Efficient and Stable Wide‐Bandgap Methylammonium‐Free Perovskite Solar Cells by Simultaneous Passivation and Cleaning with Diamine DOI Open Access
Luozheng Zhang, Yi Zhang,

Kaihuai Du

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 11, 2024

Wide‐bandgap perovskite solar cells (WBG‐PSCs) are pivotal in achieving high‐performance tandem cells. However, their power conversion efficiency (PCE) is limited by the losses from interfacial charge transfer barrier and nonradiative recombination. In this investigation, 1,4‐bis(aminomethyl)benzene (PDMA) employed as a defect passivator for fabricating methylammonium (MA)‐free (PSCs), thus effectively mitigating recombination of carriers. Meanwhile, PDMA molecules chemically rinse film to create grooved surface, leading increase contact area between electron transport layer further improve transfer. As result, PSCs based on these surface‐passivated cleaned films present champion PCE 21.23% ( E g = 1.68 eV) compared control devices with 18.23%, while maintaining over 80% after 800 h storage ambient air. This study presents highly effective approach one‐step passivation chemical cleaning wide‐bandgap efficient stable cells, offering valuable insights future research field.

Language: Английский

Self‐assembled monolayers (SAMs) in inverted perovskite solar cells and their tandem photovoltaics application DOI Creative Commons

Zijun Yi,

Xin Li,

Yuchen Xiong

et al.

Interdisciplinary materials, Journal Year: 2024, Volume and Issue: 3(2), P. 203 - 244

Published: Feb. 23, 2024

Abstract Self‐assembled monolayers (SAMs) employed in inverted perovskite solar cells (PSCs) have achieved groundbreaking progress device efficiency and stability for both single‐junction tandem configurations, owing to their distinctive versatile ability manipulate chemical physical interface properties. In this regard, we present a comprehensive review of recent research advancements concerning SAMs cells, where the prevailing challenges future development prospects applications are emphasized. We thoroughly examine mechanistic roles diverse energy‐level regulation, modification, defect passivation, charge transportation. This is by understanding how interfacial molecular interactions can be finely tuned mitigate recombination losses PSCs. Through review, aim provide valuable insights references further investigation utilization cells.

Language: Английский

Citations

43
Achieving over 42 % indoor efficiency in wide-bandgap perovskite solar cells through optimized interfacial passivation and carrier transport DOI
Zhong‐En Shi,

Ta-Hung Cheng,

Chien‐Yu Lung

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155512 - 155512

Published: Sept. 6, 2024

Language: Английский

Citations

18
Enhancing the Efficiency of Indoor Perovskite Solar Cells through Surface Defect Passivation with Coplanar Heteroacene Cored A–D–A‐type Molecules DOI
Bing‐Huang Jiang,

Zhen‐Jie Gao,

Chien‐Yu Lung

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(19)

Published: Dec. 29, 2023

Abstract The passivation of perovskite interfacial defects by the electron transport layer (ETL) has emerged as an effective strategy for enhancing performance solar cells (PSCs). Dithieno[2,3‐d:2′,3′‐d′]thieno[3,2‐b:3′,2′‐b′]dipyrrole (DTPT)‐based acceptor‐donor‐acceptor (A–D–A) molecules composed coplanar heteroacene electron‐donating core end‐capped with various electron‐accepting moieties are designed and examined ETL modifiers PSCs. Employing PCBM:DTPTCY results in defects, facilitation energy alignment at ETL/perovskite interface, enhancement carrier efficiency. optimized blended ETL‐based Cs 0.18 FA 0.82 Pb(I 0.8 Br 0.2 ) 3 p‐i‐n PSC exhibit performances 37.2% 39.9% under TL84 3000K LED (1000 lux), respectively. DTPTCY‐based device demonstrates remarkable stability, retaining 87% its initial power conversion efficiency (PCE) after 30 days storage a 40% relative humidity (RH) ambient air environment without any encapsulation, surpassing control device, which retains only 67% original PCE. These findings underscore potential A–D–A‐type molecule‐based interface modification to enhance contact properties, ultimately leading high‐efficiency stable

Language: Английский

Citations

24
Ag-LSPR and molecular additive: A collaborative approach to improve the photovoltaic performance of perovskite solar cells DOI
Le Zhang, Haipeng Jiang, Tao Huang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148572 - 148572

Published: Jan. 4, 2024

Language: Английский

Citations

13
Efficient wide-bandgap perovskite photovoltaics with homogeneous halogen-phase distribution DOI Creative Commons
Rui Wang,

Xiaoyu Liu,

Shancheng Yan

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Oct. 15, 2024

Wide-bandgap (WBG) perovskite solar cells (PSCs) are employed as top of tandem to break through the theoretical limits single-junction photovoltaic devices. However, WBG PSCs exhibit severe open-circuit voltage (V

Language: Английский

Citations

13
Recent Progress of Wide Bandgap Perovskites towards Two-Terminal Perovskite/Silicon Tandem Solar Cells DOI Creative Commons
Qianyu Chen, Long Zhou, Jiaojiao Zhang

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(2), P. 202 - 202

Published: Jan. 16, 2024

Perovskite/silicon tandem solar cells have garnered considerable interest due to their potential surpass the Shockley–Queisser limit of single-junction Si cells. The rapidly advanced efficiencies perovskite/silicon benefit from significant improvements in perovskite technology. Beginning with evolution wide bandgap towards two-terminal (2T) cells, this work concentrates on component engineering, additives, and interface modification Furthermore, advancements 2T are presented, influence central interconnect layer cell progression is emphasized. Finally, we discuss challenges obstacles associated conducting a thorough analysis providing prospect for future.

Language: Английский

Citations

10
Enhanced efficiency in two-terminal all-perovskite tandem solar cells via binary functional high polymer doping strategy DOI
Ziang Xie, Sen Chen,

Yili Pei

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148638 - 148638

Published: Jan. 8, 2024

Language: Английский

Citations

9
Enhancement of Efficiency of Perovskite Solar Cells with Hole-Selective Layers of Rationally Designed Thiazolo[5,4-d]thiazole Derivatives DOI Creative Commons

Asta Dabulienė,

Zhong‐En Shi, Karolis Leitonas

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(23), P. 30239 - 30254

Published: May 29, 2024

We introduce thiazolo[5,4-d]thiazole (TT)-based derivatives featuring carbazole, phenothiazine, or triphenylamine donor units as hole-selective materials to enhance the performance of wide-bandgap perovskite solar cells (PSCs). The optoelectronic properties underwent thorough evaluation and were substantially fine-tuned through deliberate molecular design. Time-of-flight hole mobility TTs ranged from 4.33 × 10–5 1.63 10–3 cm2 V–1 s–1 (at an electric field 1.6 105 V cm–1). Their ionization potentials −4.93 −5.59 eV. Using density functional theory (DFT) calculations, it has been demonstrated that S0 → S1 transitions in with carbazolyl ditert-butyl-phenothiazinyl substituents are characterized by local excitation (LE). Mixed intramolecular charge transfer (ICT) LE occurred for compounds containing ditert-butyl carbazolyl-, dimethoxy alkoxy-substituted triphenylamino moieties. selected TT used preparation layers (HSL) PSC structure glass/ITO/HSLs/Cs0.18FA0.82Pb(I0.8Br0.2)3/PEAI/PC61BM/BCP/Ag. (TTP-DPA) be effective material HSL. Its layer also functioned well interlayer, improving surface control HSL_2PACz (i.e., reducing energy 2PACz 66.9 52.4 mN m–1), thus enabling precise over growth level alignment carrier extraction/transportation at hole-selecting contact PSCs. 2PACz/TTP-DPA-based devices showed optimized 19.1 37.0% under 1-sun 3000 K LED (1000 lx) illuminations, respectively. These values represent improvements those achieved bare 2PACz-based devices, which attained efficiencies 17.4 32.2%, findings highlight promising potential enhancement

Language: Английский

Citations

9
Dual Interfacial Modification of Hematite Electron Transport Layer for Efficient and Stable perovskite solar cells DOI Creative Commons
Akbar Ali Qureshi, Muhammad Bilal, Muhammad Zia

et al.

Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 103954 - 103954

Published: Jan. 1, 2025

Language: Английский

Citations

1
Buried Interface Passivation with 3,4,5-Trifluorophenylboronic Acid Enables Efficient and Stable Inverted Perovskite Solar Cells DOI
Jiansheng Yang, Zhenhua Zhao, Changzeng Ding

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

The p-i-n type perovskite solar cells with a nickel oxide (NiOx) hole transport layer in combination self-assembled monolayers (SAMs) have high power conversion efficiency (PCE) of over 26%. surface properties the SAM significant impact on growth and crystallization film. In meanwhile, defects formed during thermal annealing at interface would act as charge recombination centers, decreasing device performance stability. To address these issues, this work introduces 3,4,5-trifluorophenylboronic acid (3,4,5-3FPBA) interfacial modification to improve buried that enable better With 3,4,5-3FPBA layer, based composition Cs0.05(FA0.98MA0.02)0.95Pb(I0.95Br0.05)3, increased from 21.99% 24.02%. A similar improvement was observed for Cs0.05FA0.82MA0.13Pb(I0.85Br0.15)3, where 21.87% 22.76%. universality has been confirmed. addition, resulting showed improved stability, maintaining 75% its initial after 500 h continuous heating 85 °C unencapsulated devices.

Language: Английский

Citations

1