A UOF based on a cyclotriphosphazene skeleton: fluorescence sensing of different substituted aldehydes and NACs DOI
Yao Xiao,

Zi-Xin You,

Qing-lin Guan

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(62), P. 9501 - 9504

Published: Jan. 1, 2023

A novel uranyl organic framework (U-hdpcp) based on flexible cyclic triphosphazene polycarboxylate ligands was prepared, which possesses the ability to sense aromatic aldehyde solutions (benzaldehyde, salicylaldehyde and 2-bromobenzaldehyde) nitro compounds (2,4,6-trinitrophenol, 2,4-dinitrophenol o-nitrophenol). fluorescent thin film U-hdpcp@PVA with vapors prepared via a spin coating method. The work expands library of UOF materials large-sized carboxylic acid demonstrates promising applications in field sensors.

Language: Английский

Carbon-dots encapsulated luminescent metal–organic frameworks@surface molecularly imprinted polymer: A facile fluorescent probe for the determination of chloramphenicol DOI

Mingfei Pan,

Jiaqing Sun,

Yixin Wang

et al.

Food Chemistry, Journal Year: 2024, Volume and Issue: 442, P. 138461 - 138461

Published: Jan. 21, 2024

Language: Английский

Citations

18
Recent advances in metal-organic frameworks for oxygen evolution reaction electrocatalysts DOI Open Access
Ming Liu, Yinqiang Zhang, Xuemin Wang

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(10), P. 2754 - 2779

Published: Sept. 11, 2023

Language: Английский

Citations

33
Recent progress on construction and applications of metal‐organic frameworks‐based materials for lithium‐ion batteries and supercapacitors DOI Creative Commons

Dan Wei,

Lingling Zhang, Yiming Wang

et al.

Carbon Neutralization, Journal Year: 2024, Volume and Issue: 3(3), P. 396 - 414

Published: April 29, 2024

Abstract Metal‐organic frameworks (MOFs), a special sort of three‐dimensional crystalline porous lattices composed organic multi‐site connectors and metal nodes, are characterized by unique porosity high specific surface area, which have attracted wide range interest as electrode materials for the electrochemical energy storage devices in recent years. In this contribution, we outline current research progress on construction pristine MOFs, MOF composites, derivatives their applications supercapacitors (SCs) lithium‐ion batteries (LIBs). Specifically, discuss shortcomings MOFs‐based SCs LIBs. The innovative work performance improvements combining MOFs with other conductive derivating into sulfides, oxides, phosphides, carbon is also presented detail. Finally, our perspectives challenges future grasp potential mechanisms tentatively provided. This review will inspire more developments storage.

Language: Английский

Citations

16
Solvothermally and non-solvthermally fabricated covalent organic frameworks (COFs) for eco-friendly remediation of radiocontaminants in aquatic environments: A review DOI
Stephen Sunday Emmanuel, Christopher Olusola Olawoyin, Ademidun Adeola Adesibikan

et al.

Journal of Organometallic Chemistry, Journal Year: 2023, Volume and Issue: 1005, P. 122984 - 122984

Published: Dec. 16, 2023

Language: Английский

Citations

17
Triggered factors and structure-activity relationship in the dynamic reconstruction processing of MOF for the alkaline oxygen evolution reaction DOI
Qianglong Qi, Chengxu Zhang, Jue Hu

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216235 - 216235

Published: Oct. 1, 2024

Language: Английский

Citations

8
MOF-based Sensing Materials for Non-enzymatic Glucose Sensors DOI Open Access
Jingjing Liu,

Xiaoting Zha,

Yajie Yang

et al.

Journal of Electrochemical Science and Technology, Journal Year: 2024, Volume and Issue: 15(1), P. 32 - 50

Published: Feb. 23, 2024

<p>Diabetes mellitus is one of the common chronic diseases, seriously threating to human health. The continuous monitoring blood glucose concentration can effectively prevent diabetic diseases. sensing performance non-enzymatic sensors mainly determined by working electrode materials. Metal–organic frameworks (MOFs) are recognized as promising candidate for sensor application, due its large surface areas, ordered porous structure and nearly infinite designability. In this review, performance, research progress future challenge based on MOF-based materials in recent years presented. We hope that review would provide valuable technology guidance high MOFs.</p>

Language: Английский

Citations

7
Surface-supported metal−organic frameworks with geometric topological diversity via scanning tunneling microscopy DOI Creative Commons

Xiaoyang Zhao,

Xinrui Miao

iScience, Journal Year: 2024, Volume and Issue: 27(4), P. 109392 - 109392

Published: March 4, 2024

Surface-supported metal-organic frameworks (SMOFs) are long-range ordered periodic 2D lattice layers formed by inorganic metal nodes and organic ligands via coordination bonds on substrate surfaces. The atomic resolution STM lays a solid foundation for the conception construction of SMOFs with large area, stable structure, special function. In this review, cutting-edge research from design strategy, preparation process, how to accurately achieve structural functional diversity reviewed. Furthermore, we focus novel fascinating fractal structures, in which some typical honeycomb Kagome lattice, hexagonal geometry, Sierpiński triangles summarized, related prospects designing nanoscale systems architectures prospected. Finally, challenges faced synthesis denoted, application prospect development trend forecasted based current status.

Language: Английский

Citations

6
Modular Design of Highly Stable Semiconducting Porous Coordination Polymer for Efficient Electrosynthesis of Ammonia DOI
Ziqian Xue, Ming‐Shui Yao, Ken‐ichi Otake

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(21)

Published: April 8, 2024

Developing highly stable porous coordination polymers (PCPs) with integrated electrical conductivity is crucial for advancing our understanding of electrocatalytic mechanisms and the structure-activity relationship electrocatalysts. However, achieving this goal remains a formidable challenge because electrochemical instability observed in most PCPs. Herein, we develop "modular design" strategy to construct electrochemically semiconducting PCP, namely, Fe-pyNDI, which incorporates chain-type Fe-pyrazole metal cluster π-stacking column effective synergistic effects. The three-dimensional electron diffraction (3D ED) technique resolves precise structure. Both theoretical experimental investigation confirms that Fe-pyNDI can provide an efficient transport path enhance structural stability material. As result, serve as model electrocatalyst nitrate reduction reaction (NO

Language: Английский

Citations

5
Rational Construction of Two-Dimensional Conjugated Metal–Organic Frameworks (2D c-MOFs) for Electronics and Beyond DOI Creative Commons
Yang Lu, Paolo Samorı́, Xinliang Feng

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(14), P. 1985 - 1996

Published: July 4, 2024

ConspectusTwo-dimensional conjugated metal-organic frameworks (2D c-MOFs) have emerged as a novel class of multifunctional materials, attracting increasing attention due to their highly customizable chemistry yielding programmable and unprecedented structures properties. In particular, over the past decade, synergistic relationship between conductivity porosity 2D c-MOFs has paved way toward widespread applications. Despite promising potential, majority yet achieve atomically precise crystal structures, hindering full understanding control electronic structure intrinsic charge transport characteristics. When modulating properties two-dimensional layered framework decoupling processes within in layers is paramount importance, it represents significant challenge. Unfortunately, systems developed so far failed address such major research target, which can be achieved solely by manipulating c-MOFs. offer advantage organic radical molecules covalent frameworks: polymerization through oxidative coordination viable route form "spin-concentrated assemblies". However, role these spin centers still poorly understood, dynamics spins seldom been investigated. Consequently, overcoming challenges essential unlock potential electronics other related fields, new type quantum materials.In this Account, we summarize discuss our group's efforts at atomic level applications spintronics, thereby providing distinct evidence on platform for exploring phenomena. First, unravel key played rational design ligands decrease boundary defects, large single crystals, investigate The advantages disadvantages current structural elucidation strategies will discussed. Second, fundamental challenge c-MOF studies decouple in-plane interlayer pathways tuning To challenge, propose concept second-generation ligands, termed "programmable ligands", replace first-generation lack modifiability they mainly consist

Language: Английский

Citations

5
Revealing Ion Adsorption and Charging Mechanisms in Layered Metal–Organic Framework Supercapacitors with Solid-State Nuclear Magnetic Resonance DOI Creative Commons
Chloe J. Balhatchet, Jamie W. Gittins, Seung‐Jae Shin

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(33), P. 23171 - 23181

Published: Aug. 12, 2024

Conductive layered metal–organic frameworks (MOFs) have demonstrated promising electrochemical performances as supercapacitor electrode materials. The well-defined chemical structures of these crystalline porous electrodes facilitate structure–performance studies; however, there is a fundamental lack in the molecular-level understanding charge storage mechanisms conductive MOFs. To address this, we employ solid-state nuclear magnetic resonance (NMR) spectroscopy to study ion adsorption nickel 2,3,6,7,10,11-hexaiminotriphenylene, Ni3(HITP)2. In this system, find that separate resonances can be observed for MOF's in-pore and ex-pore ions. shift electrolyte found dominated by specific interactions with MOF functional groups, result supported quantum mechanics/molecular mechanics (QM/MM) density theory (DFT) calculations. Quantification environments NMR was also provide proxy performance, which could rapid screening synthesized samples. Finally, mechanism explored using combination ex-situ operando quartz crystal microbalance (EQCM) experiments. These measurements revealed cations are dominant contributors Ni3(HITP)2, anions contributing only minor contribution storage. Overall, work establishes methods studying MOF–electrolyte via spectroscopy. Understanding how influence charging will aid design combinations optimize performance supercapacitors, well other devices including electrocatalysts sensors.

Language: Английский

Citations

5