Polymeric lanthanide 2-iodoterephthalates: synthesis and structure DOI

Mikhail A. Bondarenko,

А. S. Zaguzin, Pavel A. Abramov⧫

et al.

Журнал неорганической химии, Journal Year: 2024, Volume and Issue: 69(5), P. 696 - 702

Published: Nov. 21, 2024

Language: Английский

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B12Cl12]2– DOI
А. V. Golubev, Alexey S. Kubasov, Еlena А. Malinina

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: 24(8), P. 3319 - 3332

Published: April 2, 2024

For the first time, a systematic study of behavior Ag2[B12Cl12] in oxygen-containing organic solvents various nature (acetone, N,N-dimethylformamide (DMF), dimethoxyethane (DME), methanol (CH3OH), and tetrahydrofuran (THF)) was conducted. The used were found to compete with perchlorinated [B12Cl12]2– anion, forming silver(I) coordination polyhedron. A number compounds compositions structures solvent molecules acting as ligands obtained characterized by physicochemical methods. polymer complexes {Ag2(solv)x[B12Cl12]}n (x = 4, solv acetone (1), DMF (2), CH3OH (4), THF (7); x 2, DME (3)) coordinated well [Ag(THF)3]2[B12Cl12] (5) [Ag(THF)4Ag(THF)2][B12Cl12] (6) boron cluster anion counterion determined single-crystal X-ray diffraction. Furthermore, complexation 18-crown-6 (L1) 4-methylmorpholine (L2) investigated. Salts complex cations [Ag L1(CH3OH)]+ (8) [Ag(L2)2]+ (9) isolated. Based on results obtained, plausible pathway for process ligand L proposed. data confirmed using 109Ag NMR spectroscopy solutions salt individual their mixtures.

Language: Английский

Citations

4
Substituted (benzoimidazol-2-yl)Methanamines in Silver(I) Complexation in the Presence of Boron Cluster Anions DOI
Svetlana E. Nikiforova,

Nadezhda A. Khan,

Alexey S. Kubasov

et al.

Journal of Cluster Science, Journal Year: 2025, Volume and Issue: 36(3)

Published: April 21, 2025

Language: Английский

Citations

0
Iodide Cd(II) Complexes with 2-Halogen-substituted Pyridines: Structures and Features of Halogen Bond in Solid DOI
Sergey A. Adonin, Alexander S. Novikov

Russian Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 9, 2024

Language: Английский

Citations

2
Cd(II) and Zn(II) complexes with 2-mercaptopyridine: Synthesis, crystal structure, Hirshfeld surface analysis, luminescent properties, aggregation behaviours, current-voltage characteristic and antibacterial assay DOI Creative Commons
Arijit Das, Syed Arshad Hussain, Hritinava Banik

et al.

Polyhedron, Journal Year: 2023, Volume and Issue: 247, P. 116747 - 116747

Published: Nov. 18, 2023

Two transition metal complexes viz. [Cd(2-mcpH)4](NO3)2 (1) and [Zn(2-mcpH)4](NO3)2 (2) were synthesized by the reaction of cadmium(II) nitrate tetrahydrate or zinc(II) hexahydrate with 2-mercaptopyridine (2-mcpH) in 1:4 molar ratio. These have been fully characterized UV-Vis, IR, NMR–spectroscopy Single crystal X-ray analysis. Luminescent properties complex 2 also investigated. The emission seen is accredited due to π···π* intra-ligand transitions. structural architecture both manifested as monomeric tetra-coordinated M-centers, each adeptly coordinated four 2-mcpH ligands. arrangements effectively neutralized charge, employing two groups. Concurrently, Hirshfeld surfaces analysis showed maximum interactions 25.6%, 26.6% for H···H, 25.0%, 25.1% O···H contacts 1 2, respectively. In current-voltage (I-V) characteristic studies, it has observed that Ohmic behavior. FESEM studies give convincing visual facts aggregation behaviour complexes. To appraise their potential, ligand subjected antibacterial s. Complex most potent effect, particularly against Gram-negative bacteria, while exhibited a moderate effect Gram-positive bacteria.

Language: Английский

Citations

5
Structural variety of benzimidazole coordinated zinc(II) and cadmium(II) complexes with closo-decaborate anion DOI
Svetlana E. Nikiforova, Alexey S. Kubasov,

Lyudmila V. Goeva

et al.

Polyhedron, Journal Year: 2024, Volume and Issue: 257, P. 117012 - 117012

Published: April 27, 2024

Language: Английский

Citations

1
Polymeric Lanthanide 2-Iodoterephthalates: Synthesis and Structure DOI

Mikhail A. Bondarenko,

А. S. Zaguzin, Pavel A. Abramov⧫

et al.

Russian Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 9, 2024

Language: Английский

Citations

1
Coordination ability of the dodecachloro-closo-dodecaborate anion [B12Cl12]2– in silver(I) complexation in the presence of S-donor ligands DOI
А. V. Golubev, Alexey S. Kubasov, Еlena А. Malinina

et al.

Inorganica Chimica Acta, Journal Year: 2024, Volume and Issue: 573, P. 122344 - 122344

Published: Aug. 30, 2024

Language: Английский

Citations

1
Iodide complexes of Cd(II) with 2-halogen-substituted pyridines: structures and features of halogen bond in solid DOI
Sergey A. Adonin, Alexander S. Novikov

Журнал неорганической химии, Journal Year: 2024, Volume and Issue: 69(7), P. 1022 - 1028

Published: July 15, 2024

Language: Английский

Citations

0
Structural Variety of Benzimidazole Coordinated Zinc(Ii) and Cadmium(Ii) Complexes with Closo-Decaborate Anion DOI

Svetlana Korolenko,

Aleksey Kubasov,

Lyudmila V. Goeva

et al.

Published: Jan. 1, 2024

Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI

Language: Английский

Citations

0
Polymeric lanthanide 2-iodoterephthalates: synthesis and structure DOI

Mikhail A. Bondarenko,

А. S. Zaguzin, Pavel A. Abramov⧫

et al.

Журнал неорганической химии, Journal Year: 2024, Volume and Issue: 69(5), P. 696 - 702

Published: Nov. 21, 2024

Language: Английский

Citations

0