ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 10, 2024
Language: Английский
Biomaterials, Journal Year: 2024, Volume and Issue: 313, P. 122763 - 122763
Published: Aug. 17, 2024
Language: Английский
Citations
17
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(49)
Published: Aug. 17, 2024
Abstract Covalent organic frameworks (COFs) are a promising class of polymers with the merits robust framework, ultrahigh porosity, and molecularly precise backbones, which reveals great potential for solar‐to‐chemical energy conversion in context mitigating environmental crises. However, photochemical activities individual COFs not as desired, primarily due to their limited light absorption, insufficient dissociation photogenerated excitons readily recombined carriers. Recently, COFs‐based metal‐free heterojunctions synergistic effects provide feasible route boost photocatalytic activity more environmentally friendly cost‐competitive manners. Herein, it is first systematically overview advances from heterojunction types, heterointerfaces interactions, primary design mechanisms. Then, typical photocatalysts (e.g., g‐C 3 N 4 ‐COFs, carbon materials‐COFs, polymer semiconductor‐COFs, COFs‐COFs heterojunction) summarized. Finally, challenges long‐term outlooks future offered terms efficiency, yield, stability, cost reaction mechanisms, well standardized evaluation method activities. It anticipated that this review can deliver new insights into fundamental engineering conversion, further accelerate development area.
Language: Английский
Citations
15
Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 5, 2024
Language: Английский
Citations
10
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 530, P. 216489 - 216489
Published: Feb. 3, 2025
Language: Английский
Citations
1
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 7, 2025
Abstract Precise cancer nanomedicine requires rational molecular instructions of therapeutic agents. Harnessing the structure‐property‐function relationships represents a practical strategy toward smart and effective nanomedicine. A structurally novel hydrogen‐bonded (H‐bonded) supramolecular nanoformulation generated by orthogonal self‐sorting assembly chemo‐prodrug (FPtF) phototherapeutics (BPeB) is here reported, to reach an autonomous with improved anti‐tumor efficacy combining chemo/phototherapy (CT/PT). The high‐fidelity H‐bonding modularity from privileged heterocomplementary diaminopyridine/5‐fluorouracil (DAP/FU) Hamilton wedge/barbiturate (HW/Ba) pairs, respectively enable precise spatial control binding interactions FPtF BPeB, in turn allowing process specific “mix‐and‐match” capability. To directly stimulate phototherapy BPeB via near‐infrared (NIR) light, spectral matched upconversion nanoparticles (UCNPs, β‐NaYF 4 :Yb,Er) are encapsulated simultaneously. As result, polymeric nanomicelles, i.e., F/B/U@PHDO, readily fabricated. Moreover, distinct association constant (Ka) DAP/FU (≈10 2 M −1 ) HW/Ba 4‐5 pairs reflect different strengths stabilities H‐bonds, thus endowing programmable dissociation, accompanied release through pH/thermal‐stimuli. Therapeutic regime appreciated outcomes ultimately accomplished combined CT/PT. opportunities offered design anticipated point new paradigm for therapy.
Language: Английский
Citations
0
Polymer Journal, Journal Year: 2024, Volume and Issue: 57(1), P. 119 - 128
Published: Sept. 19, 2024
Language: Английский
Citations
4
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216430 - 216430
Published: Jan. 24, 2025
Language: Английский
Citations
0
Small Science, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 21, 2025
Functional polymer composites offer versatility and high performance through material fusion, but flammability is an obstacle to application. Metal–organic frameworks (MOFs) have attracted attention in the field of flame retardant due their structural diversity specific surface area, they suffer from low efficiency agglomeration issues when used alone. Combining with two‐dimensional (2D) nanomaterials can improve above situation. Herein, strategies are explored for integrating MOFs 2D materials physical mixing situ growth enhance dispersion flame‐retardant effects polymers. Additionally, integration sensing achieve intelligent monitoring control, as well real‐time risk assessment system optimization. In summary, this review deeply analyzes dispersion, interfacial interaction, adjustment mechanism composite discusses detail application potential hybrids formed by sensing. Finally, opportunities challenges faced functional future summarized prospected. it also expected facilitate researchers quickly understand latest developments guide effective design.
Language: Английский
Citations
0
Smart Molecules, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
Abstract Covalent organic cages (COCs) are three‐dimensional molecules with permanent cavities, known for their ordered pore structures, excellent processability, and modular design. They have shown significant potential in applications such as gas adsorption, molecular separation, catalysis. Introducing chiral elements into COCs results confined which endows them unique functions expands application prospects. This review summarizes the research progress on covalent cages, focusing strategies incorporating elements, structures synthesis methods of representative COCs, advancements functions. Additionally, we provide perspectives future directions. We hope this will inspire further interest creativity among researchers field leading to development materials
Language: Английский
Citations
0
Journal of Controlled Release, Journal Year: 2025, Volume and Issue: unknown, P. 113720 - 113720
Published: April 1, 2025
Language: Английский
Citations
0