Structures, magnetism, and oxygen evolution reaction (OER) of azidoisophthalate bridging Cu(II) and Co(II) coordination polymers DOI
Sabir Ahmed, Koushik Sarkar, Arnab Samanta

et al.

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 38(9)

Published: July 12, 2024

Two newly derived coordination polymers of Cu(II) and Co(II), namely {[Cu(μ‐5‐AzIA)(Py) 2 ]⋅[Cu(5‐AzIA)(Py) (H O)]} n ( CP1 ) {[Co(μ‐5‐AzIA) (Py) 4 ]⋅[Co(5‐AzIA)(Py) ]} CP2 5‐AzIA 2− = 5‐azidoisophthalate; Py pyridine) are synthesized structurally characterized by single‐crystal X‐ray diffraction (SXRD), powder (PXRD), Fourier transform infrared data. As evident from thermogravimetric data, loses coordinated water at 110°C the final residue reaches 530°C as CuO; is stable up to 150°C, 415°C Co O 3 . serves both chelating monodentate carboxylate bridging ligand adjacent metal centers in Co(II) construct CPs The form eight‐member carboxylato bridging, [M (RCOO) ], coordinate with rings assemblage through π‐‐‐π interaction. magnetic measurements show antiferromagnetic super‐exchange properties. Interestingly, shows field‐induced ordering a higher field temperature ̴ K owing π•••π stacking between flagging pyridine moieties. Oxygen evolution reaction (OER) excellent catalytic effectiveness than reference standard RuO catalyst. comparative activity was thoroughly investigated well supported Tafel slope, charge‐transfer resistance (Rct), electrochemically active surface area calculation.

Language: Английский

Recent advances in 3D printing of tough hydrogels: A review DOI
Xin Ning Zhang, Qiang Zheng, Zi Liang Wu

et al.

Composites Part B Engineering, Journal Year: 2022, Volume and Issue: 238, P. 109895 - 109895

Published: April 13, 2022

Language: Английский

Citations

136

Research progress of advanced microneedle drug delivery system and its application in biomedicine DOI
Rui Zhang, Qing Miao, Dan Deng

et al.

Colloids and Surfaces B Biointerfaces, Journal Year: 2023, Volume and Issue: 226, P. 113302 - 113302

Published: April 8, 2023

Language: Английский

Citations

42

Metal‐Organic Frameworks (MOFs): Classification, Synthesis, Modification, and Biomedical Applications DOI
Dayang Wang,

Huanchen Yao,

Jiashuo Ye

et al.

Small, Journal Year: 2024, Volume and Issue: 20(47)

Published: Aug. 16, 2024

Abstract Metal‐organic frameworks (MOFs) are a new variety of solid crystalline porous functional materials. As an extension inorganic materials, it has made important progress in preparation and application. MOFs widely used various fields such as gas adsorption storage, drug delivery, sensing, biological imaging due to their high specific surface area, porosity, adjustable pore size, abundant active sites, modification by introducing groups. In this paper, the types classified, synthesis methods mechanisms materials summarized. Finally, application prospects challenges metal‐organic framework biomedical field discussed, hoping promote multidisciplinary fields.

Language: Английский

Citations

20

Magneto‐Orientation of Magnetic Double Stacks for Patterned Anisotropic Hydrogels with Multiple Responses and Modulable Motions DOI
Chen Fei Dai,

Olena Khoruzhenko,

Chengqian Zhang

et al.

Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(35)

Published: June 24, 2022

Reported here is a multi-response anisotropic poly(N-isopropylacrylamide) hydrogel developed by using rotating magnetic field to align double stacks (MDSs) that are fixed polymerization. The magneto-orientation of MDSs originates from the unique structure with γ-Fe

Language: Английский

Citations

57

Recent developments, challenges and future prospects of magnetic field effects in supercapacitors DOI

K. A. Sree Raj,

Chandra Sekhar Rout

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(11), P. 5495 - 5519

Published: Jan. 1, 2023

This review article covers the scientific discussion on some of recent advancements in magnetic field controlled effects supercapacitors and analyzes these detail based their energy storage mechanisms.

Language: Английский

Citations

39

Smart biomaterials in healthcare: Breakthroughs in tissue engineering, immunomodulation, patient-specific therapies, and biosensor applications DOI Creative Commons
Ansheed Raheem, Kalpana Mandal, Swarup Biswas

et al.

Applied Physics Reviews, Journal Year: 2025, Volume and Issue: 12(1)

Published: March 1, 2025

Smart biomaterials have significantly impacted human healthcare by advancing the development of medical devices designed to function within tissue, mimicking behavior natural tissues. While intelligence has evolved from inert active over past few decades, smart take this a step further making their surfaces or bulk respond based on interactions with surrounding tissues, imparting outcomes similar tissue functions. This interaction helps in creating stimuli-responsive biomaterials, which can be useful engineering, regenerative medicine, autonomous drug delivery, orthopedics, and much more. Traditionally, material engineering focused refining static properties accommodate them body without evoking an immune response, was major obstacle unrestricted operation. review highlights explains various approaches currently under research for developing that tune responses bodily factors like temperature, pH, ion concentration external magnetism, light, conductivity. Applications soft hard 4D printing, scaffold design are also discussed. The advanced application microfluidics, organ-on-a-chip models, extensively benefits intrinsic discussed below. elaborates how biomaterial could revolutionize biosensor applications, thereby improving patient care quality. We delineate limitations key challenges associated providing insights into path forward outlining future directions next-generation will facilitate clinical translation.

Language: Английский

Citations

1

Static magnetic fields as a factor in modification of tissue and cell structure: a review DOI Creative Commons
Bogdan Saletnik, Anna Puchalska-Sarna, Aneta Saletnik

et al.

International Agrophysics, Journal Year: 2024, Volume and Issue: 38(1), P. 43 - 75

Published: Jan. 11, 2024

1. Abdolmaleki P., Ghanati F., Sahebjamei H., and Sarvestani A.S., 2007. Peroxidase activity, lignification promotion of cell death in tobacco cells exposed to static magnetic field. Environmentalist, 27, 435-440. https://doi.org/10.1007/s10669.... CrossRef Google Scholar

Language: Английский

Citations

6

Natural micropatterned fish scales combing direct osteogenesis and osteoimmunomodulatory functions for enhancing bone regeneration DOI
Di Qin,

Xin-Guo You,

Haonan Wang

et al.

Composites Part B Engineering, Journal Year: 2023, Volume and Issue: 255, P. 110620 - 110620

Published: Feb. 14, 2023

Language: Английский

Citations

15

Magnetically anisotropic hydrogels for tissue engineering DOI
Lili Hao, Hongli Mao

Biomaterials Science, Journal Year: 2023, Volume and Issue: 11(19), P. 6384 - 6402

Published: Jan. 1, 2023

The magnetically anisotropic structure confers unique properties and promising application prospects to hydrogels in tissue engineering.

Language: Английский

Citations

14

Biosensors and Drug Delivery in Oncotheranostics Using Inorganic Synthetic and Biogenic Magnetic Nanoparticles DOI Creative Commons
Tatiana M. Zimina, Nikita O. Sitkov, Kamil G. Gareev

et al.

Biosensors, Journal Year: 2022, Volume and Issue: 12(10), P. 789 - 789

Published: Sept. 25, 2022

Magnetic nanocarriers have attracted attention in translational oncology due to their ability be employed both for tumor diagnostics and therapy. This review summarizes data on applications of synthetic biogenic magnetic nanoparticles (MNPs) oncological theranostics related areas. The basics types MNPs including synthesis approaches, structure, physicochemical properties are discussed. compared with regard antitumor therapeutic efficiency, diagnostic potential, biocompatibility, cellular toxicity. comparative analysis demonstrates that could efficiently used cancer theranostics, biosensorics drug delivery. At the same time, reduced toxicity particles was noted, which makes them advantageous vivo applications, such as delivery, or MRI imaging tumors. Adaptability surface modification based natural biochemical processes is also well good compatibility cells proliferation them. Advances bionanotechnology field should lead implementation clinical trials.

Language: Английский

Citations

21