Physica Scripta, Journal Year: 2023, Volume and Issue: 99(1), P. 015923 - 015923

Published: Dec. 19, 2023

Abstract The characteristics of metal–organic framework (MOF) composites make them the most significant materials for energy conversion applications. MOFs are hybrid molecular frameworks synthesized using metal ions like Copper, Cobalt, Zinc, Nickel, etc and organic ligands such as BTC, NDC, etc. To meet fulfill futuristic demands needs, it is feasible to expand cost-effective solar cell devices MOF materials, therefore in present work, Cobalt-based (Co-MOF) by coordinating Cobalt nitrate 1,3,5 Benzene tricarboxylic acid (BTC or Trimesic acid) ligand Solvothermal method. study physiochemical properties Co-BTC MOFs, these have gone through a variety characterization processes where structural exploration unveils that intensity dominant peak obtained at 18.7° gradually decreases with decrease concentration trimesic ligand. First second weight losses, corresponding release solvent molecules breakdown frameworks, respectively, were detected thermogravimetric analysis (TGA) measurements. In FTIR spectra, metal-oxide, modified benzene, carboxylic, hydroxyl groups different modes vibrations observed. Analysis surface morphology demonstrated creation rod-like geometry whereas elemental studies inveterate effective formation MOFs. Additionally, optimized applied potential interfacial layer cells outcome implies device designed 10 LBL cycle evolutions provided relatively desirable performance parameters. findings recommended material progression necessary develop high-performance MOF-based devices.

Language: Английский