ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(44), P. 59962 - 59978
Published: Oct. 25, 2024
The
development
of
novel,
safe,
and
efficient
pest
disease
control
technologies
for
agricultural
crops
remains
a
pivotal
area
research.
In
this
study,
by
combining
ZIF-8
ZIF-90,
water-stable,
pH-responsive
bilayer
MOF
nanoparticle
(NP)
named
Z8@Z90
was
created,
tebuconazole
(TEB)
added
to
form
T@Z8@Z90,
used
controlling
peanut
southern
blight.
loading
efficiency
TEB
within
the
T@Z8@Z90
reached
26.15%,
enabling
rapid
release
in
acidic
environments
triggered
oxalic
acid
(OA)
secreted
Sclerotium
rolfsii.
vitro
experiments
showed
that
can
regulate
secretion
S.
rolfsii
destroy
its
cell
membrane
structure.
Additional
revealed
reduced
sclerotial
formation,
decreased
total
protein
content
sclerotia,
influenced
their
sensitivity
pesticides,
thereby
mitigating
risk
reinfection
Notably,
exhibited
translocation
seedlings,
being
absorbed
through
roots
transported
leaves.
At
concentration
200
mg/L,
high
safety
profiles
seedling
growth
compared
suspension.
Moreover,
is
safer
earthworms
than
SC.
Overall,
study
offers
valuable
insights
management
soil-borne
diseases
agriculture
contributes
advancement
sustainable
practices.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(13), P. 9486 - 9499
Published: March 18, 2024
Agrichemical
losses
are
a
severe
threat
to
the
ecological
environment.
Additionally,
some
agrichemical
compounds
contain
abundant
salt,
which
increases
instability
of
formulations,
leading
lower
utilization
and
soil
hardening.
Fortunately,
biological
amphiphilic
emulsifier
sodium
deoxycholate
alleviates
these
problems
by
forming
stable
Janus
core–shell
emulsions
through
salinity-driven
interfacial
self-assembly.
According
behavior,
dilational
rheology,
molecular
dynamics
simulations,
Janus-emulsion
molecules
more
closely
arranged
than
traditional-emulsion
generate
an
oil–water
film
that
transforms
into
gel
film.
In
addition,
at
same
spray
volume,
deposition
area
emulsion
increased
37.70%
compared
with
traditional
emulsion.
Owing
topology
effect
deformation,
adheres
rice
micropapillae,
achieving
better
flush
resistance.
Meanwhile,
based
on
response
stimulation
carbon
dioxide
(CO2),
lost
can
form
rigid
shell
for
inhibiting
release
pesticides
metal
ions
from
harming
soil.
The
pyraclostrobin
rate
decreased
50.89%
4
h
after
was
exposed
CO2.
Chao1
index
12.49%
as
coconut
oil
delivery
in
microbial
community.
ingested
harmful
organisms
be
effectively
absorbed
intestine
achieve
control
effects.
This
study
provides
simple
effective
strategy,
turns
waste
treasure,
combining
agrichemicals
natural
prepare
enhancing
rainfastness
weakening
environmental
risk.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(21), P. 13781 - 13793
Published: May 16, 2024
Pine
wood
nematode
(PWN)
disease
is
a
globally
devastating
forest
caused
by
infestation
with
PWN,
Bursaphelenchus
xylophilus,
which
mainly
occurs
through
the
vector
insect
Japanese
pine
sawyer
(JPS),
Monochamus
alternatus.
PWN
notoriously
difficult
to
manage
effectively
and
known
as
"cancer
of
trees."
In
this
study,
dual
enzyme-responsive
nanopesticides
(AVM@EC@Pectin)
were
prepared
using
nanocoating
avermectin
(AVM)
after
modification
natural
polymers.
The
proposed
treatment
can
respond
cell
wall-degrading
enzymes
secreted
PWNs
insects
during
tree
intelligently
release
pesticides
cut
off
transmission
pathways
realize
integrated
control
disease.
LC50
value
AVM@EC@Pectin
was
11.19
mg/L
for
26.31
JPS.
insecticidal
activity
higher
than
that
commercial
emulsifiable
concentrate
(AVM-EC),
photostability,
adhesion,
target
penetration
improved.
half-life
(t1/2)
133.7
min,
approximately
twice
AVM-EC
(68.2
min).
Sprayed
injected
applications
showed
had
superior
bidirectional
transportation,
five-times
AVM
contents
detected
in
roots
relative
those
when
sprayed
at
top.
safety
experiment
lower
toxicity
nontarget
organisms
application
environment
human
cells.
This
study
presents
green,
safe,
effective
strategy
management
Journal of Agricultural and Food Chemistry,
Journal Year:
2024,
Volume and Issue:
72(20), P. 11295 - 11307
Published: May 8, 2024
The
advancement
of
science
and
technology,
coupled
with
the
growing
environmental
consciousness
among
individuals,
has
led
to
a
shift
in
pesticide
development
from
traditional
methods
characterized
by
inefficiency
misuse
toward
more
sustainable
eco-friendly
approach.
Cellulose,
as
most
abundant
natural
renewable
resource,
opened
up
new
avenue
field
biobased
drug
carriers
developing
cellulose-based
delivery
systems.
These
systems
offer
unique
advantages
terms
deposition
rate
enhancement,
modification
facilitation,
impact
reduction
when
designing
nanopesticides.
Consequently,
their
application
nanoscale
pesticides
gained
widespread
recognition.
present
study
provides
comprehensive
review
cellulose
methods,
carrier
types
for
nanopesticides
(CPDS),
various
stimulus-response
factors
influencing
release.
Additionally,
main
challenges
design
CPDS
are
summarized,
highlighting
immense
potential
materials
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 28, 2025
Abstract
The
development
of
multi‐action
pesticides
presents
significant
advantages,
including
cost‐effectiveness,
reduced
application
frequency,
enhanced
resistance
management,
and
minimized
environmental
impact.
Despite
its
efficacy
in
targeting
chitin
synthase
both
fungi
insects,
the
insecticidal
performance
polyoxin
B
remains
limited.
To
overcome
this
limitation,
a
novel
nano‐formulation,
B@ZTS
is
developed,
utilizing
agricultural
byproducts,
tea
saponin,
zein.
This
formulation
features
small
particle
size,
high
leaf
deposition
efficiency,
excellent
dispersion
properties.
Leveraging
disulfide
bond
system,
designed
to
respond
intracellular
reducing
environment,
enabling
controlled
release
B.
Remarkably,
nano‐formulation
facilitates
penetration
physiological
barriers,
achieving
equivalent
fungicidal
at
only
one‐fifth
dosage.
work
highlights
potential
eco‐friendly,
cost‐effective,
multifunctional
nano‐pesticides,
providing
compelling
solution
for
sustainable
practices
demonstrating
broad
applicability
integrated
pest
disease
management.
Bacterial
infections
pose
a
significant
threat
to
human
health
and
economic
stability.
The
overuse
of
antibiotics
has
exacerbated
bacterial
resistance,
highlighting
the
urgent
need
for
innovative
strategies
combat
this
issue.
Bacteria-responsive
drug
delivery
systems
present
promising
solution
overcoming
resistance.
Metal-organic
frameworks
(MOFs),
versatile
porous
materials
created
by
linking
metal
clusters
with
organic
ligands,
are
ideal
candidates
such
applications.
Here,
we
employed
zeolite
imidazole
framework
8
(ZIF-8)
as
carrier
ceftiofur
(EFT),
enhanced
carboxymethyl
cellulose
develop
smart
system
(CMC-EFT@ZIF-8)
responsive
pH
cellulase.
In
vitro
tests
demonstrated
that
released
higher
quantity
EFT
under
acidic
conditions
in
presence
cellulase,
leading
more
effective
disruption
membranes
subsequent
death.
CMC-EFT@ZIF-8
achieved
99%
clearance
Pseudomonas
aeruginosa
within
6
h
showed
superior
efficacy
mouse
skin
wound
model.
These
findings
underscore
potential
our
significantly
improve
treatment
outcomes
infections,
representing
advancement
fight
against
antibiotic
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 1, 2024
The
development
of
smart
systems
for
pesticidal
delivery
presents
a
significant
advancement
in
enhancing
the
utilization
efficiency
pesticides
and
mitigating
environmental
risks.
Here
an
acid-responsive
system
using
microspheres
formed
by
self-assembly
halloysite
clay
nanotubes
(HNTs)
is
proposed.
Insecticide
avermectin
(AVM)
herbicide
prometryn
(PMT)
are
used
as
two
models
hydrophobic
pesticide
encapsulated
within
porous
microspheres,
followed
coating
tannic
acid/iron
(TA/Fe