Effect of Water Flow Intermittency on Organic Micropollutants Biodegradation Capacity of the Hyporheic Zone DOI
Maria Vittoria Barbieri, Oriane Della‐Negra, Dominique Patureau

et al.

Published: Jan. 1, 2023

A lab-scale study using column experiments was conducted to provide knowledge on the biodegradation capacity of river hyporheic zone under flow intermittency. River water contamination simulated a mixture six compounds including pesticides (chloranthraniliprole, fluopyram and trifloxystrobin) pharmaceuticals (venlafaxine, amisulpride paroxetine) spiked at 1 µg/L level for degradation kinetic studies mg/L transformation products identification suspect non-target liquid chromatography high-resolution mass spectrometry approaches. The results suggested that intermittent flows stimulated three namely fluopyram, trifloxystrobin venlafaxine, showing large range profiles in batch water/sediment testing system. Biodegradation rate enhancement ascribed occurrence additional routes after desiccation period sediment. 16S rDNA sequencing revealed favored growth nitrifying denitrifying bacteria which could partially explain emergence new pathways most specifically those leading N-oxide derivatives. Identification also reductive were relevant this study, being dehydrogenation, dehalogenation, ether bond cleavage sulfone reduction into sulphide important reactions.

Language: Английский

Partially saturated vertical surface flow constructed wetland for emerging contaminants and antibiotic resistance genes removal from wastewater: The effect of bioaugmentation with Trichoderma DOI Creative Commons
Đorđe Tadić, Andrés Sauvêtre, Francisco Cerqueira

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(2), P. 112128 - 112128

Published: Feb. 3, 2024

Language: Английский

Citations

5
Effect of intermittent water flow on biodegradation of organic micropollutants in the hyporheic zone DOI Creative Commons
Maria Vittoria Barbieri, Oriane Della‐Negra, Dominique Patureau

et al.

Chemosphere, Journal Year: 2025, Volume and Issue: 371, P. 144082 - 144082

Published: Jan. 8, 2025

Language: Английский

Citations

0
Relevance of photocatalytic redox transformations of selected pharmaceuticals in a copper- and iron-rich Mediterranean intermittent river DOI Creative Commons
Maria Vittoria Barbieri, Serge Chirón

Chemosphere, Journal Year: 2023, Volume and Issue: 339, P. 139762 - 139762

Published: Aug. 7, 2023

Language: Английский

Citations

3
In-stream attenuation and enantioselective fractionation of psychiatric pharmaceuticals in a wastewater effluent-dominated river basin DOI
Weimin Wang, Tian Xie,

Ning Ma

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 951, P. 175521 - 175521

Published: Aug. 13, 2024

Language: Английский

Citations

0
Partially Saturated Vertical Surface Flow Constructed Wetland for Emerging Contaminants and Antibiotic Resistance Genes Removal from Wastewater: The Effect of Bioaugmentation with <i>Trichoderma</i> Fungus DOI
Đorđe Tadić,

André Sauvetre,

Francisco Cerqueira

et al.

SSRN Electronic Journal, Journal Year: 2022, Volume and Issue: unknown

Published: Jan. 1, 2022

The removal of contaminants emerging concern and antibiotic resistance genes (ARGs) were investigated at pilot-scale with partially saturated vertical flow constructed wetland bioaugmented or not the Trichoderma asperellum T34 strain by means non-target liquid chromatography high-resolution mass spectrometry SmartChip™ Real-Time PCR methodological approaches. High variability in efficiency along a four-week experiment precluded to statically conclude that bioaugmentation was able significantly improve treatment performances for most CECs except diclofenac benzotriazole. Trichodermasp. grew fed secondary treated domestic wastewater but quick wash-out external secreted laccase peroxidase enzymes likely occurred. In contrast, there clear relationship between biodegradability as well sorption capacity identified compounds. As expected, biodegradation main driver accounting moderate when log Dow < 3. However, types reaction (hydrolysis vs oxidation reactions) key determinant rates rather substituents functional groups chemical structures leading different levels electronic steric hindrances. Sorption prevailed over only hydrophobic (log > 3) slowly biodegradable fate selected transformation products (TPs) could also be first time such treatments. formation persistence N-oxide TPs highlighted while which prone undergo further N-dealkylation hydroxylation partly eliminated. Noteworthy exception 14-hydroxyclarithromycin tended accumulate preserving an antimicrobial activity. Investigated treatments did reduce overall bacterial load flowing water. may have cause shift ARGs composition no statistical difference average rates.

Language: Английский

Citations

1
Effect of Water Flow Intermittency on Organic Micropollutants Biodegradation Capacity of the Hyporheic Zone DOI
Maria Vittoria Barbieri, Oriane Della‐Negra, Dominique Patureau

et al.

Published: Jan. 1, 2023

A lab-scale study using column experiments was conducted to provide knowledge on the biodegradation capacity of river hyporheic zone under flow intermittency. River water contamination simulated a mixture six compounds including pesticides (chloranthraniliprole, fluopyram and trifloxystrobin) pharmaceuticals (venlafaxine, amisulpride paroxetine) spiked at 1 µg/L level for degradation kinetic studies mg/L transformation products identification suspect non-target liquid chromatography high-resolution mass spectrometry approaches. The results suggested that intermittent flows stimulated three namely fluopyram, trifloxystrobin venlafaxine, showing large range profiles in batch water/sediment testing system. Biodegradation rate enhancement ascribed occurrence additional routes after desiccation period sediment. 16S rDNA sequencing revealed favored growth nitrifying denitrifying bacteria which could partially explain emergence new pathways most specifically those leading N-oxide derivatives. Identification also reductive were relevant this study, being dehydrogenation, dehalogenation, ether bond cleavage sulfone reduction into sulphide important reactions.

Language: Английский

Citations

0