Nano-Micro Letters,
Journal Year:
2024,
Volume and Issue:
16(1)
Published: Jan. 16, 2024
Abstract
The
insufficient
active
sites
and
slow
interfacial
charge
transfer
of
photocatalysts
restrict
the
efficiency
CO
2
photoreduction.
synchronized
modulation
above
key
issues
is
demanding
challenging.
Herein,
strain-induced
strategy
developed
to
construct
Bi–O-bonded
interface
in
Cu
porphyrin-based
monoatomic
layer
(PML-Cu)
Bi
12
O
17
Br
(BOB),
which
triggers
surface
dual
polarization
PML-Cu/BOB
(PBOB).
In
this
multi-step
polarization,
built-in
electric
field
formed
between
interfaces
induces
electron
from
conduction
band
(CB)
BOB
CB
PML-Cu
suppresses
its
reverse
migration.
Moreover,
further
promotes
converge
atoms.
introduction
endows
a
high
density
dispersed
on
PBOB,
significantly
promoting
adsorption
activation
desorption.
conversion
rate
photoreduction
for
PBOB
can
reach
584.3
μmol
g
−1
,
7.83
times
higher
than
20.01
PML-Cu.
This
work
offers
valuable
insights
into
regulation
site
design
catalysts.
Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
123(11), P. 6891 - 6952
Published: May 3, 2023
All
forms
of
energy
follow
the
law
conservation
energy,
by
which
they
can
be
neither
created
nor
destroyed.
Light-to-heat
conversion
as
a
traditional
yet
constantly
evolving
means
converting
light
into
thermal
has
been
enduring
appeal
to
researchers
and
public.
With
continuous
development
advanced
nanotechnologies,
variety
photothermal
nanomaterials
have
endowed
with
excellent
harvesting
capabilities
for
exploring
fascinating
prospective
applications.
Herein
we
review
latest
progresses
on
nanomaterials,
focus
their
underlying
mechanisms
powerful
light-to-heat
converters.
We
present
an
extensive
catalogue
nanostructured
materials,
including
metallic/semiconductor
structures,
carbon
organic
polymers,
two-dimensional
materials.
The
proper
material
selection
rational
structural
design
improving
performance
are
then
discussed.
also
provide
representative
overview
techniques
probing
photothermally
generated
heat
at
nanoscale.
finally
recent
significant
developments
applications
give
brief
outlook
current
challenges
future
directions
nanomaterials.
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(15), P. 6307 - 6416
Published: Jan. 1, 2022
This
review
highlights
the
recent
advances
of
metalated
covalent
organic
frameworks,
including
synthetic
strategies
and
applications,
discusses
current
challenges
future
directions.
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(9), P. 3609 - 3647
Published: Jan. 1, 2022
This
review
provides
an
up-to-date
understanding
on
emerging
thermo-photo
catalytic
processes
with
emphasis
the
synergetic
effects
of
thermal
and
photo
energies.
ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(3), P. 1725 - 1738
Published: Feb. 3, 2023
Converting
carbon
dioxide
(CO2)
into
value-added
fuels
or
chemicals
through
photothermal
catalytic
CO2
hydrogenation
is
a
promising
approach
to
alleviate
the
energy
shortage
and
global
warming.
Understanding
nanostructured
material
strategies
in
process
vital
for
designing
devices
catalysts
maximizing
performance.
In
this
Perspective,
we
first
describe
several
essential
nanomaterial
design
concepts
enhance
sunlight
absorption
utilization
hydrogenation.
Subsequently,
review
latest
progress
C1
(e.g.,
CO,
CH4,
CH3OH)
multicarbon
hydrocarbon
(C2+)
products.
Finally,
relevant
challenges
opportunities
exciting
research
realm
are
discussed.
This
perspective
provides
comprehensive
understanding
light–heat
synergy
over
nanomaterials
instruction
rational
catalyst
utilization.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(41)
Published: Aug. 9, 2022
Abstract
Photocatalytic
reduction
of
CO
2
to
value‐added
liquid
fuels
is
a
promising
approach
alleviate
the
global
energy
and
environmental
problems.
However,
highly
selective
production
C2+
products
from
reaction
(CO
RR)
very
difficult
because
sluggish
CC
coupling
reaction.
An
asymmetric
coupled
heteronuclear
photocatalyst
designed
overcome
this
limitation.
The
new
catalyst
contains
single
atoms
nickel
cobalt
loaded
on
titanium
dioxide.
It
exhibits
an
impressive
71%
selectivity
for
acetic
acid.
experimental
data
theoretical
calculations
reveal
that
Ni
Co
atom
sites
not
only
significantly
lower
barrier
electron
transfer
in
photocatalysis
but
also
efficiently
promote
toward
CH
3
COOH.
high
activity
such
system
will
shed
light
future
development
effective
materials
RR.
Materials Today,
Journal Year:
2023,
Volume and Issue:
68, P. 234 - 253
Published: July 17, 2023
Photothermal
catalysis
is
an
innovative
approach
that
integrates
photochemical
and
thermocatalytic
processes
to
enable
efficient
use
of
full-spectrum
sunlight
in
catalyzing
various
chemical
reactions
for
energy
conversion
environmental
governance.
This
has
demonstrated
competitive
performance
efficiency
compared
conventional
techniques,
making
it
suitable
large-scale
applications.
In
this
review,
we
will
comprehensively
examine
the
fundamentals
classification
photothermal
discuss
detailed
design
principles
types
catalysts,
focusing
on
enhancing
solar
light
absorption,
improving
internal
electric
field
more
energetic
hot
carriers
(EHC)
localized
thermal
(LTE),
interfacial
engineering
robust
directed
EHC
transferring,
regulating
LTE
continuous
24/7
operation.
We
also
report
a
diverse
range
reactions.
Moreover,
introduce
latest
technologies
synthesizing
catalysts
advanced
concentrators
pilot
testing
production
fuels
at
scale.
Finally,
future
opportunities
challenges
promising
but
fledging
be
discussed,
which
expected
transform
industries
into
clean
sustainable
manner.
