particular attention to the various roles played by constituents of and conceivable synergistic effects. Stability composite electrode materials, an essential property practical application, is addressed, taking account observed causes effects degradation.
Language: Английский
Citations
44Inorganics, Journal Year: 2023, Volume and Issue: 11(2), P. 65 - 65
Published: Jan. 30, 2023
Metal organic frameworks (MOFs) are a family of crystalline porous materials which attracts much attention for their possible application in energy electrochemical conversion and storage devices due to ordered structures characterized by large surface areas the presence selected cases redox-active skeleton. Their synthetic versatility relevant host-guest chemistry make them suitable platform use stable flexible conductive materials. In this review we summarize most recent results obtained field, analyzing MOFs fuel solar cells with special emphasis on PEMFCs PSCs, supercapacitors employment batteries differentiating Li-, Na- other metal ion-batteries. Finally, an overview water splitting reaction MOF-catalyzed is also reported.
Language: Английский
Citations
33