Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 28, 2024
Language: Английский
Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 28, 2024
Language: Английский
Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The latest advancements in MOF-based three-dimensional macrostructures, encompassing fascinating characteristics, preparation strategies, characterization methods, and environmental applications, are examined.
Language: Английский
Citations
2Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(24), P. 10021 - 10027
Published: June 6, 2024
Although oxygen reduction reaction (ORR) as an effective signal amplification strategy has been extensively investigated for the improvement of sensitivity electrochemical sensors, their activity and stability are still a great challenge. Herein, single-atom Fe (FeSA) nanoparticles (FeNP) on nitrogen-doped carbon (FeSA/FeNP) catalysts demonstrate highly active stable ORR performance, thus achieving sensitive sensing organophosphorus pesticides (OPs). Experimental investigations indicate that FeNP in FeSA/FeNP can improve by adjusting electronic structure FeSA sites. Besides, owing to excellent catalase-like activity, rapidly consume situ generated H2O2 process avoid leakage sites, thereby improving ORR. Utilizing performance FeSA/FeNP, sensor OPs is established based thiocholine-induced poison demonstrating satisfactory stability. This work provides new insight into design high sensing.
Language: Английский
Citations
6International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: unknown, P. 137945 - 137945
Published: Nov. 1, 2024
Language: Английский
Citations
5Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 403, P. 124858 - 124858
Published: April 30, 2024
Language: Английский
Citations
4Applied Sciences, Journal Year: 2025, Volume and Issue: 15(4), P. 2085 - 2085
Published: Feb. 17, 2025
The aim of this study was to develop an innovative material by combining the properties magnetic biochar derived from orange peels and hydrogel beads (BCA-Mag/AB) apply for adsorption methylene blue dye in water. BCA-Mag/AB were synthesized using physical crosslinking methods characterized various techniques. surface functional groups analyzed FTIR, crystal structure examined through XRD, area determined BET, pore distribution assessed via BJH, thermal stability evaluated with TGA, morphology investigated SEM, element percentages EDX. specific obtained nitrogen found be 455.4 m2/g, total volume 0.268 cm3/g. removal on concerning three variables Box–Behnken Design (BBD) as follows: A: dosage (0.02–0.1 g); B: contact time (20–150 min); C: initial pH (2–10). Adsorption kinetic isotherm analyses indicated that onto governed pseudo-first-order Freundlich models. mechanisms associated electrostatic interaction, hydrophobic π-π stacking. results suggest could effective locally available candidate adsorbent pollutants contaminated industrial wastewater.
Language: Английский
Citations
0Chemical Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Palladium (Pd), a rare and precious metal, is highly valued due to its non-renewable nature significant cost. Therefore, recovering palladium from industrial wastewater of great importance but remains challenge. Herein, composite aerogel adsorbent has been developed by linking bipyridine covalent organic framework, termed TpBpy, with chitosan (CS) through robust bonds. The resulting TpBpy/CS employed for the selective separation recovery at low concentrations in real wastewater. Experimental results reveal that maximum adsorption capacity Pd(ii) 274.4 mg g-1 pH 1. Additionally, even presence other coexisting ions 100 times higher than Pd(ii), efficiency above 99%. Mechanistic investigations indicate aerogels primarily occurs coordination between pyridine N as well electrostatic interaction protonated amino groups Pd(ii). Moreover, demonstrates exceptional reusability, maintaining an 99% after nine adsorption-desorption cycles. Overall, promising monolithic efficient acidic selectivity, demonstrating substantial potential practical applications.
Language: Английский
Citations
0The Science of The Total Environment, Journal Year: 2025, Volume and Issue: 972, P. 179096 - 179096
Published: March 14, 2025
Language: Английский
Citations
0Gels, Journal Year: 2025, Volume and Issue: 11(4), P. 224 - 224
Published: March 21, 2025
This study utilized the Schiff base reaction as a chemical bonding method to successfully graft 2-aminopyridine onto oxidized sodium alginate, resulting in formation of modified alginate (OSM). Subsequently, OSM/polyacrylic acid (OSM/PAA) hydrogel was synthesized via thermally initiated free radical polymerization process and evaluated an adsorbent for removal heavy metal ions from wastewater. Comprehensive characterization prepared samples performed using FT-IR, SEM, TGA. The influence temperature, pH, dosage, contact time, ion concentration on adsorption capacity OSM/PAA simulated wastewater thoroughly investigated. Additionally, detailed analysis thermodynamics, kinetics, mechanisms conducted. Experimental results indicated that at 25 °C, pH 5.0, dosage 0.4 g/L, maximum capacities Cu(II), Zn(II), Ni(II) were 367.64 mg/g, 398.4 409.83 respectively. These findings suggest by is spontaneous, heterogeneous with significant potential practical applications treatment.
Language: Английский
Citations
0Journal of Environmental Management, Journal Year: 2025, Volume and Issue: 380, P. 125122 - 125122
Published: March 26, 2025
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: March 31, 2025
Language: Английский
Citations
0