Journal of the Energy Institute, Journal Year: 2024, Volume and Issue: unknown, P. 101832 - 101832
Published: Sept. 1, 2024
Language: Английский
Journal of the Energy Institute, Journal Year: 2024, Volume and Issue: unknown, P. 101832 - 101832
Published: Sept. 1, 2024
Language: Английский
Journal of the Energy Institute, Journal Year: 2025, Volume and Issue: unknown, P. 101984 - 101984
Published: Jan. 1, 2025
Language: Английский
Citations
1Sustainable Energy Technologies and Assessments, Journal Year: 2025, Volume and Issue: 75, P. 104210 - 104210
Published: Jan. 31, 2025
Language: Английский
Citations
1International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 79, P. 1237 - 1249
Published: July 14, 2024
Language: Английский
Citations
4Fuel, Journal Year: 2024, Volume and Issue: 381, P. 133362 - 133362
Published: Oct. 9, 2024
Language: Английский
Citations
4Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(22), P. 21735 - 21792
Published: Nov. 1, 2024
Polycyclic aromatic hydrocarbons (PAHs) are formed invariably through oxidative and pyrolytic degradation of organic materials fuels. Understanding the highly complex reaction mechanisms that dictate their synthesis in thermal systems has been given a great deal focus. Such interest stems from two broad perspectives, namely, enhancing efficiency combustion system, energy recovery fuels protecting environment. Health environmental effects widely vary among PAHs where certain compounds exhibit carcinogenic tendencies. This critical review mainly aims to provide general mechanistic view commonly discussed formation pathways PAHs. The attained knowledge often incorporates experimental measurements kinetic modelings, as well mapped out by quantum chemical calculations. A sampling species is typically conducted via molecular beam (MB)–mass spectroscopy (MS) technique connected reactor (flow reactor, jet-stirred or shock tube). Generally, PAH precursors encompass four categories (radicals molecules): acetylenic compounds, alkyl radicals, phenyl resonance-stabilized cyclic radicals. Overall, relevance mechanism depends on consistency between proposed model pathways, profiles products at investigated conditions (i.e., temperatures, pressures, distance burners). effect seeding common precursors, with other explored surveying pertinent studies. Growth higher PAHs, including toxic pyrene, most likely involves hydrogen abstraction acetylene addition (HACA)-like starting anthracene bimolecular reactions involve benzyl radicals indene molecules. synergistic collaboration different suggested account for observed fast growth rate As experimentally shown, sequential mass 15 u, 24 26 74 indicate routes MAC, HACA, HAVA*, PAC routes, respectively. Whether physical process initial step conversion into soot (the inception step) still debated literature. Recent evidence underscores commence creating dimers clustering under real flame 400–1200 K). Formation synthetic natural polymers ensues condensation fragments structural arrangements polymeric entities, prior fragmentation. surveyed presented this will be useful readers who aim comprehend chemistry underlying systems.
Language: Английский
Citations
4Journal of the Energy Institute, Journal Year: 2025, Volume and Issue: unknown, P. 102011 - 102011
Published: Jan. 1, 2025
Language: Английский
Citations
0International Journal of Chemical Reactor Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 10, 2025
Abstract Hydrogen (H 2 ) and ammonia (NH 3 are highly promising carbon-free fuels can mitigate the greenhouse effect threat. The laminar combustion characteristics of ethylene (C H 4 doped with NH were numerically calculated at large doping proportion (0–50 %), initial temperatures (T u = 300–400 K), pressures (P 0.1–1.0 MPa) by using Chemkin/Premix Code. equivalence ratio ( Φ ranged from 0.75 to 1.5. Laminar burning velocities (LBVs), adiabatic flame (AFTs), net heat release rates (NHRRs), temperature sensitivity analysis (TSA), mole fractions radicals H, O, OH intermediates C , NO, NO rate production (ROP) reaction pathways studied in this research. results showed that promoted increase /air LBVs, AFTs NHRRs, while had contrary effects. R1 + O <=> OH) largest positive coefficient more than 0.3. Through TSA ROP, R146 was main product could be effectively inhibited after . Additionally, fraction decreased as increased but peak located much closer nozzle inlet R392 (NO HO linked pathway on reducing CO stronger
Language: Английский
Citations
0Particuology, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of the Energy Institute, Journal Year: 2025, Volume and Issue: unknown, P. 102056 - 102056
Published: Feb. 1, 2025
Language: Английский
Citations
0Energy, Journal Year: 2025, Volume and Issue: unknown, P. 135457 - 135457
Published: March 1, 2025
Language: Английский
Citations
0