Ozonation Processes for Color Removal from Urban and Leather Tanning Wastewater DOI Open Access
Anna Lanzetta, Stefano Papirio, Armando Oliva

et al.

Water, Journal Year: 2023, Volume and Issue: 15(13), P. 2362 - 2362

Published: June 27, 2023

The need to ensure adequate levels of both human and environmental health protection calls for the identification efficient wastewater treatment processes that target removal conventional pollutants as well emerging contaminants, including synthetic dyes. This study explores potential ozone use in decolorization pretreated tannery urban effluents. Different contact times (15, 30, 45 min) were applied such samples at an uncontrolled (7.5–8.2) pH a adjusted 10. highest color efficiencies (REs) (>90%) obtained with after min time Under same conditions, COD RE from 31 51% was achieved. Even without adjustment, REs ranging 81 92% 39 41%, respectively, obtained. A preliminary evaluation costs associated implementation ozonation stage within plant (WWTP) generating used here carried out. energy cost would account 69% increase total WWTP, suggesting identify proper strategies enhance cost-competitiveness this technology.

Language: Английский

Direct pesticide exposure of insects in nature conservation areas in Germany DOI Creative Commons
Carsten A. Brühl, Nikita Bakanov,

Sebastian Köthe

et al.

Scientific Reports, Journal Year: 2021, Volume and Issue: 11(1)

Published: Dec. 16, 2021

Abstract In Germany, the decline of insect biomass was observed in nature conservation areas agricultural landscapes. One main causal factors discussed is use synthetic pesticides conventional agriculture. a Germany-wide field study, we collected flying insects using Malaise traps adjacent to land. We used multi-component chemical trace element analysis detect 92 common ethanol from sampled May and August 2020. total, residues 47 current were detected, samples on average contaminated with 16.7 pesticides. Residues herbicides metolachlor-S, prosulfocarb terbuthylazine, fungicides azoxystrobin fluopyram recorded at all sites. The neonicotinoid thiacloprid detected 16 21 areas, most likely due final before an EU-wide ban. A change residue mixture composition noticeable higher herbicide spring increasing fungicide applications summer. number substances related proportion production area radius 2000 m. Therefore, drastic pesticide reduction large buffers around necessary avoid contamination their fauna.

Language: Английский

Citations

112

River ecological status is shaped by agricultural land use intensity across Europe DOI Creative Commons
Christian Schürings, Lidija Globevnik,

Jan U. Lemm

et al.

Water Research, Journal Year: 2024, Volume and Issue: 251, P. 121136 - 121136

Published: Jan. 21, 2024

Agriculture impacts the ecological status of freshwaters through multiple pressures such as diffuse pollution, water abstraction, and hydromorphological alteration, strongly impairing riverine biodiversity. The agricultural effects, however, likely differ between types practices. In Europe, show distinct spatial patterns related to intensity, biophysical conditions, socioeconomic history, which have been operationalised by various landscape typologies. Our study aimed at analysing whether incorporating intensity enhances correlation land use status. For this, we aggregated continent's activities into 20 Areas Farming-induced Freshwater Pressures (AFFP), specifying individual pressure profiles regarding nutrient enrichment, pesticides, in riparian zone establish an index this river Using index, nearly doubled correlative strength agriculture rivers compared share sub-catchment (based on analysis more than 50,000 units). Strongest were found for high cropland Mediterranean Temperate regions, while extensive grassland, fallow farmland livestock farming Northern Highland well low mosaic farming, featured lowest pressures. results provide advice pan-European management freshwater ecosystems highlight urgent need sustainable agriculture. Consequently, they can also be used a basis European Union-wide global policies halt biodiversity decline, post-2027 renewal Common Agricultural Policy.

Language: Английский

Citations

21

Multi-decadal improvements in the ecological quality of European rivers are not consistently reflected in biodiversity metrics DOI
James S. Sinclair, Ellen A. R. Welti, Florian Altermatt

et al.

Nature Ecology & Evolution, Journal Year: 2024, Volume and Issue: 8(3), P. 430 - 441

Published: Jan. 26, 2024

Language: Английский

Citations

20

Assessing pesticide residues occurrence and risks in water systems: A Pan-European and Argentina perspective DOI Creative Commons
Irene Navarro, Adrián de la Torre, Paloma Sanz

et al.

Water Research, Journal Year: 2024, Volume and Issue: 254, P. 121419 - 121419

Published: March 7, 2024

Freshwater ecosystems face a particularly high risk of biodiversity loss compared to marine and terrestrial systems. The use pesticides in agricultural fields is recognized as relevant stressor for freshwater environments, exerting negative impact worldwide on the overall status health communities. In present work, part Horizon 2020 funded SPRINT project, occurrence 193 pesticide residues was investigated 64 small water bodies distinct typology (creeks, streams, channels, ditches, rivers, lakes, ponds reservoirs), located regions with activity 10 European countries Argentina. Mixtures were detected all (20, median; 8-40 min-max). Total levels found ranged between 6.89 5860 ng/L, highlighting herbicides dominant type pesticides. Glyphosate compound highest median concentration followed by 2,4-D MCPA, lower degree dimethomorph, fluopicolide, prothioconazole metolachlor(-S). Argentina site total Netherlands, Portugal France. One or more exceeded threshold values established Water Framework Directive surface 9 out 11 case study sites (CSS), surpassed reference value 500 ng/L 8 CSS. Although only 5% (bifenthrin, dieldrin, fipronil sulfone, permethrin, terbutryn) individual denoted (RQ > 1), ratios estimated mixtures suggested potential environmental aquatic compartment studied.

Language: Английский

Citations

18

A review of modeling pesticides in freshwaters: Current status, progress achieved and desirable improvements. DOI Creative Commons
Marco Centanni, Giovanni Francesco Ricci, Anna Maria De Girolamo

et al.

Environmental Pollution, Journal Year: 2022, Volume and Issue: 316, P. 120553 - 120553

Published: Nov. 5, 2022

This study comprises a critical review of modeling pesticides in surface waters. The aim was to update the status use models simulate fate from diffuse sources. ISI papers were selected on Scopus and information concerning areas, type (herbicides, fungicides insecticides), model, methodology adopted (i.e., calibration and/or validation, spatial temporal scales) analyzed. studies carried out Europe (55.5%), North America (22.3%), Asia (13.9%) South (8.3%). Soil Water Assessment Tool proved be most used model (45.95%). Herbicides modeled (71.4%), followed by insecticides (18.2%) (10.4%). main herbicides atrazine, metolachlor, isoproturon, glyphosate, acetochlor. Insecticides such as chlorpyrifos metaldehyde. Chlorothalonil, tebuconazole) widely investigated. Based published studies, it found that approaches for assessing are constantly evolving algorithms work well with diverse watershed conditions, management strategies, pesticide properties. Several reported concentrations exceeding ecotoxicological thresholds revealing water contamination agriculture urban areas is priority issue current global concern.

Language: Английский

Citations

39

Water pollution threats in important bird and biodiversity areas from Spain DOI Creative Commons
Maria Dulsat‐Masvidal, Carlos Ciudad,

Octavio Infante

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 448, P. 130938 - 130938

Published: Feb. 2, 2023

Chemical pollution is still an underestimated threat to surface waters from natural areas. This study has analysed the presence and distribution of 59 organic micropollutants (OMPs) including pharmaceuticals, lifestyle compounds, pesticides, organophosphate esters (OPEs), benzophenone perfluoroalkyl substances (PFASs) in 411 water samples 140 Important Bird Biodiversity Areas (IBAs) Spain, evaluate impact these pollutants sites environmental relevance. Lifestyle pharmaceuticals OPEs were most ubiquitous chemical families, while pesticides PFASs showed a detection frequency below 25% samples. The mean concentrations detected ranged 0.1 301 ng/L. According spatial data, agricultural been identified as important source all OMPs compounds have related artificial wastewater treatment plants (WWTPs) discharges, which also waters. Fifteen out found at levels posing high risk for aquatic IBAs ecosystems, being insecticide chlorpyrifos, antidepressant venlafaxine perfluorooctanesulfonic acid (PFOS) concerning compounds. first quantify evidence that are emerging freshwater ecosystems essential biodiversity conservation.

Language: Английский

Citations

36

Pesticides at brain borders: Impact on the blood-brain barrier, neuroinflammation, and neurological risk trajectories DOI
Noémie Cresto,

Isabel Forner-Piquer,

Asma Baig

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 324, P. 138251 - 138251

Published: March 4, 2023

Language: Английский

Citations

35

Review: mountain lakes as freshwater resources at risk from chemical pollution DOI Creative Commons
Oliver Machate, Dirk S. Schmeller, Tobias Schulze

et al.

Environmental Sciences Europe, Journal Year: 2023, Volume and Issue: 35(1)

Published: Jan. 13, 2023

Abstract Background Chemical pollution forms a severe threat for human and environmental health. While the risks European lowland water bodies are well known, there is little knowledge on remote aquatic ecosystems particularly mountain lakes, despite their importance provision of freshwater. Here, we critically review current exposure risk by chemical lakes present tiered approach how to advance effectively our understanding in future. Results Generally, pollutant monitoring data currently incomplete, with many regions substances having been only poorly investigated. More reliable exist persistent organic pollutants (POPs). However, increasing evidence that even exposed wide range pollutants. Among them potent pesticides used agricultural biocidal applications, such as diazinon permethrin. The follows complex pattern. Pollutants introduced into via atmospheric deposition run-off from watershed, but also local sources, like tourism pastoralism. Our assessment recent biomonitoring studies suggest widespread chronic toxic crustacean ranges. If ranges pastoralism, acute effects possible. Thereby, vulnerability has be expected high due harsh conditions at altitudes, organism’s traits, insular position lower species richness altitudes. Furthermore, biological processes leading degradation under ecological ecosystems. Conclusion sensitivity investigated, existing it very likely do suffer pollution-induced toxicity. To verify this suggestion expand knowledge, necessary future combine more holistic modelling links effects. Only then will possible obtain impact protect these fragile

Language: Английский

Citations

26

Chemical Mixtures and Multiple Stressors: Same but Different? DOI Creative Commons
Ralf B. Schäfer, Michelle Jackson, Noël P. D. Juvigny‐Khenafou

et al.

Environmental Toxicology and Chemistry, Journal Year: 2023, Volume and Issue: 42(9), P. 1915 - 1936

Published: April 10, 2023

Ecosystems are strongly influenced by multiple anthropogenic stressors, including a wide range of chemicals and their mixtures. Studies on the effects stressors have largely focussed nonchemical whereas studies chemical mixtures ignored other stressors. However, both research areas face similar challenges require tools methods to predict joint or frameworks integrate missing. We provide an overview paradigms, tools, commonly used in stressor mixture discuss potential domains cross-fertilization challenges. First, we compare general paradigms ecotoxicology (applied) ecology explain historical divide. Subsequently, approaches for identification interactions, characterization, designing experiments. suggest that too focused interactions would benefit from integration regarding null model selection. Stressor characterization is typically more costly While comprehensive classification systems at suborganismal level been developed, recent account environmental context. Both suffer rather simplified experimental designs focus only limited number chemicals, treatments. concepts can guide realistic capturing spatiotemporal dynamics. process-based data-driven models particularly promising tackle challenge prediction (meta-)communities (meta-)food webs. propose framework assessment Environ Toxicol Chem 2023;42:1915-1936. © 2023 The Authors. Environmental Toxicology Chemistry published Wiley Periodicals LLC behalf SETAC.

Language: Английский

Citations

23

Aquatic-terrestrial transfer of neonicotinoid insecticides in riparian food webs DOI
Alexis P. Roodt, Maike Huszarik, Martin H. Entling

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 455, P. 131635 - 131635

Published: May 13, 2023

Language: Английский

Citations

23