Uranyl–Nickel(II) Cation–Cation Interaction in a Triperiodic Framework with cis‐1,2‐Cyclohexanedicarboxylate and Isonicotinate Ligands DOI Creative Commons

Pierre Thuéry,

Youssef Atoini, Jack M. Harrowfield

et al.

Zeitschrift für anorganische und allgemeine Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Abstract Uranyl and nickel(II) nitrates have been reacted with cis ‐1,2‐cyclohexanedicarboxylic (H 2 chdc) isonicotinic (H‐int) acids under solvo‐hydrothermal conditions, giving the heterometallic, mixed‐ligand complex [(UO ) Ni(chdc) (int) ]⋅CH 3 CN ( 1 ). The uranyl cation is bound to carboxylate groups of both ligands while Ni II attached two nitrogen donors, strong additional interactions oxo a nearly regular octahedral environment. short Ni−O(oxo) bond length 2.114(3) Å amounts 67 % sum van der Waals radii. trimetallic (UO 6+ clusters thus formed are assembled by chdc 2− into linear chains which further bridged int − links give triperiodic framework dia topology, in small channels encompass rows acetonitrile solvent molecules. Complex does not display luminescence excitation solid state.

Language: Английский

Porous Metallophilic Frameworks Incorporating Metal–Organic Chains as Humidity Sensors Exploring Uranyl Photoluminescence DOI Open Access
Jakub J. Zakrzewski, Damian Jędrzejowski, Junhao Wang

et al.

Advanced Optical Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

Abstract Luminescent coordination polymers, including metal–organic frameworks, serve as a platform for optical sensing of physical and chemical stimuli, temperature or pressure the former, gases, solvent vapors, explosives, toxic species, etc. latter. The related materials built uranyl cations, UO 2 2+ , remain unexplored, despite their tunable photoluminescence. While recently, bimetallic supramolecular systems cyanido metal complexes have proven successful pathway toward stimuli‐responsive materials, combination with species is limited. Here, construction novel uranyl‐based demonstrating distinct sensitivity emission to vapors reported, which achieved by generating metal–organic, i.e, uranyl–2,4′‐bipyridine‐ N,N ’‐dioxide, chains that are arranged into porous framework metallophilic interactions between attached tetracyanidometallates(II), [M II (CN) 4 ] 2− (M = Pd, 1 ; Pt, ). Both resulting reveal reversible single‐crystal‐to‐single‐crystal transformation upon removal crystallization molecules, due flexibility forming resembling MOF‐74. presence infinite channels introduces capabilities water while emissive character leads humidity‐variable characteristics, strong variation in intensity lifetime. obtained exhibit repeatable adsorption meeting criteria luminescent sensors.

Language: Английский

Citations

0
γ-Radiation synthesis of bis-amidoxime-based three-dimensional hydrogel uranium adsorbent based on nano-rubber toughening DOI
Bo Tian, Wenze Li, Jianwei Zhang

et al.

Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 71, P. 107280 - 107280

Published: Feb. 19, 2025

Language: Английский

Citations

0
Preface to the special issue of the 13th international symposium on nano & supramolecular chemistry (ISNSC-13) DOI Creative Commons
Yang Kim, Mauro Mocerino

Journal of Inclusion Phenomena and Macrocyclic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Language: Английский

Citations

0
Ion Pair Effects of Zwitterionic Ni/Pd Allyl Complexes Bearing an α-Sulfonate-β-diimine Ligand by Binding of B(C6F5)3 on Norbornene Polymerization DOI

Donghui Li,

Handou Zheng,

Heng Gao

et al.

Organometallics, Journal Year: 2024, Volume and Issue: 43(20), P. 2527 - 2536

Published: Aug. 6, 2024

This paper initially reports the remote binding of B(C6F5)3 to zwitterionic nickel and palladium allyl complexes bearing an α-sulfonate-β-diimine ligand ion pair effects on norbornene polymerization. The coordination reaction lithium salt with η3-allyl nickel/palladium chloride dimers produces (Ni-1 Pd-1) uncoordinated sulfonate group tight pairs (M+--O–SO2 < 3 Å, M = Ni Pd). Zwitterionic Ni-1 Pd-1 are inactive without any additional activators for After activation by MAO, shows very high activity while exhibits moderate Using as activator, whereas activity. mechanism studies show that oxygen affords new Ni-2 Pd-2 loose (M+- - -O–B > 4.68 Å). leads less electrophilic metal centers looser pairs. Enhanced polymerization using activator is a result effects.

Language: Английский

Citations

2
High photoluminescence quantum yield of a uranyl ion complex with the hemi-zwitterion 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium DOI Creative Commons
Young Hoon Lee, Youssef Atoini, Sotaro Kusumoto

et al.

Polyhedron, Journal Year: 2024, Volume and Issue: 262, P. 117172 - 117172

Published: Aug. 6, 2024

[UO2(L)2] (1) and [(UO2)2(L)2(C2O4)] (2), where L– is 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium, are two uranyl ion complexes with a hemi-zwitterionic dicarboxylate ligand which have been synthesized under solvo-hydrothermal conditions characterized by their crystal structure luminescence properties. In both cases, the uranium atom in pentagonal-bipyramidal environment. Although diperiodic networks formed differences coordination mode of presence bis-chelating oxalate anions generated situ 2 result distinct topologies, hcb (with double edges) 1 V2O5 2. Parallel-displaced π–π interactions occur cases but particularly prominent While non-emissive excitation at 420 nm, gives well-resolved spectrum maxima locations agreement those usual for O5 equatorial environments. A photoluminescence quantum yield ∼ 43 % has measured solid state, this being among highest values known carboxylate complex.

Language: Английский

Citations

2
4-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes DOI Creative Commons
Youssef Atoini, Jack M. Harrowfield, P. Thuéry

et al.

CrystEngComm, Journal Year: 2024, Volume and Issue: 26(27), P. 3714 - 3725

Published: Jan. 1, 2024

The zwitterionic 4-(ammoniomethyl)benzoate ligand contains both a metal-coordinating carboxylate and hydrogen-bond donor, primary ammonium group, which contribute to the formation arrangement of oligomeric or polymeric assemblies.

Language: Английский

Citations

2
Crystal structure of catena-poly[[methanoldioxidouranium(VI)]-μ-2-[5-(2-oxidophenyl)-1H-1,2,4-triazol-3-yl]acetato-κ2 O:O′] DOI Creative Commons
Oleksandr V. Vashchenko, Dmytro M. Khomenko,

Roman O. Doroshchuk

et al.

Acta Crystallographica Section E Crystallographic Communications, Journal Year: 2024, Volume and Issue: 80(8), P. 852 - 856

Published: July 12, 2024

In the title complex, [U(C 10 H 7 N 3 O )O 2 (CH OH)] n , U VI cation has a typical pentagonal–bipyramidal environment with equatorial plane defined by one and two atoms of doubly deprotonated 2-[5-(2-hydroxyphenyl)-1 -1,2,4-triazol-3-yl]acetic acid ligand, carboxylate atom symmetry-related ligand methanol molecule [U—N/O eq 2.256 (4)–2.504 (5) Å]. The axial positions are occupied oxide atoms. almost coplanar, largest deviation from mean being 0.121 Å for benzene triazole rings tetradentate chelating–bridging twisted approximately 21.6 (2)° respect to each other. group bridges uranyl cations, forming neutral zigzag chain reinforced strong O—H...O hydrogen bond. crystal, adjacent chains linked into two-dimensional sheets parallel ac C/N—H...N/O bonding π–π interactions. Further weak C—H...O contacts consolidate three-dimensional supramolecular architecture. solid state, compound shows broad medium intensity LMCT transition centred around 463 nm, which is responsible its red colour.

Language: Английский

Citations

0
Synthesis of crystalline uranyl ion coordination polymers with zwitterionic carboxylate ligands: comparing solvothermal and ambient conditions DOI Creative Commons
Sotaro Kusumoto,

Yoshihiro Koide,

Shinya Hayami

et al.

Journal of Inclusion Phenomena and Macrocyclic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 17, 2024

Language: Английский

Citations

0
(Benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)), a novel uranyl-complexing tetrazwitterion DOI
Young Hoon Lee, Sotaro Kusumoto, Youssef Atoini

et al.

Australian Journal of Chemistry, Journal Year: 2024, Volume and Issue: 77(11)

Published: Oct. 22, 2024

The tetrazwitterionic, tetracarboxylate (benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)) (L) has been synthesized and used as a ligand in mixed-ligand complexes of the uranyl cation involving anionic carboxylates. {[(UO2)2(tdc)2(L)]·2H2O}n (1), where tdc2– is 2,5-thiophenedicarboxylate, crystallizes monoperiodic, ladder-like coordination polymer which two UO2(tdc) rows are bridged by L ligands with monodentate carboxylate groups. {[(UO2)2(OH)4(L)]·2H2O}n (2) diperiodic dinuclear (UO2)2(OH)22+ units nodes square lattice (sql) network being bound its four positional isomer (benzene-1,2,4,5-tetrayl)tetrakis(4-(1-carboxylatomethylpyridinium)) (L′) undergoes decarboxylation during synthesis under solvo-hydrothermal conditions, giving tetracationic (benzene-1,2,4,5-tetrayl)tetra{4-(N-methylpyridinium)} (btp4+) included counterion [btp][(UO2)4(O)2(pht)4]·1.5H2O (3), pht2– phthalate. discrete, tetranuclear 3 usual form μ3-oxo bridges alternating anions cations linked through π–π interactions arranged into layers.

Language: Английский

Citations

0
Uranyl–Nickel(II) Cation–Cation Interaction in a Triperiodic Framework with cis‐1,2‐Cyclohexanedicarboxylate and Isonicotinate Ligands DOI Creative Commons

Pierre Thuéry,

Youssef Atoini, Jack M. Harrowfield

et al.

Zeitschrift für anorganische und allgemeine Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Abstract Uranyl and nickel(II) nitrates have been reacted with cis ‐1,2‐cyclohexanedicarboxylic (H 2 chdc) isonicotinic (H‐int) acids under solvo‐hydrothermal conditions, giving the heterometallic, mixed‐ligand complex [(UO ) Ni(chdc) (int) ]⋅CH 3 CN ( 1 ). The uranyl cation is bound to carboxylate groups of both ligands while Ni II attached two nitrogen donors, strong additional interactions oxo a nearly regular octahedral environment. short Ni−O(oxo) bond length 2.114(3) Å amounts 67 % sum van der Waals radii. trimetallic (UO 6+ clusters thus formed are assembled by chdc 2− into linear chains which further bridged int − links give triperiodic framework dia topology, in small channels encompass rows acetonitrile solvent molecules. Complex does not display luminescence excitation solid state.

Language: Английский

Citations

0