Single-step conversion of methane-steam to methanol on single-atom Cu1/γ-Al2O3 catalyst prepared via electrostatic anchoring DOI

Hailong Zhang,

Xinyi Zhang,

Xueke Shi

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124648 - 124648

Published: Sept. 1, 2024

Language: Английский

Direct Methane to Methanol Conversion: An Overview of Non‐Syn Gas Catalytic Strategies DOI Creative Commons

Anjana Rajeev,

Thasnim P Mohammed,

Akhila George

et al.

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract Direct methane to methanol conversion is a dream reaction in industrial chemistry, which takes inspiration from the biological production catalysed by monooxygenase enzymes (MMOs). Over years, extensive studies have been conducted on this topic bioengineering MMOs, and tailoring methods isolate MMOs active form. Similarly, remarkable achievements noted other activation strategies such as use of heterogeneous catalysts or molecular catalysts. In review, we outline metabolism performed methanotrophs detail latest advancements site structures catalytic mechanisms both types MMOs. Also, recent progress bioinspired approaches using various catalysts, especially first‐row transition metal zeolites mechanistic insights are discussed. addition, complexes “Periana catalyst” for through methyl ester formation presence strong acids also detailed. Compared zeolites‐mediated field, utilisation application still its nascent phase further research required overcome limitations these effectively.

Language: Английский

Citations

1
Investigation on performance optimization of a novel microreactor with multiple-pulsation combustion for methanol steam reforming to hydrogen production for proton exchange membrane fuel cell DOI
Bo Luo,

E Jiaqiang,

Changling Feng

et al.

Applied Energy, Journal Year: 2025, Volume and Issue: 384, P. 125488 - 125488

Published: Feb. 11, 2025

Language: Английский

Citations

1
Methane Bubbled Through Seawater Can be Converted to Methanol With High Efficiency DOI Creative Commons
Xiaowei Song, Chanbasha Basheer, Jinheng Xu

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 21, 2025

Partial oxidation of methane (POM) is achieved by forming air-methane microbubbles in saltwater to which an alternating electric field applied using a copper oxide foam electrode. The solubility increased putting it contact with water containing dissolved KCl or NaCl (3%). Being fully dispersed as (20-40 µm diameter), reacts more hydroxyl radicals (OH·) at the gas-water interface. voltage (100 mV) generates two synergistic POM processes dominated Cl- → Cl· + e- and O2 -• under positive negative potentials, respectively. By tuning frequency amplitude, extent path process can be precisely controlled so that than 90% methanol selectively formed compared byproducts, dichloromethane, acetic acid. conversion yield estimated 57% rate approximately 887 µM h-1. This method appears have potential for removing from air seawater converting higher-concentration sources into value-added methanol.

Language: Английский

Citations

0
Unveiling Zeolite Confinement Effects on N2O Decomposition Reaction over [Cu2(μ-O)]2+ Active Sites DOI

Kuyyilthodi M. Farhan,

P. K. Sajith

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 25, 2025

Language: Английский

Citations

0
Catalytic materials based on metals (ions) used in the upcycling of plastics and polymers into fuels and valuable chemicals as part of sustainable development DOI
Kacper Pobłocki, Marta Pawlak, Joanna Drzeżdżon

et al.

Materials Science and Engineering R Reports, Journal Year: 2024, Volume and Issue: 162, P. 100881 - 100881

Published: Nov. 23, 2024

Language: Английский

Citations

2
ABO4 as an Active Catalyst Structure for Direct Partial CH4 Oxidation as Identified through Screening of Supported Catalysts DOI
Junya Ohyama,

Yuriko Yoshioka,

Masato TSUKAMOTO

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 15(2), P. 697 - 705

Published: Dec. 24, 2024

In the present study, 76 different metal-oxide-supported-transition-metal catalysts were prepared using 11 metal oxides (MgO, Al2O3, SiO2, TiO2, V2O5, ZrO2, Nb2O5, MoO3, Ta2O5, WO3, and La2O3) seven 3d metals (V, Mn, Fe, Co, Ni, Cu, Zn). The supported catalysts, along with single oxides, screened to identify catalytically active lattice oxygen structures for partial oxidation of CH4 formaldehyde methanol. Fe/MoO3, Fe/V2O5, particularly Fe/Nb2O5 found be highly effective. Structural analysis Fe sites in was performed high-energy-resolution-fluorescence-detected K-edge X-ray absorption near-edge structure spectroscopy, revealing that FeNbO4, FeMoO4, FeVO4 species Fe/Nb2O5, respectively, are responsible their partial-oxidation activities. contrast, Fe2O3 formed Fe/Al2O3, Fe/SiO2, Fe/Ta2O5, Fe/WO3 complete CO2 than oxidation, as MgFe2O4, LaFeO3, TiFe2O5 Fe/MgO, Fe/La2O3, Fe/TiO2, interstitial solid solution Fe3+ ZrO2 generated Fe/ZrO2. Furthermore, while Fe/WO4 ineffective FeWO4 by a hydrothermal method exhibits high selectivity oxidation. Additionally, previous studies have shown CuWO4 CuMoO4 Accordingly, ABO4 (where A is B group 5 or 6 metal) indicated viable design basis development

Language: Английский

Citations

2
Direct partial oxidation of low-concentration methane to methanol with copper-based clay catalysts DOI

Zhiheng Lu,

Yishuang Wang, Mingqiang Chen

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 81, P. 535 - 547

Published: July 26, 2024

Language: Английский

Citations

1
Direct Methane to Methanol Conversion Technologies Methods, Applications, and Future Prospects DOI

Saeed Gandomi,

Mohammad Reza Rahimpour

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

1
Recent advances on oxidation of alcohols over various types of materials as effective catalysts: An overview DOI
Zahra Shariatinia‬, Zahra Karimzadeh

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 526, P. 216372 - 216372

Published: Dec. 5, 2024

Language: Английский

Citations

1
Single-step conversion of methane-steam to methanol on single-atom Cu1/γ-Al2O3 catalyst prepared via electrostatic anchoring DOI

Hailong Zhang,

Xinyi Zhang,

Xueke Shi

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124648 - 124648

Published: Sept. 1, 2024

Language: Английский

Citations

0