Metal–Organic Frameworks as a Versatile Platform for Proton Conductors

Advanced Materials, Journal Year: 2020, Volume and Issue: 32(21)

Published: April 3, 2020

Metal-organic frameworks (MOFs) are an intriguing type of crystalline porous materials that can be readily built from metal ions or clusters and organic linkers. Recently, MOF materials, featuring high surface areas, rich structural tunability, functional pore surfaces, which accommodate a variety guest molecules as proton carriers to systemically regulate the concentration mobility within available space, have attracted tremendous attention for their roles solid electrolytes in fuel cells. Recent advances MOFs versatile platform conduction field humidity condition proton-conduction, anhydrous atmosphere single-crystal including MOF-based membranes cells, summarized highlighted. Furthermore, challenges, future trends, prospects also discussed.

Language: Английский

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Recent advances in process engineering and upcoming applications of metal–organic frameworks

Coordination Chemistry Reviews, Journal Year: 2020, Volume and Issue: 426, P. 213544 - 213544

Published: Sept. 18, 2020

Language: Английский

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Conductive MOFs

EnergyChem, Journal Year: 2020, Volume and Issue: 2(2), P. 100029 - 100029

Published: March 7, 2020

Language: Английский

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Recent Progress on Microfine Design of Metal–Organic Frameworks: Structure Regulation and Gas Sorption and Separation

Advanced Materials, Journal Year: 2020, Volume and Issue: 32(44)

Published: July 16, 2020

Metal-organic frameworks (MOFs) have emerged as an important and unique class of functional crystalline hybrid porous materials in the past two decades. Due to their modular structures adjustable pore system, such distinctive exhibited remarkable prospects key applications pertaining adsorption gas storage, liquid separations, trace impurity removal. Evidently, gaining a better understanding structure-property relationship offers great potential for enhancement given associated MOF property either by structural adjustments via isoreticular chemistry or design construction new practice reticular chemistry. Correspondingly, application paves way microfine structure regulation presented MOFs. Explicitly, tuning is mainly based on known platforms, focusing modification and/or functionalization precise part thus providing effective approach produce richer systems with enhanced performances from limited number platforms. Here, latest progress this field highlighted emphasizing differences connections between various methods. Finally, challenges together are also discussed.

Language: Английский

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Rational strategies for proton-conductive metal–organic frameworks

Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(11), P. 6349 - 6368

Published: Jan. 1, 2021

Since the transition of energy platforms, proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.

Language: Английский

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Design and applications of water-stable metal-organic frameworks: status and challenges

Coordination Chemistry Reviews, Journal Year: 2020, Volume and Issue: 423, P. 213507 - 213507

Published: Aug. 9, 2020

Language: Английский

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Covalent‐Organic Frameworks (COFs) as Proton Conductors

Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 11(39)

Published: Sept. 1, 2021

Abstract Proton conductivity is the paramount property of proton‐conducting materials that are playing significant roles in diverse electrochemical devices with applications proton exchange membranes (PEMs) for fuel cells (PEMFCs). Considering scarcity fossil fuels, development clean and green renewable energy resources in‐demand across globe. Toward this direction, solid‐state conductors interest. The higher structural tunability, lower density, good crystallinity, accessible well‐defined pores, excellent thermal chemical stability covalent‐organic frameworks (COFs) make them versatile platforms as both under hydrous anhydrous conditions. Taking advantage such superior properties, reports on COFs have been increasing swiftly since 2014, which demands a summarization comprehensive discussion “at glance” visualization further development. In review, showcased newer class material. A presented by organizing strategies taken to develop COFs. Establishment structure–function relationships implementation discussed well. Moreover, challenges future prospects elaborately critically analyzed.

Language: Английский

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Recent advances in the development of electronically and ionically conductive metal-organic frameworks

Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 439, P. 213915 - 213915

Published: April 1, 2021

Language: Английский

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Organic carboxylate-based MOFs and derivatives for electrocatalytic water oxidation

Coordination Chemistry Reviews, Journal Year: 2020, Volume and Issue: 428, P. 213619 - 213619

Published: Oct. 14, 2020

Language: Английский

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Proton conductive covalent organic frameworks

Coordination Chemistry Reviews, Journal Year: 2020, Volume and Issue: 422, P. 213465 - 213465

Published: July 13, 2020

Language: Английский

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