Phosphorus Doped MoO2 Enhanced Pt Catalyst for Methanol Oxidation DOI Creative Commons
Yuanbo Li, Meng Li,

Mamutjan Tursun

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Abstract The sluggish kinetics of methanol oxidation reaction (MOR) required high‐performing catalysts in the development direct fuel cells. Herein, a phosphorus‐doped MoO 2 nanorods‐supported Pt catalyst was proposed which exhibited remarkably enhanced catalytic performance toward MOR comparison with Pt/MoO and commercial Pt/C. Specifically, ‐P possessed highest peak current density 62.63 mA cm −2 , about 1.38 2.21 times higher than that (45.24 ) Pt/C (28.40 ), respectively. Meanwhile, high intrinsic activity expressed by specific mass activity, largely improved kinetics. Moreover, chronoamperometry CO‐stripping testing successfully revealed superior stability CO‐poisoning resistance ‐P, rendering promising for MOR. theoretical calculation electron redistribution strong metal‐support interaction among catalysts. greatly could be attributed to heteroatom doping engineering, enhancing conductivity, inducing redistribution, thereby leading CO‐anti poisoning ability.

Language: Английский

High valence Ni3+ was introduced into MoO2 to improve its performance of electrocatalytic N2 reduction to NH3 DOI
Xuemei Gao, Huimin Yang, Jiaqi Yang

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: 57, P. 105740 - 105740

Published: Jan. 1, 2025

Language: Английский

Citations

2

Recent advancements and perspectives in MoO2-based heterostructures for electrochemical hydrogen evolution reaction DOI
Ha Huu, Nguyen Tien Tran, Vinh Van Tran

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 105, P. 234 - 247

Published: Jan. 23, 2025

Language: Английский

Citations

2

Transition metal-based heterojunctions for alkaline electrocatalytic water splitting DOI

Chengshuang Xu,

Ying Hong, Zhong Li

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216287 - 216287

Published: Oct. 29, 2024

Language: Английский

Citations

4

Regulating oxygen vacancy and interface structure of NiCu/NiMoO4 bifunctional catalyst for stable and efficient photothermal catalysis and overall water splitting DOI
Baoyu Huang, Danyang Wei, Zhiwei Meng

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1028, P. 180701 - 180701

Published: April 29, 2025

Language: Английский

Citations

0

Nickel foam/reduced graphene oxide/CoNi2S4-MoO2 nanosheets with a core–shell structure formed: An efficient electrocatalyst for the hydrogen evolution reaction DOI Creative Commons
Meiling Liu, Cuili Xiang, Yongjin Zou

et al.

Materials Today Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 100079 - 100079

Published: Nov. 1, 2024

Language: Английский

Citations

1

Electronic-Structure-Modulated Cu,Co-Coanchored N-Doped Nanocarbon as a Difunctional Electrocatalyst for Hydrogen Evolution and Oxygen Reduction Reactions DOI Creative Commons
Liyun Cao, Rui Liu, Yixuan Huang

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(13), P. 2973 - 2973

Published: June 22, 2024

To alleviate the problems of environmental pollution and energy crisis, aggressive development clean alternative technologies, in particular, water splitting, metal-air batteries, fuel cells involving two key half reactions comprising hydrogen evolution reaction (HER) oxygen reduction (ORR), is crucial. In this work, an innovative hybrid heterogeneous Cu/Co bimetallic nanoparticles homogeneously dispersed on a nitrogen-doped carbon layer (Cu/Co/NC) was constructed as bifunctional electrocatalyst toward HER ORR via hydrothermal along with post-solid-phase sintering technique. Thanks to interfacial coupling electronic synergism between Cu Co nanoparticles, Cu/Co/NC catalyst showed improved catalytic activity half-wave potential 0.865 V excellent stability more than 30 h, even compared 20 wt% Pt/C. The also exhibited performance overpotential below 149 mV at 10 mA/cm

Language: Английский

Citations

0

Phosphorus Doped MoO2 Enhanced Pt Catalyst for Methanol Oxidation DOI Creative Commons
Yuanbo Li, Meng Li,

Mamutjan Tursun

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Abstract The sluggish kinetics of methanol oxidation reaction (MOR) required high‐performing catalysts in the development direct fuel cells. Herein, a phosphorus‐doped MoO 2 nanorods‐supported Pt catalyst was proposed which exhibited remarkably enhanced catalytic performance toward MOR comparison with Pt/MoO and commercial Pt/C. Specifically, ‐P possessed highest peak current density 62.63 mA cm −2 , about 1.38 2.21 times higher than that (45.24 ) Pt/C (28.40 ), respectively. Meanwhile, high intrinsic activity expressed by specific mass activity, largely improved kinetics. Moreover, chronoamperometry CO‐stripping testing successfully revealed superior stability CO‐poisoning resistance ‐P, rendering promising for MOR. theoretical calculation electron redistribution strong metal‐support interaction among catalysts. greatly could be attributed to heteroatom doping engineering, enhancing conductivity, inducing redistribution, thereby leading CO‐anti poisoning ability.

Language: Английский

Citations

0