Biocompatible Nano-Cocrystal Engineering for Targeted Herbicide Delivery: Enhancing Efficacy through Stimuli-Responsive Release and Reduced Environmental Losses DOI
Yuntian Xiao,

Chuanhua Wu,

Yongkang Liu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(38), P. 51283 - 51300

Published: Sept. 10, 2024

In addressing the critical challenges posed by misuse and inefficiency of traditional pesticides, we introduce a Nano-Cocrystal material composed herbicide clopyralid coformer phenazine. Developed through synergistic supramolecular self-assembly mechanochemical nanotechnology, this significantly enhances pesticide performance. It exhibits marked improvement in stability, with reductions hygroscopicity volatility approximately 38%. Moreover, it intelligently modulates release according to environmental factors, such as temperature, pH, soil inorganic salts, demonstrating decreased solubility up four times improved wettability adhesion on leaf surfaces. Importantly, herbicidal activity surpasses that pure clopyralid, increasing suppression rates

Language: Английский

Water-soluble stimuli-responsive supramolecular nanoagrochemicals based on macrocycle compounds DOI

Ya-Hui Song,

Qiang Bian, Fang Wang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 524, P. 216299 - 216299

Published: Nov. 9, 2024

Language: Английский

Citations

4
Eco-friendly 2,4-D ionic cocrystal with enhanced release and reduced non-target losses DOI
Zhiqing Li, Yuntian Xiao, Xiao‐Yang Qiu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159859 - 159859

Published: Jan. 1, 2025

Language: Английский

Citations

0
Alginate supramolecular for encapsulation of plant biocontrol bacteria: A review DOI
Roohallah Saberi Riseh, Fariba Fathi,

Masoumeh Vatankhah

et al.

Carbohydrate Polymers, Journal Year: 2025, Volume and Issue: unknown, P. 123511 - 123511

Published: March 1, 2025

Language: Английский

Citations

0
Cocrystal engineering for sustained release of dicamba: Mitigating secondary drift and reducing leaching DOI

Chuanhua Wu,

Yuntian Xiao, Na Wang

et al.

Journal of Controlled Release, Journal Year: 2024, Volume and Issue: 375, P. 178 - 192

Published: Sept. 10, 2024

Language: Английский

Citations

2
From Original Ferrocene‐Based Small‐Molecule Design to Multifunctional Supramolecular Bactericides: Their Efficient Applications in Controlling Biofilm‐Associated Bacterial Infections DOI

Haicong Zhao,

Xinyu He, Jinghan Yang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 20, 2024

Abstract Conventional bactericides struggle with biofilm barriers and inefficient deposition on hydrophobic leaves, resulting in undesirable control of plant bacterial diseases. To overcome these challenges, an innovative ferrocene‐based small‐molecule (FccA8R) is conceived, featuring disruption capabilities. Further optimizing FccA8R seven‐membered oligosaccharide‐involved host–guest supramolecular strategy creates two kinds biocompatible multifunctional nanospheres (FccA8R@ β ‐CD FccA8R@HP‐ ‐CD). This manipulation efficiently eradicates mature while enhancing droplet retention leaves. At a concentration 56.64 µg mL −1 , the materials remove Xanthomonas‐ biofilms by 76.32–76.83%, notably surpassing that single (57.96%). Their versatility extends to enhanced inhibition motility, extracellular enzymes secretion, exopolysaccharides production, all reducing virulence. In vivo pot experiments, FccA8R@ demonstrate workable efficacies 48.91–52.03% against rice blight at 200 superior commercial thiodiazole‐copper‐20%SC (36.42%) FccA8R‐0.1%Tween (39.54%). Furthermore, assemblies disclose broad‐spectrum bactericidal efficacy (71.45–73.19%) kiwifruit canker, significantly higher than (43.05%) (57.24%). Besides, are safe for plants non‐target organisms like zebrafish earthworms. Briefly, this research builds key foundation creating green from conception eco‐friendly assemblies, realizing prevention diseases environmental safety.

Language: Английский

Citations

2
Biocompatible Nano-Cocrystal Engineering for Targeted Herbicide Delivery: Enhancing Efficacy through Stimuli-Responsive Release and Reduced Environmental Losses DOI
Yuntian Xiao,

Chuanhua Wu,

Yongkang Liu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(38), P. 51283 - 51300

Published: Sept. 10, 2024

In addressing the critical challenges posed by misuse and inefficiency of traditional pesticides, we introduce a Nano-Cocrystal material composed herbicide clopyralid coformer phenazine. Developed through synergistic supramolecular self-assembly mechanochemical nanotechnology, this significantly enhances pesticide performance. It exhibits marked improvement in stability, with reductions hygroscopicity volatility approximately 38%. Moreover, it intelligently modulates release according to environmental factors, such as temperature, pH, soil inorganic salts, demonstrating decreased solubility up four times improved wettability adhesion on leaf surfaces. Importantly, herbicidal activity surpasses that pure clopyralid, increasing suppression rates

Language: Английский

Citations

1