Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(11), P. 5175 - 5184
Published: March 1, 2024
Nowadays,
the
utilization
of
noncontact
temperature
and
pressure
sensing
is
experiencing
growing
popularity.
In
this
work,
Bi3+,
Eu3+-doped
Ca5(BO3)3F
(CBOF)
phosphors
were
synthesized
via
an
ionic
liquid-assisted
electrospinning
approach.
The
effect
molecular
weight
polyvinylpyrrolidone
on
morphology
CBOF
was
investigated,
a
comprehensive
analysis
its
formation
mechanism
presented.
luminescence
properties
CBOF:
Eu3+
studied
systematically.
temperature-dependent
emission
phosphor
discussed,
it
displayed
thermal
sensitivity,
which
can
be
attributed
to
distinct
response
behaviors
Bi3+
Eu3+.
investigation
pressure-dependent
behavior
revealed
anomalous
phenomenon:
with
increase
pressure,
peak
showed
trend
first
blue
shift
then
red
shift.
This
anomaly
discussed
in
detail.
exhibits
visual
color
change
(blue
cyan),
remarkable
sensitivity
(4.76
nm/GPa),
high
upper
limit
(24.2
GPa),
indicating
potential
use
as
optical
sensor.
Consequently,
study
presents
innovative
synthetic
approach
for
fabricating
CBOF,
presenting
bifunctional
material
promising
prospects
fields
sensing.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
13(4)
Published: Jan. 17, 2025
Abstract
A
new
method
is
presented
for
the
in
vitro
detection
of
glucose
using
oxidase
(GOx)
covalently
linked
to
persistent
luminescent
nanoparticles
(PLNPs).
This
ensures
both
sensitive
and
specific
by
exploiting
enhanced
luminescence
PLNPs
presence
H
2
O
,
generated
an
enzymatic
reaction.
To
this
end,
three
different
composed
ZnGa
4
:Cr
3+
(ZGO)
are
prepared
hydrothermal
synthesis
at
120
°C
6
h
(ZGO1),
12
(ZGO2),
24
(ZGO3),
followed
a
calcination
500
°C,
resulting
with
average
hydrodynamic
diameter
100
nm
±
5
after
grinding
centrifugation.
These
efficiently
functionalized
GOx,
via
PEG
linker.
Following
production
reaction
between
GOx
bound
ZGO
surface
present
100‐fold
diluted
serum,
significant
increase
signal
observed.
phenomenon
most
pronounced
ZGO2,
which
limit
0.01
µ
m
range
from
0.05
1
obtained.
results
demonstrate
innovative
potential
technique
monitoring,
opening
up
avenues
real‐time
monitoring
effective
management
diabetes.
Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 6, 2025
The
luminescence
kinetics
of
Ti3+
ions,
resulting
from
the
spin-allowed
2E
→
2T2
electron
transition,
are
generally
expected
to
be
fast,
within
microsecond
range.
However,
in
this
study,
we
observed
average
lifetimes
up
30
ms
nanocrystalline
LaAlO3:Ti3+
powders.
Our
detailed
analysis
spectroscopic
and
thermoluminescence
properties
suggests
that
prolonged
is
associated
with
presence
traps
proximity
excited
state
conduction
band,
which
facilitates
energy
transfer
between
them.
Furthermore,
shift
Urbach
states
an
increasing
concentration
correlates
efficiency
deeper
ions.
This
study
provides
a
comprehensive
strategy
for
controlling
ions
through
trap
engineering,
induced
by
dopant
ion
concentration,
can
applied
various
fields
including
thermometry.
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(15), P. 17759 - 17767
Published: July 24, 2024
Near-infrared
(NIR)
persistent
luminescence
nanoparticles
(PLNPs)
showed
great
potential
for
bioimaging
due
to
their
integration
of
non-in
situ
excitation
and
deep
tissue
penetration.
However,
PLNPs
are
often
introduced
with
Cr3+
ions
as
the
NIR
emission
centers.
Herein,
we
report
Cr-free
Bi2Ga3.985O9:1.5%
Fe3+
(BGF),
BGF
under
310
nm
exhibited
afterglow
at
794
in
first
biological
imaging
window
(650–950
nm),
duration
3
h.
was
grafted
hydroxyl
groups
then
polydopamine
(PDA)
indocyanine
green
(ICG)
through
π–π
stacking
hydrophobic
interactions,
PLNP–PDA–ICG
composite.
Bi
composite,
a
heavy
atom
element,
exhibits
computed
tomography
(CT)
contrast
capacity,
while
PDA
is
photothermal
agent,
ICG
excited
produce
reactive
oxide
species
photodynamic
therapy.
The
afterglow/CT
dual-modality
imaging-guided
photothermal/photodynamic
combination
therapy
validated
vitro/vivo
therapeutic
applications.
This
work
provides
PLNP
composite
drug-free
theranostics
low
toxicity.
Exploration,
Journal Year:
2024,
Volume and Issue:
4(4)
Published: Jan. 23, 2024
Abstract
Inorganic
persistent
phosphors
feature
great
potential
for
cancer
diagnosis
due
to
the
long
luminescence
lifetime,
low
background
scattering,
and
minimal
autofluorescence.
With
prominent
advantages
of
near‐infrared
light,
such
as
deep
penetration,
high
resolution,
autofluorescence,
tissue
absorption,
can
be
used
bioimaging.
We
focus
on
highlighting
inorganic
phosphors,
emphasizing
synthesis
methods
applications
in
diagnostics.
Typical
synthetic
high‐temperature
solid
state,
thermal
decomposition,
hydrothermal/solvothermal,
template
are
proposed
obtain
small‐size
biological
organisms.
The
mechanisms
with
different
excitation
discussed
effective
matrixes
including
galliumate,
germanium,
aluminate,
fluoride
explored.
Finally,
current
directions
where
continue
optimized
how
further
overcome
challenges
summarized.