Optics & Laser Technology, Journal Year: 2024, Volume and Issue: 180, P. 111450 - 111450
Published: July 16, 2024
Language: Английский
Optics & Laser Technology, Journal Year: 2024, Volume and Issue: 180, P. 111450 - 111450
Published: July 16, 2024
Language: Английский
Materials & Design, Journal Year: 2024, Volume and Issue: 241, P. 112906 - 112906
Published: April 1, 2024
Fluorescent temperature measurement has become a research hotspot due to its characteristics of non-contact, miniaturization, and fast response. However, it remains key challenge realize excellent sensitivity high resolution. Herein, series La2MgTiO6:Dy3+,Mn4+ phosphors are developed the related energy transfer between Dy3+→Mn4+ is discovered. The coupling distance Mn4+ adjacent ligands greatly affected by temperature. differences emission levels lower Dy3+ hinder multi-phonon relaxation process, which moderates thermal quenching rate Dy3+. Therefore, highly sensitive FIR thermometers built according significant discrimination dependence Mn4+. maximum Sa Sr reach 0.022 K−1(@563 K) 2.622 %K−1(@544 K). In contrast, thermometer based on lifetime fabricated, extremely Interestingly, can effectively promote Mn4+, then improve sensitivity. enhanced from 1.621 %K−1(@503 2.305 %K−1 (@480 resolution dual-mode fluorescence thermometry have exceeded most current optical materials. Besides, thermochromic properties presented designed be combined with PDMS films qualitatively evaluate ambient
Language: Английский
Citations
18Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: 169, P. 113138 - 113138
Published: Sept. 10, 2024
Language: Английский
Citations
16Laser & Photonics Review, Journal Year: 2024, Volume and Issue: 18(11)
Published: July 5, 2024
Abstract Traditional anti‐counterfeiting luminescent phosphors are usually composed of single‐mode photoluminescence materials, which greatly limits the security encryption by its static fluorescent pattern. Herein, multi‐mode luminescence properties achieved including fluorescence and persistent (PersL) within single host co‐doping Bi 3+ Eu in CaNaSb 2 O 6 F (CNSOF). A tunable emission is observed from blue (Bi , 3 P 1 → S 0 ) to white then orange‐yellow (Eu 5 D 7 0, 1, 2, 3, 4 as excitation schemes, environment temperatures doping level modulated. Impressively, attributed rapidly disappears after stopping light irradiation, only intense PersL produced can be observed. And a possible model for energy transfer mechanism proposed investigation crystal structure photoluminescence/PersL. schematic logo digital information demonstrated using prepared samples, shows dynamic evolution color brightness. The excellent property multiple outputs, different decay processes, external field stimulation modes (including low light, thermal, mechanical stimuli) present CNSOF:Bi provides fast, low‐cost, effective method advanced applications.
Language: Английский
Citations
9ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 14, 2025
Constructing multifunctional phosphors grounded in the intricate relationship between energy level structures and luminescent properties has captivated researchers material field. Herein, using embedded cluster multiconfigurational ab initio method, levels of Bi3+ SrLaGa3O7 host at different geometries were calculated, which results establishment complete configurational coordinate curves, yielding breathing mode vibrational frequencies equilibrium bond lengths for all excited states. These curves supply deep insight into luminescence Bi3+-doped highlight impact ions second coordination sphere on luminescence. Inspired by calculated results, we designed SrLaGa3(1–x)O7−δ:0.01 with Ga3+ reductions. The artificially introduced gallium vacancy perturbed luminescence, as verified systematic experimental analysis, causes to exhibit a novel greenish-yellow emission band addition original blue band, leading excitation-wavelength-dependent multicolor phosphors. obtained phosphor displayed fluorescent anticounterfeiting function, switching system was merits direct visualization easy identification encrypted information. Additionally, white light-emitting diodes fabricated employing prepared UV chips. indicate that SrLaGa3(1-x)O7-δ:0.01 significant potential both lighting applications. Our study demonstrates necessity considering two spheres ligands when interpreting illustrates effectiveness spectral design under theoretical guidance, providing feasible path development
Language: Английский
Citations
1Journal of Solid State Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 125281 - 125281
Published: Feb. 1, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161129 - 161129
Published: Feb. 1, 2025
Language: Английский
Citations
1Journal of Advanced Ceramics, Journal Year: 2024, Volume and Issue: 13(6), P. 821 - 833
Published: April 24, 2024
Language: Английский
Citations
7Journal of Luminescence, Journal Year: 2024, Volume and Issue: 276, P. 120853 - 120853
Published: Aug. 17, 2024
Language: Английский
Citations
7Progress in Solid State Chemistry, Journal Year: 2024, Volume and Issue: 75, P. 100477 - 100477
Published: Aug. 30, 2024
Language: Английский
Citations
5Ceramics International, Journal Year: 2024, Volume and Issue: 50(20), P. 39175 - 39185
Published: July 20, 2024
Language: Английский
Citations
4