Advanced Materials for Vanadium Redox Flow Batteries: Major Obstacles and Optimization Strategies DOI
Jinqing Du,

Huitong Lin,

Longyan Zhang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 21, 2025

Abstract Electrochemical energy storage (EES) demonstrates significant potential for large‐scale applications in renewable storage. Among these systems, vanadium redox flow batteries (VRFB) have garnered considerable attention due to their promising prospects widespread utilization. The performance and economic viability of VRFB largely depend on critical components, including membranes, electrodes, electrolytes. However, as the fundamental materials ion conduction, often struggle effectively balance proton transfer while preventing crossover, enhancing long‐term stability, reducing manufacturing costs. Additionally, inherent structural limitations surface property defects electrode significantly impact improvement V 2+ /V 3+ electrochemical reaction kinetics enhancement power density. Furthermore, composition concentration electrolyte play a crucial role determining cost VRFB, well its density cycling performance. This review analyzes summarizes each component, reviews evaluates latest research advancements material modification, optimization, processes components over past 5 years. Moreover, comprehensive assessment environmental sustainability, feasibility, is presented, aiming provide strategic guidance commercialization VRFB.

Language: Английский

Electrolyte additive engineering for aqueous Zn ion batteries DOI
Yifei Geng,

Liang Pan,

Ziyu Peng

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 51, P. 733 - 755

Published: July 12, 2022

Language: Английский

Citations

351

A Review on 3D Zinc Anodes for Zinc Ion Batteries DOI
Na Guo, Wenjie Huo, Xiaoyu Dong

et al.

Small Methods, Journal Year: 2022, Volume and Issue: 6(9)

Published: July 19, 2022

Abstract Zinc ion batteries (ZIBs) have been gradually developed in recent years due to their abundant resources, low cost, and environmental friendliness. Therefore, ZIBs received a great deal of attention from researchers, which are considered as the next generation portable energy storage systems. However, poor overall performance restricts development, is attributed zinc dendrites series side reactions. Constructing 3D anodes has proven be an effective way significantly improve electrochemical performance. In this review, challenges ZIBs, including dendrites, hydrogen evolution corrosion, well passivation, comprehensively summarized mechanisms discussed. with different structures fiberous, porous, ridge‐like structures, plated on substrates other anodes, subsequently discussed detail. Finally, emerging opportunities perspectives material design highlighted that need solved future practical applications discussed, hopefully illuminating forward for development ZIBs.

Language: Английский

Citations

223

A Review on Application of Biochar in the Removal of Pharmaceutical Pollutants through Adsorption and Persulfate-Based AOPs DOI Open Access

Ziyang Kang,

Xigai Jia,

Yuchen Zhang

et al.

Sustainability, Journal Year: 2022, Volume and Issue: 14(16), P. 10128 - 10128

Published: Aug. 16, 2022

Increasing quantities of pharmaceutical pollutants have been found in aquatic ecosystems. The treatment has a major task that people committed to recent years. removal can be achieved by adsorption and advanced oxidation processes (AOPs). Compared with other carbon materials, biochar strong capacity persulfate activation ability, more importantly, is cheap easy obtain; thus, it higher economic benefits. This study firstly reviews the application drugs (tetracycline (TC), sulfamethoxazole (SMX), acetaminophen (ACT), cephalexin (CPX), levofloxacin (LEV), etc.) through persulfate-based AOPs. In addition, we summarize mechanism for various main attack sites on different AOPs catalyzed biochar. Finally, challenges prospects respect are put forward.

Language: Английский

Citations

107

Recent advances in carbon-based electrocatalysts for vanadium redox flow battery: Mechanisms, properties, and perspectives DOI

Qingchun Jiang,

Yujie Ren, Yujie Yang

et al.

Composites Part B Engineering, Journal Year: 2022, Volume and Issue: 242, P. 110094 - 110094

Published: July 1, 2022

Language: Английский

Citations

102

Ultrafine SnO2 in situ modified graphite felt derived from metal–organic framework as a superior electrode for vanadium redox flow battery DOI

Qingchun Jiang,

Jin Li, Yujie Yang

et al.

Rare Metals, Journal Year: 2023, Volume and Issue: 42(4), P. 1214 - 1226

Published: Feb. 27, 2023

Language: Английский

Citations

83

Tailoring desolvation strategies for aqueous zinc-ion batteries DOI
Wenhao Ma,

Sunyufei Wang,

Xianwen Wu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(14), P. 4819 - 4846

Published: Jan. 1, 2024

This review provides a comprehensive overview detailing the advancements in desolvation strategies pertaining to aqueous zinc-ion batteries (AZIBs) performances, addressing applications and working mechanisms of AZIBs.

Language: Английский

Citations

70

High-activity and stability graphite felt supported by Fe, N, S co-doped carbon nanofibers derived from bimetal-organic framework for vanadium redox flow battery DOI

Qingchun Jiang,

Yujie Ren, Yujie Yang

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 460, P. 141751 - 141751

Published: Feb. 6, 2023

Language: Английский

Citations

61

Vanadium Redox Flow Battery: Review and Perspective of 3D Electrodes DOI

Lingzhi Ye,

Shaotian Qi,

Tukang Cheng

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(29), P. 18852 - 18869

Published: July 12, 2024

Vanadium redox flow battery (VRFB) has garnered significant attention due to its potential for facilitating the cost-effective utilization of renewable energy and large-scale power storage. However, limited electrochemical activity electrode in vanadium reactions poses a challenge achieving high-performance VRFB. Consequently, there is pressing need assess advancements electrodes inspire innovative approaches enhancing structure composition. This work categorizes three-dimensional (3D) derived from materials such as foam, biomass, electrospun fibers. By employing flexible design compositional functionalization, high-speed mass transfer channels abundant active sites can be created. Furthermore, incorporation 3D electrocatalysts into discussed, including metal-based, carbon-based, composite materials. The strong interaction ordered arrangement these nanocomposites have an influence on uniformity stability surface charge distribution, thereby performance electrodes. Finally, challenges perspectives VRFB are explored through electrodes, electrocatalysts, mechanisms. It hoped that this review will development methodology concept VRFB, so promote future scientific storage conversion technology.

Language: Английский

Citations

37

Electrolyte engineering for efficient and stable vanadium redox flow batteries DOI
Zihan Yu,

Xiongjie Jia,

Yuhao Cai

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 69, P. 103404 - 103404

Published: April 10, 2024

Language: Английский

Citations

25

Review of the Research Status of Cost-Effective Zinc–Iron Redox Flow Batteries DOI Creative Commons
Huan Zhang, Chuanyu Sun, Mingming Ge

et al.

Batteries, Journal Year: 2022, Volume and Issue: 8(11), P. 202 - 202

Published: Oct. 31, 2022

Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability have been the research focus of electrochemical energy storage technology due to their low electrolyte cost. This review introduces characteristics ZIRFBs which can be operated within a wide pH range, including acidic ZIRFB taking advantage Fen+ with high solubility, alkaline operating at relatively open-circuit potential current densities, neutral providing non-toxic, harmless, mild environment. No matter what kind ZIRFB, there are always zinc dendrites limiting areal capacity on anode, has become an obstacle that must considered in zinc-based RFBs. Therefore, we progress, especially summarizing analysis dendrites, Fe(III) hydrolysis, electrolytes. Given these challenges, this reports optimization electrolyte, electrode, membrane/separator, battery structure, numerical simulations, aiming promote performance development as practical application technology. Based investigations, also provide prospects direction ZIRFBs.

Language: Английский

Citations

51