Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films DOI Creative Commons

Achilleas Kechagias,

Constantinos E. Salmas, Nikolaos Chalmpes

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(23), P. 1938 - 1938

Published: Dec. 2, 2024

Although a lot of recent research revealed advantages novel biopolymers' implementation as active food packaging polymers, there is not an equivalent effort from industry to use such films, probably because the required cost change supply chain and equipment. This study investigates two natural abundant nanoclays, laponite (Lap) montmorillonite (Mt), eugenol slow-release carriers for enhancing functionality low-density polyethylene (LDPE) films. The target combine spirit circular economy with existent technology broadly used materials develop attractive product applications. Utilizing vacuum-assisted adsorption method, was successfully intercalated into Lap Mt forming EG@Lap EG@Mt nanohybrids. Testing results confirmed effective integration dispersion nanohybrids within LDPE matrix. most promising final film seems be 15%

Language: Английский

Recent Developments in Synthesis, Properties, Applications and Recycling of Bio-Based Elastomers DOI Creative Commons
Manuel Burelo, Araceli Martínez, Josué David Hernández‐Varela

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(2), P. 387 - 387

Published: Jan. 12, 2024

In 2021, global plastics production was 390.7 Mt; in 2022, it 400.3 Mt, showing an increase of 2.4%, and this rising tendency will yearly. Of data, less than 2% correspond to bio-based plastics. Currently, polymers, including elastomers, are non-recyclable come from non-renewable sources. Additionally, most elastomers thermosets, making them complex recycle reuse. It takes hundreds thousands years decompose or biodegrade, contributing plastic waste accumulation, nano microplastic formation, environmental pollution. Due this, the synthesis natural renewable resources has attracted attention researchers industries. review paper, new methods strategies proposed for preparation elastomers. The main goals advances improvements synthesis, properties, applications industrial rubbers, polyurethanes, polyesters, polyethers, approach their circular economy sustainability. Olefin metathesis is as a novel sustainable method which allows depolymerization degradation rubbers with use essential oils, terpenes, fatty acids, alcohols such chain transfer agents (CTA) donors terminal groups chain, allow control molecular weights functional groups, obtaining compounds, oligomers, added value application polymers materials. This contributes development that can reduce carbon emissions, avoid cross-contamination fossil fuels, obtain greener material biodegradable and/or compostable behavior.

Language: Английский

Citations

27

Natural Antioxidants: Advancing Stability and Performance in Sustainable Biobased and Biodegradable Plastics DOI Creative Commons
Norma Mallegni, Francesca Cicogna, Elisa Passaglia

et al.

Compounds, Journal Year: 2025, Volume and Issue: 5(1), P. 4 - 4

Published: Feb. 3, 2025

The depletion of fossil fuels and environmental concerns have driven the development sustainable materials, including bio-based biodegradable plastics, as alternatives to conventional plastics. Although these plastics aid in waste management climate change mitigation, their vulnerability oxidative degradation impacts longevity, durability, performance. Natural antioxidants such tocopherols, flavonoids, tannins, extracted from plants or agri-food waste, present a alternative synthetic stabilizers by enhancing thermal stability polymers like poly(lactic acid) (PLA), poly(butylene succinate) (PBS), succinate-adipate) (PBSA), adipate-co-terephthalate) (PBAT), poly(hydroxyalkanoate) (PHA), starch-based materials. This review highlights recent advances stabilized with natural antioxidants, mechanisms action, role improving material properties for applications packaging. Additionally, it explores impact on recycling processes, advancements composite production techniques, future research directions. Bioplastics can achieve enhanced performance, reduce support circular economy incorporating antioxidants.

Language: Английский

Citations

5

Bio‐Polyethylene and Polyethylene Biocomposites: An Alternative toward a Sustainable Future DOI
Xiang Yun Debbie Soo, Joseph Kinyanjui Muiruri, Wen‐Ya Wu

et al.

Macromolecular Rapid Communications, Journal Year: 2024, Volume and Issue: 45(14)

Published: April 10, 2024

Abstract Polyethylene (PE), a highly prevalent non‐biodegradable polymer in the field of plastics, presents waste management issue. To alleviate this issue, bio‐based PE (bio‐PE), derived from renewable resources like corn and sugarcane, offers an environmentally friendly alternative. This review discusses various production methods bio‐PE, including fermentation, gasification, catalytic conversion biomass. Interestingly, bio‐PE volumes market are expanding due to growing environmental concerns regulatory pressures. Additionally, biocomposites using agricultural as filler materials, highlights demand for sustainable alternatives conventional plastics. According previous studies, addition ≈50% defibrillated abaca fibers into matrix compatibilizer, results highest Young's modulus 4.61 5.81 GPa, respectively. These have potential applications automotive, building construction, furniture industries. Moreover, advancement made abiotic biotic degradation is elucidated address their impacts. Finally, paper concludes with insights opportunities, challenges, future perspectives utilization biocomposites. In summary, can contribute cleaner future.

Language: Английский

Citations

12

Evaluation of Fenton, Photo-Fenton and Fenton-like Processes in Degradation of PE, PP, and PVC Microplastics DOI Open Access
Kristina Bule Možar,

Martina Miloloža,

Viktorija Martinjak

et al.

Water, Journal Year: 2024, Volume and Issue: 16(5), P. 673 - 673

Published: Feb. 25, 2024

The global problem of microplastics in the environment is “inspiring” scientists to find environmentally friendly and economically viable methods remove these pollutants from environment. Advanced oxidation processes are among most promising methods. In this work, potential Fenton, photo-Fenton, Fenton-like for degradation low-density polyethylene (LDPE), polypropylene (PP), poly(vinyl chloride) (PVC) water suspensions was investigated. influence three parameters on efficiency process tested: pH medium (3–7), mass added iron (10–50 times less than microplastics), H2O2 (5–25 more iron). effectiveness treatment monitored by FTIR-ATR spectroscopy. After 60-min treatments, PP microparticles were found be insensitive. Fenton PVC photo-Fenton LDPE PVC, changes FTIR spectra related observed. cases, optimized. It that a low (3) high (optimal values 1/12 1/10 respectively) favored all three. concentrations (25 higher iron), while significantly lower (11 15 treatment, respectively), suggesting scavenging activity occurs.

Language: Английский

Citations

10

Development and Properties of Bio-Based Polymer Composites Using PLA and Untreated Agro-Industrial Residues DOI Creative Commons

Alexa K. Gamiz-Conde,

Manuel Burelo, Edgar Adrián Franco Urquiza

et al.

Polymer Testing, Journal Year: 2024, Volume and Issue: 139, P. 108576 - 108576

Published: Sept. 12, 2024

Language: Английский

Citations

9

Ocean current modulation of the spatial distribution of microplastics in the surface sediments of the Beibu Gulf, China DOI
Liyuan Wu, Chengyong Li, Chao Huang

et al.

Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 488, P. 137332 - 137332

Published: Jan. 22, 2025

Language: Английский

Citations

1

Plastic Waste and COVID-19 Incidence Among Hospital Staff After Deescalation in PPE Use DOI Creative Commons
Stephanie Sutjipto,

Aung Hein Aung,

Margaret Mei Ling Soon

et al.

JAMA Network Open, Journal Year: 2025, Volume and Issue: 8(4), P. e255264 - e255264

Published: April 15, 2025

Importance In September 2023, the Singapore Ministry of Health revised national personal protective equipment (PPE) guideline for health care personnel (HCP) attending to suspected or confirmed patients with COVID-19, recommending use N95 respirators alone. However, data on associations between PPE deescalation, staff COVID-19 incidence, and sustainability outcomes are limited. Objective To evaluate deescalation guidelines incidence environmental measure. Design, Setting, Participants This was a retrospective quality improvement study hospital usage using from Tan Tock Seng Hospital National Centre Infectious Diseases (NCID), analyzing monthly rates among HCP (all medical staff, allied workers, ancillary administrative campus) in community over 12 months before after measures (October 2021 2022 October 2023). Main Outcomes Measures community; economic removing single-use gowns routine care, including reductions carbon footprint, plastic waste generation, cost savings. Results The mean (SD) number 10 774 (79) (range, 636-10 891) preimplementation 11 099 (200) 864-11 449) postimplementation. Our analysis revealed not associated an increase infections trends aligning population infection rates. median (IQR) rate relative 2.6 (1.9-3.6) compared 1.5 (0.9-3.1) An estimated 4 per patient-day were saved, totaling 440 532 months. equated reduction costs by SGD 453 748 (approximately USD 333 970) 398 681.46 kg dioxide equivalent emissions 66 080 waste. Conclusions Relevance observed that corresponded gown use, costs, generation no apparent compromise safety health.

Language: Английский

Citations

1

An evaluation of a hepatotoxicity risk induced by the microplastic polymethyl methacrylate (PMMA) using HepG2/THP-1 co-culture model DOI Creative Commons
Tuğçe Boran, Özge Sultan Zengin, Zehra Şeker

et al.

Environmental Science and Pollution Research, Journal Year: 2024, Volume and Issue: 31(20), P. 28890 - 28904

Published: April 2, 2024

Abstract Inappropriate disposal of plastic wastes and their durability in nature cause uncontrolled accumulation land/marine ecosystems, also causing destructive effects by bioaccumulating along the food chain. Microplastics may chronic inflammation relation to permanent structures, especially through oxidative stress cytotoxic cellular damage, which could increase risk cancer development. The microplastics liver is a major concern, therefore, identification mechanisms hepatotoxic great importance. Polymethyl methacrylate (PMMA) widely used thermoplastic. It has been determined that PMMA disrupts lipid metabolism various aquatic organisms causes reproductive developmental toxicity. PMMA-induced humans have not yet clarified. In our study, toxic (in range 3–10 μm) on human were investigated using HepG2/THP-1 macrophage co-culture model, sensitive immune-mediated injury model. Cellular uptake micro-sized cells was done transmission electron microscopy. Determination its cell viability inflammatory response, stress, with gene protein expression levels play role mechanism pathways underlying investigated. results concluded inflammation, disruptions should be focus attention as important hepatotoxicity. Our points out potential adverse health, supports literature information subject.

Language: Английский

Citations

7

Mechanical recycling of carbon fibre reinforced polymers. Part 1: influence of cutting speed on recycled particles and composites properties DOI Creative Commons

Carolina Vega-Leal,

Cecilia Zárate-Pérez,

Victor A. Gomez-Culebro

et al.

International Journal of Sustainable Engineering, Journal Year: 2024, Volume and Issue: 17(1), P. 159 - 168

Published: March 18, 2024

Scientific advances and technological requirements to develop carbon fibre-reinforced polymers (CFRP) with excellent strength-to-weight ratios led the high consumption of CFRP composites. The mechanical recycling is a simpler, more economical, environmentally responsible solution for effectively recovering this structural material that contains epoxy resin fibre. laminates were placed on Computer Numerical Control (CNC) milling cutting at 1100, 1800, 2500 rpm. recovered particles mixed acrylonitrile butadiene styrene (ABS) using melt intercalation approach. Recovered increased molecular mobility reduced thermal stability ABS. main differences between ABS composites pronounced necking region in than notable reduction strain. strain was 27.58%, while composites, it 4.29, 4.02, 3.51%, depending speed. Thus, ductility decreased up 87% This work's successful method provides powder, individual fibres, particles, opening research field great economic environmental relevance developing new materials.

Language: Английский

Citations

6

Soil Microplastic Pollution and Microbial Breeding Techniques for Green Degradation: A Review DOI Creative Commons
Zhuang Xiong, Yunfeng Zhang,

Xiaodie Chen

et al.

Microorganisms, Journal Year: 2024, Volume and Issue: 12(6), P. 1147 - 1147

Published: June 5, 2024

Microplastics (MPs), found in many places around the world, are thought to be more detrimental than other forms of plastics. At present, physical, chemical, and biological methods being used break down MPs. Compared with physical chemical methods, biodegradation have been extensively studied by scholars because their advantages greenness sustainability. There numerous reports recent years summarizing microorganisms capable degrading However, there is a noticeable absence systematic summary on technology for breeding strains that can degrade This paper summarizes strain-breeding MP-degrading first time way, which provides new idea efficient strains. Meanwhile, potential techniques bacteria MPs proposed, providing direction selecting future. In addition, this reviews sources pollution status soil MPs, discusses current challenges related emphasizes safety MP biodegradation.

Language: Английский

Citations

6