Green Chemistry, Journal Year: 2023, Volume and Issue: 25(6), P. 2042 - 2086
Published: Jan. 1, 2023
This review aims to assess the sustainability and greenness of modification processing lignin feedstock using an adaptation CHEM21 Metrics Toolkit includes a guide for green solvents designing ionic liquids.
Language: Английский
Environments, Journal Year: 2022, Volume and Issue: 10(1), P. 6 - 6
Published: Dec. 23, 2022
An upsurge in global population and rapid urbanization has accelerated huge dependence on petroleum-derived fuels consequent environmental concerns owing to greenhouse gas emissions the atmosphere. integrated biorefinery uses lignocellulosic feedstock as raw material for production of renewable biofuels, other fine chemicals. The sustainable bio-economy industry would benefit greatly from effective use biomass obtained agricultural feedstocks replace petrochemical products. Lignin, cellulose, hemicellulose, extractives, which are essential components biomass, must be separated or upgraded into useful forms order fully realize potential biorefinery. development low-cost green pretreatment technologies with deconstruction is imperative an efficient bioprocess. abundance microorganisms along their continuous various degradative enzymes makes them suited environmentally friendly bioconversion agro-industrial wastes viable bioproducts. present review highlights concept biorefinery, its valorization by strategies biofuels biochemicals. major barriers challenges technologies, sustainability bioproducts, promising solutions alleviate those bottlenecks also summarized.
Language: Английский
Citations
109
Catalysts, Journal Year: 2022, Volume and Issue: 12(11), P. 1373 - 1373
Published: Nov. 5, 2022
The grave environmental, social, and economic concerns over the unprecedented exploitation of non-renewable energy resources have drawn attention policy makers research organizations towards sustainable use agro-industrial food crop wastes. Enzymes are versatile biocatalysts with immense potential to transform industry lignocellulosic biorefineries. Microbial enzymes offer cleaner greener solutions produce fine chemicals compounds. production industrially important from abundantly present waste offers for commercial value-added chemicals. recent developments in biocatalytic systems designed either increase catalytic capability or create new distinctive properties. limitations low efficiency enzyme denaturation ambient conditions can be mitigated by employing diverse inexpensive immobilization carriers, such as agro-food based materials, biopolymers, nanomaterials. Moreover, revolutionary protein engineering tools help designing constructing tailored improved substrate specificity, activity, stability, reaction product inhibition. This review discusses essential industrial trash application low-cost approaches development.
Language: Английский
Citations
108
Bioresource Technology, Journal Year: 2022, Volume and Issue: 369, P. 128328 - 128328
Published: Nov. 17, 2022
Language: Английский
Citations
103
Bioresource Technology, Journal Year: 2022, Volume and Issue: 369, P. 128396 - 128396
Published: Nov. 26, 2022
Pretreatment processes - recognized as critical steps for efficient biomass refining have received much attention over the last two decades. In this context, deep eutectic solvents (DES) emerged a novel alternative to conventional representing step forward in achieving more sustainable with both environmental and economic benefits. This paper presents an updated review of state-of-the-art DES-based applications biorefinery schemes. Besides describing fundamentals DES composition, synthesis, recycling, study comprehensive existing techno-economic life cycle assessment studies. Challenges, barriers, perspectives scale-up are also discussed.
Language: Английский
Citations
100
Bioresource Technology, Journal Year: 2022, Volume and Issue: 360, P. 127651 - 127651
Published: July 20, 2022
Language: Английский
Citations
99
The Science of The Total Environment, Journal Year: 2022, Volume and Issue: 861, P. 160560 - 160560
Published: Nov. 26, 2022
Language: Английский
Citations
83
Bioresource Technology, Journal Year: 2023, Volume and Issue: 381, P. 129145 - 129145
Published: May 9, 2023
Language: Английский
Citations
72
Bioresource Technology Reports, Journal Year: 2023, Volume and Issue: 21, P. 101365 - 101365
Published: Feb. 1, 2023
Language: Английский
Citations
53
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(7), P. 3627 - 3669
Published: Jan. 1, 2024
Deep eutectic solvents (DESs) enable many processes to be environmentally friendly. This Tutorial Review aims showcase the roles of DESs in synthesis functional materials from a green chemistry perspective.
Language: Английский
Citations
53
Industrial & Engineering Chemistry Research, Journal Year: 2023, Volume and Issue: 62(29), P. 11723 - 11734
Published: July 18, 2023
Deep eutectic solvents (DESs) have attracted significant interest in dissolving lignocellulosic components. However, revealing the relationship between solvation properties of DESs and their ability to dissolve components remains a challenge. Herein, 56 were prepared applied This revealed that Kamlet–Taft parameters (i.e., α, β, π*) significantly affected by structures DESs. More notably, correlation solubility varied with Concretely, greater values β β–α (net basicity), are expected cellulose efficiently, net basicity, favorable lignin, xylan was linearly correlated value. These findings provided valuable information necessary theoretical guidance on designing robust based solvatochromic parameters.
Language: Английский
Citations
51