Highly efficient and selective hydrogenation of furfural to furfuryl alcohol and cyclopentanone over Cu-Ni bimetallic Catalysts: The crucial role of CuNi alloys and Cu+ species

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 436, P. 115603 - 115603

Published: June 13, 2024

Language: Английский

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Phytic acid-assisted phase-controlled synthesis of nickel phosphides for highly selective hydrogenation of biomass-derived furfural

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 359, P. 124413 - 124413

Published: July 25, 2024

Language: Английский

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Intermetallic Palladium–Zinc Nanoparticles for the Ultraselective Hydrogenative Rearrangement of Furan Compounds

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(20), P. 13205 - 13214

Published: Sept. 27, 2023

The tandem hydrogenative rearrangement of furan aldehydes/ketones into cyclopentanones is crucial for synthesizing biobased fine chemicals but remains challenging because the complexity reaction network. Herein, intermetallic PdZn nanoparticle-supported catalysts were prepared, which showed a high catalytic efficiency 3-methyl cyclopentanone with 96.3% yield from 5-methyl furfural at hitherto lowest temperature 120 °C. Furthermore, they exhibited generality synthesis yields above 90% other aldehydes (i.e., furfural, 5-hydroxymethyl and 5-ethyl furfural) ketones 2-furan methyl ketone ethyl ketone). Investigations mechanism that H2 was heterolytically activated on Pd–Zn pair to form H––Pd–Zn–H3O+ via an ionic water-mediated pathway, not only functioned as unconventional active sites carbonyl group hydrogenation step also provided Brønsted acid ring opening intramolecular aldol condensation steps. This study presents exciting strategy bifunctional catalysis substrates by generating transient H+–H– pairs using advanced alloy catalysts.

Language: Английский

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High-throughput screening of 2,500 ionic liquids for sustainable furfural recovery: Bridging quantum simulations, machine learning, and experimental validation

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 153965 - 153965

Published: July 14, 2024

Language: Английский

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Understanding the Different Preference of PtM (M=Fe, Co, Ni, Cu, Zn) Bimetallic Surfaces for Catalyzing Furanic Compounds to Chain Alcohol in Aqueous Solution

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125078 - 125078

Published: Jan. 1, 2025

Language: Английский

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Efficient Hydrogenolysis of Lignin into Aromatic Monomers over N-Doped Carbon Supported Co and Dual-Phase MoxC Nanoparticles

Catalysts, Journal Year: 2025, Volume and Issue: 15(4), P. 297 - 297

Published: March 21, 2025

The key to selectively cleaving C–O bonds in lignin produce high-value aromatic chemicals lies the development of efficient and stable catalysts. In this study, a heterostructured catalyst with N-doped carbon-supported Co dual-phase MoxC nanoparticles was prepared via situ pyrolysis Co–Mo–N precursor. α-MoC/β-Mo2C heterostructure is adjusted by varying Co:Mo ratio affect structure electronic properties catalyst. heterostructures bring about enhanced electron transfer from Mo, which promotes hydrogen dissociation over sites, significantly improving catalyst’s hydrogenolysis activity stability. optimal Co1MoxC@NC exhibits excellent activity; under reaction conditions (260 °C, 1 MPa H2, 3 h), yield monomers reaches 28.5%. Such prominent performance not only benefits numerous hetero-interfaces that offer abundant active sites for dissociation, but also should be ascribed strong synergistic effect between Mo.

Language: Английский

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Unveiling the Synergistic Coupling Between Nickel Phosphide and Graphitic Carbon Nitride for Sustainable Catalytic Transfer Hydrogenation of Quinoline: Ensemble and Ligand Effects

Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Abstract In recent years, metal phosphide catalysts have garnered immense attention among the catalysis community due to their facile synthesis and excellent catalytic activity but promising potential in field of organic transformation is not been fully explored. The synergistic coupling between support material plays a crucial role enhancing overall as well recovery catalyst. Herein, this study reports nickel (Ni 2 P) graphitic carbon nitride (GCN) nanosheets an interfacial catalyst for effective efficient transfer hydrogenation quinoline. significance developed interface Ni P GCN revealed by detailed spectroscopic theoretical investigations, which enhances dissociation hydrogen source substrate interaction with surface catalyst, thereby selective quinoline 1,2,3,4‐tetrahydroquinoline. proposed protocol quinoline, formic acid utilized bio‐renewable source, serves replacement molecular hydrogen. Further, optimization studies are carried out achieve good selectivity product yield varying reaction parameters. Therefore, using mechanistic studies, supported on P‐GCN) provides

Language: Английский

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Feasibility Study of Amadori Rearrangement Products of Glycine, Diglycine, Triglycine, and Glucose as Potential Food Additives for Production, Stability, and Flavor Formation

Journal of Agricultural and Food Chemistry, Journal Year: 2023, Volume and Issue: 72(1), P. 657 - 669

Published: Dec. 18, 2023

Amadori rearrangement products (ARPs), as intermediates of the Maillard reaction (MR), are potential natural flavor additives but there is a lack investigation especially in oligopeptide-ARPs. This study for first time conducted systematic analysis comparing ARPs glycine, diglycine, triglycine, and glucose to corresponding classic MR systems, including production, stability, analysis. The were effectively produced by prelyophilization with heating at 70 °C 60 min purified 96% two-step purification method. Correlated stability order amino compounds (glycine > diglycine triglycine), was Gly-ARP Digly-ARP ≈ Trigly-ARP. In negative correlation temperature time, less stable than original high temperatures (100, 130, 160 °C). exhibited better formation ability pyrazines furans similar compositions different preferences. Diglycine- triglycine-ARPs efficiency glycine-ARP. Heating initial pH, carbon chain length found be parameters that affect ARPs. suggested ARPs, peptide-ARPs, have great usage food future.

Language: Английский

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Enhanced furfural extraction using neoteric hydrophobic solvents for sustainable biomass recovery and bioenergy applications

Bioresource Technology, Journal Year: 2024, Volume and Issue: 413, P. 131535 - 131535

Published: Sept. 24, 2024

Language: Английский

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Highly efficient selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over MOF-derived Co-Ni bimetallic catalysts: The effects of Co-Ni alloy and adsorption configuration

Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115824 - 115824

Published: Oct. 1, 2024

Language: Английский

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