Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110944 - 110944
Published: April 1, 2025
Language: Английский
ACS Energy Letters, Journal Year: 2023, Volume and Issue: 8(9), P. 3860 - 3867
Published: Aug. 25, 2023
A [4-(3,6-dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) self-assembled monolayer (SAM) has been employed in perovskite devices demonstrating high efficiencies. However, a uniform layer does not form due to the hydrophobicity of Me-4PACz. Here, we tackle this challenge by adding conjugated polyelectrolyte, poly(9,9-bis(3′-(N,N-dimethyl)-N-ethylammonium-propyl-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)) dibromide (PFN-Br), Me-4PACz specific ratio, defined as Pz:PFN. With mixing engineering strategy using Pz:PFN, PFN-Br interaction with A-site cation is confirmed via solution-state nuclear magnetic resonance studies. The narrow full widths at half-maxima diffraction peaks and photoluminescence spectra films reveal improved crystallization optimal ratio Interestingly, additionally tunes work function built-in voltage solar cells. Devices employing optimized Pz:PFN deliver an open-circuit 1.16 V efficiency >20% for perovskites bandgap 1.6 eV reproducibility concomitant stability.
Language: Английский
Citations
61
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)
Published: Feb. 7, 2024
Abstract Inverted perovskite solar cells (IPSCs) have attracted unprecedented attention due to their negligible hysteresis, long‐term operational stability, low temperature, and cost‐effective fabrication process, as well wide applications. The power conversion efficiency (PCE) of IPSCs has skyrocketed from 3.9% in 2013 certified 26.1% 2023, which is over the 25.8% regular counterpart, benefiting emergence a great number organic hole‐transporting materials (HTM). This review provides an overview recent development stability IPSCs, including small molecules conjugated conductive polymers. effective strategies for charge‐transport layer films are also discussed. Finally, prospective further outlined, developing novel fabricating techniques meet requirements commercial application.
Language: Английский
Citations
39
Advanced Powder Materials, Journal Year: 2025, Volume and Issue: unknown, P. 100275 - 100275
Published: Feb. 1, 2025
Language: Английский
Citations
3
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 469, P. 143860 - 143860
Published: June 5, 2023
Language: Английский
Citations
29
Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(20)
Published: April 5, 2023
Abstract The interface stability and non‐radiative recombination loss of the cathode greatly limit performance inverted perovskite solar cells (PSCs). Here, an efficient multifunctional anti‐corrosive modification strategy based on 2,2′‐(1,3‐phenylene)‐bis[5‐(4‐tert‐butylphenyl)‐1,3,4‐oxadiazole] (OXD‐7) is proposed to overcome issues. OXD‐7 molecules chemically coordinate Ag electrode form a stable complex film OXD7‐Ag, which suppresses halide ion migration thus enhances corrosion resistance as well. In addition, trap density film, PCBM/Ag interfaces contact, built‐in potential, moisture resistance, well unfavorable exciton dissociation elimination devices, are also improved with arrangement upon PCBM correspondingly device stability. Bidirectional ITO observed, suppressed by modification. high power conversion efficiency (PCE) 21.84% fill factor (≈84.63%) obtained via this strategy, one highest PCEs FFs solution‐process MAPbI 3 /PCBM heterojunctions. PCE can maintain ≈80% its initial value after 1080 h at 85 °C
Language: Английский
Citations
28
ACS Nano, Journal Year: 2024, Volume and Issue: 18(16), P. 10688 - 10725
Published: April 11, 2024
Metal-halide perovskite solar cells (PSCs), an emerging technology for transforming energy into a clean source of electricity, have reached efficiency levels comparable to those commercial silicon cells. Compared with other types PSCs, inverted (IPSCs) shown promise regard commercialization due their facile fabrication and excellent optoelectronic properties. The interlayer interfaces play important role in the performance cells, not only affecting charge transfer transport, but also acting as barrier against oxygen moisture permeation. Herein, we describe summarize last three years studies that advantages interface engineering-based advances IPSCs. This review includes brief introduction structure working principle IPSCs, analyzes how affect IPSC devices from perspective photovoltaic device lifetime. In addition, comprehensive summary various engineering approaches solving these problems challenges including use interlayers, modification, defect passivation, others, is summarized. Moreover, based upon current developments breakthroughs, fundamental perspectives on future pathways are provided innovation design next-generation
Language: Английский
Citations
15
Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(33)
Published: April 10, 2024
Abstract Herein, we synthesized two donor‐acceptor (D‐A) type small organic molecules with self‐assembly properties, namely MPA‐BT‐BA and MPA‐2FBT‐BA, both containing a low acidity anchoring group, benzoic acid. After systematically investigation, it is found that, the fluorination, MPA‐2FBT‐BA demonstrates lower highest occupied molecular orbital (HOMO) energy level, higher hole mobility, hydrophobicity stronger interaction perovskite layer than that of MPA‐BT‐BA. As result, device based‐on displays better crystallization morphology larger grain size less non‐radiative recombination. Consequently, using as transport material achieved power conversion efficiency (PCE) 20.32 % remarkable stability. being kept in an N 2 glove box for 116 days, unsealed PSCs’ retained 93 its initial PCE. Even exposed to air relative humidity range 30±5 43 PCE remained above 91 condition. This study highlights vital importance fluorination strategy combined group SAMs, offering pathway achieve efficient stable PSCs.
Language: Английский
Citations
10
Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 103954 - 103954
Published: Jan. 1, 2025
Language: Английский
Citations
1
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(28)
Published: March 28, 2023
Abstract Efficient modification of the interface between metal cathode and electron transport layer are critical for achieving high performance stability inverted perovskite solar cells (PSCs). Herein, a new alcohol‐soluble rhodamine‐functionalized dodecahydro‐ closo ‐dodecaborate derivate, RBH, is developed applied as an efficient interlayer to overcome (6,6)‐phenyl‐C 61 butyrie acid methyl ester (PCBM)/Ag issues. By introducing RBH interlayer, functions traps passivation, interfacial hydrophobicity enhancement, contact improvement well built‐in potential enhancement realized at same time thus correspondingly improve device stability. Consequently, power conversion efficiency (PCE) 21.08% fill factor 83.37% achieved, which one highest values based on solution‐processed MAPbI 3 /PCBM heterojunction PSCs. Moreover, can act shielding slow down moisture erosion self‐corrosion. The PCE devices still maintain 84% 456 h (85 °C @ N 2 ), 87% 360 (23 relative humidity (RH) 35%) its initial value, while control only ≈23%, 58% value under exposure conditions, respectively.
Language: Английский
Citations
21
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 459, P. 141524 - 141524
Published: Jan. 20, 2023
Language: Английский
Citations
19