Zeitschrift für Physikalische Chemie,
Journal Year:
2024,
Volume and Issue:
238(8), P. 1431 - 1449
Published: May 15, 2024
Abstract
The
single
crystals
of
bimetallic
thiocyanate
ligands,
namely
manganese
cadmium
(MCTC),
zinc
(ZCTC),
mercury
dimethylsulphoxide
(MMTD),
and
(CMTD),
are
cultivated
through
the
utilization
slow
solvent
evaporation
gradual
cooling
methodologies.
Through
optical
microscopic
techniques
such
as
field
emission
scanning
electron
microscopy
(FESEM),
atomic
force
(AFM),
epifluorescence,
a
state-of-the-art
methodology
extensively
employed
in
realms
biochemical,
medical,
chemical
research,
we
delve
into
examination
growth
mechanisms
surface
topographies.
It
is
additionally
LED,
fluorescent,
various
other
luminous
sources.
FESEM
analysis
MCTC
elucidates
manifestation
an
extended
dendritic
pattern,
which
arises
from
oscillation
Mn
Cd
metal
ligands
when
connected
by
(SCN)
bridges.
presence
three
notable
mounds
exhibiting
cavities
within
multi-component
thin
film
coating
(MCTC)
has
been
duly
ascertained
(AFM)
imagery.
histogram
unveiled
that
average
diameter
exhibited
augmentation
concomitant
with
alteration
breadth
distribution
throughout
process
growth.
Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
39(1)
Published: Sept. 27, 2024
ABSTRACT
The
structure
and
biological
diversities
of
[Zn(BPT
Morph
)(H
2
O)
3
](ClO
4
)
(
1
),
)(NO
]
[Cd(BPT
complexes
were
described.
In
all
complexes,
the
Zn(II)
Cd(II)
ions
are
coordinated
with
one
4‐(4,6‐
bis
(3,5‐dimethyl‐1
H
‐pyrazol‐1‐yl)‐1,3,5‐triazin‐2‐yl)morpholine
BPT
molecule
as
a
pincer
NNN
‐chelate.
rest
coordination
sphere
was
found
to
depend
on
type
anion.
,
there
three
water
molecules
leading
distorted
octahedral
geometry
around
Zn(II).
two
NO
−
groups
that
differ
in
their
modes.
monodentate
bidentate
.
Hence,
numbers
5
7,
respectively.
Supramolecular
investigations
indicated
importance
O···H
contacts
molecular
packing.
percentages
35.4%–36.1%,
44.8%,
39.7%
–
energy
breakdown
for
intermolecular
interactions
performed
using
framework
analysis
explore
forces
dominate
these
interactions.
Anticancer
activity
against
HepG‐2,
MCF‐7,
A‐549
cancerous
cells
presented.
best
result
is
complex
where
IC
50
2.77
±
0.26
μg/mL
selectivity
index
12.5
although
corresponding
values
32.39
2.82
2.7,
addition,
outperformed
anticancer
drug
cis
‐platin
cell
lines.
antimicrobial
compared
Interestingly,
showed
antibacterial
efficiency
comparable
gentamycin
Proteus
vulgaris
Zeitschrift für Physikalische Chemie,
Journal Year:
2024,
Volume and Issue:
238(8), P. 1431 - 1449
Published: May 15, 2024
Abstract
The
single
crystals
of
bimetallic
thiocyanate
ligands,
namely
manganese
cadmium
(MCTC),
zinc
(ZCTC),
mercury
dimethylsulphoxide
(MMTD),
and
(CMTD),
are
cultivated
through
the
utilization
slow
solvent
evaporation
gradual
cooling
methodologies.
Through
optical
microscopic
techniques
such
as
field
emission
scanning
electron
microscopy
(FESEM),
atomic
force
(AFM),
epifluorescence,
a
state-of-the-art
methodology
extensively
employed
in
realms
biochemical,
medical,
chemical
research,
we
delve
into
examination
growth
mechanisms
surface
topographies.
It
is
additionally
LED,
fluorescent,
various
other
luminous
sources.
FESEM
analysis
MCTC
elucidates
manifestation
an
extended
dendritic
pattern,
which
arises
from
oscillation
Mn
Cd
metal
ligands
when
connected
by
(SCN)
bridges.
presence
three
notable
mounds
exhibiting
cavities
within
multi-component
thin
film
coating
(MCTC)
has
been
duly
ascertained
(AFM)
imagery.
histogram
unveiled
that
average
diameter
exhibited
augmentation
concomitant
with
alteration
breadth
distribution
throughout
process
growth.
