Chemistry of Heterocyclic Compounds, Journal Year: 2024, Volume and Issue: 60(5-6), P. 257 - 261
Published: June 1, 2024
Language: Английский
FirePhysChem, Journal Year: 2021, Volume and Issue: 2(2), P. 83 - 139
Published: Oct. 1, 2021
Energetic material is a very essential company of compounds, widely used in various fields, primarily the military industry and space technologies. These compounds are unique that they capable instantly decomposing to release enormous energy. The chemical diversity energetic organic constantly increasing through combination high-nitrogen frameworks explosophoric groups, which follows overall trend interest their chemistry applications. scientific community looking for more powerful less sensitive external impulses both civilian use. Herein, detailed overview regarding classic novel groups frameworks, as well description selected synthesis target has been given time period since 2010. physical properties performances benchmark prospective also collected.
Language: Английский
Citations
123
ACS Applied Materials & Interfaces, Journal Year: 2022, Volume and Issue: 14(8), P. 10594 - 10604
Published: Feb. 22, 2022
The development of energetic materials is still facing a huge challenge because the relationship between energy and sensitivity usually contradictory: high always accompanied with low sensitivity. Here, high-energy, low-sensitivity polynitro-functionalized azopyrazole (TNAP) its salts have been synthesized. structural characterization these compounds was analyzed by elemental analysis, 1H 13C NMR spectroscopies, infrared spectroscopy. single-crystal structure K2TNAP, TNAP, 5, 6 obtained X-ray diffraction, K2TNAP novel metal-organic framework. calculated detonation properties TNAP (9040 m s-1 36.0 GPa) are superior to that RDX (8796 33.6 GPa). In addition, also has lower mechanical (IS > 40 J, FS = 244 N) higher decomposition temperature (Td 221 °C) than 7.4 120 N, Td 204 °C). These experimental results suggest may become new candidate for secondary explosives.
Language: Английский
Citations
41
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 470, P. 144144 - 144144
Published: June 24, 2023
Language: Английский
Citations
31
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 479, P. 147355 - 147355
Published: Nov. 24, 2023
Language: Английский
Citations
22
The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 89(1), P. 174 - 182
Published: Dec. 11, 2023
A majority of known and newly synthesized energetic materials comprise polynitrogen or nitrogen–oxygen heterocycles with various explosophores. However, available structural combinations these organic scaffolds are finite about to reach their limits. Herein, we present the design synthesis a series sulfur-containing polyazole structures comprising 1,3,4-thiadiazole furazan rings linked by C–C bonds enriched nitro azo functionalities. In terms detonation performance, all 1,3,4-thiadiazole-furazan assemblies (D = 7.7–7.9 km s–1; P 26–28 GPa) lie between powerful explosive TATB 8.0 31 melt-cast material TNT 6.9 23 GPa). series, azo-bridged derivative 5 seems be most practically interesting, as it combines relatively high performance 7.9 28 GPa), very thermal stability (271 °C), insensitivity friction. By functional properties, outperforms benchmark heat-resistant hexanitrostilbene (HNS). To best our knowledge, this is first example an alliance rare case high-energy materials, which can certainly considered evolutionary step in science.
Language: Английский
Citations
20
Journal of Heterocyclic Chemistry, Journal Year: 2024, Volume and Issue: 61(5), P. 713 - 722
Published: March 5, 2024
Abstract New promising energetic materials comprised of 1,2,4‐triazole and furoxan rings bearing explosophoric nitro group were rationally designed synthesized. All newly prepared compounds thoroughly characterized their physicochemical properties estimated. In the synthesized series, (1,2,4‐triazolyl)furoxan 4 is completely insensitive to impact friction possesses good detonation performance (D = 8.4 km s −1 ; P 33 GPa) enabling its further exploration as a high‐energy material.
Language: Английский
Citations
4
Frontiers in Chemistry, Journal Year: 2022, Volume and Issue: 10
Published: Oct. 13, 2022
Energetic Metal Organic Frameworks (EMOFs) have been a hotspot of research on solid propellants in recent years. In this paper, the application EMOFs-based burning rate catalysts was reviewed and development trend these explored. The analyzed included monometallic organic frameworks-based energetic catalysts, bimetallic multifunctional carbon-supported EMOFs that can be used conjunction with EMOFs. review suggest relatively simple catalytic effects, adding metal salts improve their effect. Bimetallic excellent performance potential for broad application. investigation is still at preliminary stage, but preparation become focus catalyst field. compounded should promoted. Finally, environmental protection, high energy low sensitivity, nanometerization, compounding solvent-free are proposed as key directions future research. This study aims to provide reference propellants.
Language: Английский
Citations
19
Mendeleev Communications, Journal Year: 2025, Volume and Issue: 35(3), P. 249 - 251
Published: Jan. 1, 2025
Language: Английский
Citations
0
Chemistry of Heterocyclic Compounds, Journal Year: 2022, Volume and Issue: 58(1), P. 37 - 44
Published: Jan. 1, 2022
Language: Английский
Citations
16
Russian Chemical Bulletin, Journal Year: 2024, Volume and Issue: 73(5), P. 1352 - 1361
Published: May 1, 2024
Language: Английский
Citations
3