Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 42, P. 102441 - 102441
Published: Dec. 1, 2024
Language: Английский
Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 42, P. 102441 - 102441
Published: Dec. 1, 2024
Language: Английский
Polymers, Journal Year: 2025, Volume and Issue: 17(1), P. 92 - 92
Published: Jan. 1, 2025
The highly selective and sensitive determination of pesticide residues in food is critical for human health protection. Herein, the specific selectivity molecularly imprinted polymers (MIPs) was proposed to construct an electrochemical sensor detection carbendazim (CBD), one famous broad-spectrum fungicides, by combining with synergistic effect bioelectrocatalysis nanocomposites. Gold nanoparticle-reduced graphene oxide (AuNP-rGO) composites were electrodeposited on a polished glassy carbon electrode (GCE). Then MIP films electropolymerized surface nanolayer using CBD as template molecule o-phenylenediamine (OPD) monomer. sensitivity heterogeneous structure greatly amplified AuNP-rGO bioelectrochemical oxidation glucose, which catalyzed glucose oxidase (GOD) help mediator underlying solution. developed showed high selectivity, good reproducibility, excellent stability towards linear range from 2.0 × 10−9 7.0 10−5 M, limit (LOD) 0.68 nM (S/N = 3). expected system would provide new idea development simple sensors (MIESs).
Language: Английский
Citations
3Sustainable materials and technologies, Journal Year: 2024, Volume and Issue: 40, P. e00935 - e00935
Published: April 17, 2024
Language: Английский
Citations
10Journal of Separation Science, Journal Year: 2024, Volume and Issue: 47(16)
Published: Aug. 1, 2024
Molecularly imprinted polymers, a type of special polymer materials, are widely used in biosensing and other fields due to their ability specifically recognize target molecules, often called "artificial receptors.". Nowadays, researchers constantly exploring new design synthesis methods for molecularly materials improve the selectivity sensitivity materials. Among them, selection functional monomers has attracted great attention. This review comprehensively analyzes discusses monomers. The most commonly among different types templates screened based on structural properties template including ion-imprinted protein-imprinted bacterial polymers. rich binding sites group multifunctional also highlighted advance development molecular imprinting technology. article further explores current challenges prospects emphasizes multiplex experiments computer simulations as important directions future research. provides comprehensive information constructive guidelines selecting areas such analytical chemistry biosensors.
Language: Английский
Citations
8Composites Part B Engineering, Journal Year: 2024, Volume and Issue: 279, P. 111432 - 111432
Published: April 4, 2024
Language: Английский
Citations
6Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 112743 - 112743
Published: Jan. 1, 2025
Language: Английский
Citations
0Molecules, Journal Year: 2025, Volume and Issue: 30(4), P. 798 - 798
Published: Feb. 9, 2025
Heavy metal ions impair human health and irreversibly damage the ecosystem. As a result, it is critical to create an efficient approach for identifying heavy ions. The electrochemical sensor method type of detection that highly sensitive, low in cost, allows real-time monitoring. In this study, solid carbon spheres were made using resorcinol formaldehyde as raw materials, followed by formation PEDOT/carbon sphere composites via situ oxidative polymerization, Pb2+ was detected utilizing them electrode modification materials. structure spherical analyzed scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR). To investigate properties these composites, impedance (EIS), cyclic voltammetry (CV), differential pulse (DPV) employed. addition, mechanism material Pb2⁺ studied CV. showcased extensive linear range 7.5 × 10-2 1.0 μM ions, achieving limit (LOD) 3.5 nM displaying exceptional selectivity. These results can be attributed its large surface area, superior electrical conductivity, outstanding transport properties. This study offers effective detecting concentrations Pb2+, with potential applications future detection.
Language: Английский
Citations
0Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 45, P. 102646 - 102646
Published: March 19, 2025
Language: Английский
Citations
0Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 5, 2025
The combination of diuron (DU) and thidiazuron (TDZ) is commonly used in cotton production for its excellent adaptability to low temperatures, which may lead increased crop soil pollution. simultaneous detection DU TDZ poses significant challenges due their weak overlapping signals, along with an unclear electrochemical mechanism TDZ. This study developed a dual-channel multifunctional molecularly imprinted (MMIP-EC) sensing platform by optimizing the substrate material MIP layer high performance. First, amino-functionalized graphene-based poly(pyrrole)-poly(3,4-ethylenedioxythiophene) (NH2-rGO/PPy-PEDOT) conductivity was synthesized as substrate. Subsequently, MMIPs were prepared one step using electropolymerization introducing chloroauric acid (HAuCl4) bifunctional monomers (dopamine thiophene). method not only enhanced specific binding capacity MMIP but also amplified signal through synergistic effect reduced AuNPs monomers. Furthermore, two independent modules (MMIP-DU MMIP-TDZ) integrated into EC transmission responses separate windows. Finally, based on high-performance liquid chromatography-mass spectrometry (HPLC-MS) kinetics studies, it speculated that oxidation via carbonylation secondary amine under strongly acidic conditions, followed hydrolysis form carboxyl group, reveals sensor exhibited performance selectivity sensitivity, limits 26.6 pg/mL 39.2 (TDZ). In conclusion, this presents novel perspective cost-effective highly efficient diverse environmental pollutants.
Language: Английский
Citations
0Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 121669 - 121669
Published: April 1, 2025
Language: Английский
Citations
0Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1310, P. 342703 - 342703
Published: May 8, 2024
Language: Английский
Citations
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