(Self) assembled news: recent highlights from the supramolecular chemistry literature (quarter 2, 2024) DOI
Cally J. E. Haynes, Nicholas G. White

Supramolecular chemistry, Journal Year: 2023, Volume and Issue: 34(9-10), P. 313 - 315

Published: Oct. 2, 2023

Language: Английский

Structural diversity in 1D hydrogen-bonded chains assembled through bis(triazole) self-association DOI
Jordan N. Smith, Nicholas G. White

CrystEngComm, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

We show that phenyl-bis(triazole) groups dimerise in solution. A ditopic receptor containing two motifs predictably self-associates through C–H⋯N hydrogen bonding to give crystalline tape structures.

Language: Английский

Citations

0
Computer-aided design of triazolo-cages as anion receptors DOI Creative Commons
Minwei Che, Sibali Debnath, Amar H. Flood

et al.

Physical Chemistry Chemical Physics, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Molecular cages with three-dimensional cavities have garnered significant interest due to their enhanced encapsulation abilities.

Language: Английский

Citations

0
Molecular Interaction of Water-Soluble Resorcinarenes for Potential Choline Detectors DOI Open Access

Cielo Urquijo,

Miguel Herguedas Vela,

R Néstor Sarmiento

et al.

Processes, Journal Year: 2025, Volume and Issue: 13(2), P. 553 - 553

Published: Feb. 16, 2025

The molecular interactions of water-soluble crown resorcinarenes with choline were analyzed. To this end, four sulfonated synthesized and characterized by ATR-IR, 1H-NMR, 13C-NMR spectroscopy. interaction studies carried out through FT-IR spectroscopy, 1H-NMR titrations, conductimetric which it was possible to determine that the complexes formed 1:1 stoichiometries host, in addition showing good electronic cavity macrocycle, demonstrating great potential for host–guest systems detection aqueous media. Finally, incidence structural aspects

Language: Английский

Citations

0
Proline-based tripodal cages with guest-adaptive features for capturing hydrophilic and amphiphilic fluoride substances DOI Creative Commons
Bo Huang, Sihao Li,

Cong Pan

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: April 4, 2025

Proteins exhibit remarkable molecular recognition by dynamically adjusting their conformations to selectively interact with ligands at specialized binding sites. To bind hydrated ligands, proteins leverage amino acid residues similar water affinities as the substrate, minimizing energy required strip molecules from hydrophilic substrates. In synthetic receptor design, replicating this sophisticated adaptability remains a challenge, most artificial receptors are optimized desolvated substances. Here, we show that proline-based can mimic conformational dynamics of achieve selective and amphiphilic fluoride substances in aqueous environments. This finding highlights critical role flexibility strategic hydrophilicity enhancing ligand affinity water. Moreover, it establishes new framework for designing versatile tunable hydrophobicity profiles.

Language: Английский

Citations

0
Capturing the perfluorobutane sulfonate by bambus[6], calix[6] and pillar[6] derivatives: Determination of stability constants by cellmetry method DOI
Mihály Purgel

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125473 - 125473

Published: July 9, 2024

Language: Английский

Citations

1
Synthetic transporters for oxoanions DOI
Karolis Norvaiša, Aarón Torres‐Huerta, Hennie Valkenier

et al.

Current Opinion in Chemical Biology, Journal Year: 2024, Volume and Issue: 83, P. 102542 - 102542

Published: Nov. 14, 2024

Language: Английский

Citations

1
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors DOI
Willow A. Davis, Darren W. Johnson

Chem, Journal Year: 2024, Volume and Issue: 10(6), P. 1635 - 1637

Published: June 1, 2024

Language: Английский

Citations

0
Transmembrane anion transport mediated by the well-designed electron-rich resorcin[4]arenes DOI

Yuxiao Mei,

Ziyang Guo,

Yue Sun

et al.

Matter, Journal Year: 2024, Volume and Issue: 7(8), P. 2761 - 2763

Published: Aug. 1, 2024

Language: Английский

Citations

0
Supramolecular blends of C-alkylpyrogallol[4]arenes and polytetrahydrofurans DOI Creative Commons

Oleg Andrew Kulikov,

Arshad Mehmood,

Sergey Vodzinsky

et al.

Results in Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 101804 - 101804

Published: Sept. 1, 2024

Language: Английский

Citations

0
HFIP as a versatile solvent in resorcin[n]arene synthesis DOI Creative Commons
Hormoz Khosravi,

Valeria Stevens,

Raúl Hernández Sánchez

et al.

Beilstein Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 20, P. 2469 - 2475

Published: Oct. 2, 2024

Herein, we present 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) as an efficient solvent for synthesizing resorcin[ n ]arenes in the presence of catalytic amounts HCl at ambient temperature and within minutes. Remarkably, resorcinols with electron-withdrawing groups halogens, which are reported literature most challenging precursors this cyclization, tolerated. This method leads to a variety 2-substituted single synthetic step isolated yields up 98%.

Language: Английский

Citations

0