Mechanistic insights to define the directional role of hydrogen-bonding network between aryl oximes and propargyl alcohols in Rh(III) catalysis DOI
Yi Wang, Ping Qi, Hui Gao

et al.

Molecular Catalysis, Journal Year: 2023, Volume and Issue: 550, P. 113448 - 113448

Published: Sept. 15, 2023

Language: Английский

Experimental and computational journey on transition-metal-catalyzed C H functionalization with fluorinated π-systems DOI
Zhongyi Zeng, Huiying Xu, Hui Gao

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216244 - 216244

Published: Sept. 24, 2024

Language: Английский

Citations

4

Synthesis of gem-difluorinated pentacyclic indenopyrazolopyrazolones via Rh(iii)-catalyzed cascade C–H functionalization/[3 + 2] dipolar cycloaddition DOI

Fu‐Xiaomin Liu,

Weijie Chen, Ying Cai

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(9), P. 2512 - 2517

Published: Jan. 1, 2024

A Rh( iii )-catalysed cascade C–H functionalization/[3 + 2] dipolar cycloaddition was realized to deliver gem -difluorinated pentacyclic indenopyrazolopyrazolones with four continuous chiral carbon centres in a one-pot fashion.

Language: Английский

Citations

3

Rh(iii)-catalyzed redox-neutral C–H [4 + 1] annulation of sulfoximines with α,α-difluoromethylene alkynes: diastereoselective synthesis of E-monofluoroalkenyl benzoisothiazole 1-oxides DOI
Ting Wang,

Zhi‐Huan Peng,

Liexin Wu

et al.

Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(23), P. 5916 - 5922

Published: Jan. 1, 2023

Rh( iii )-catalyzed redox-neutral C–H [4 + 1] annulation of sulfoximines with α,α-difluoromethylene alkynes has been realized to diastereoselectively build E -monofluoroalkenyl benzoisothiazole 1-oxides.

Language: Английский

Citations

7

Copper-catalyzed 1,4-silylcyanation of 1,3-enynes: A silyl radical-initiated approach for synthesis of difunctionalized allenes DOI
Qi Li, Zi‐Lu Wang, Yun‐He Xu

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 109991 - 109991

Published: May 1, 2024

Language: Английский

Citations

2

Practical conversion of gem-difluorocyclopropenes for the chemodivergent assembly of fluorinated heterocyclic frameworks DOI

Dongping Pan,

Fu‐Xiaomin Liu,

Zhongyi Zeng

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(24), P. 10630 - 10637

Published: Jan. 1, 2023

A green method has been established by employing gem -difluorocyclopropylenes as versatile building blocks, leading to the chemodivergent formation of several fluorinated structural motifs including cyclopropapyrazolopyridines, indolizines etc .

Language: Английский

Citations

6

Cp*Rh(iii)-catalyzed regioselective cyclization of aromatic amides with allenes DOI
Jing Liu,

Deng-Yin Liu,

Qian Yang

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 60(5), P. 598 - 601

Published: Dec. 7, 2023

A new Cp*Rh(III)-catalyzed regioselective cyclization reaction of aromatic amides with allenes is reported. The use allenyl derivatives bearing a directing-group assistant as promoter was the key to success this protocol. In catalytic system,

Language: Английский

Citations

4

Mechanistic insights to define the directional role of hydrogen-bonding network between aryl oximes and propargyl alcohols in Rh(III) catalysis DOI
Yi Wang, Ping Qi, Hui Gao

et al.

Molecular Catalysis, Journal Year: 2023, Volume and Issue: 550, P. 113448 - 113448

Published: Sept. 15, 2023

Language: Английский

Citations

1