Knowledge-Based Engineering and Sciences,
Journal Year:
2024,
Volume and Issue:
5(1), P. 98 - 119
Published: April 30, 2024
The
study
explored
the
efficacy
of
an
innovative
adsorbent
crafted
from
carbon
nanotubes
and
nano
fibbers
integrated
with
aluminium
oxide,
in
purging
water
solutions
both
organic
(2-Nitrophenol)
inorganic
(Chromium
III)
contaminants.
refined
impregnation
method
to
boost
adsorption
efficiency
CNAs/Al2O3
removing
certain
pollutants.
Through
a
central
composite
design
(CCD)
strategy,
optimal
conditions
were
determined.
most
effective
removal
2-NPh
Cr3+
occurred
at
18%
ratio,
after
3
hours
ultrasonication
calcination
Temperature
300
oC.
This
technique
yielded
capacities
82.02
mg/g
for
96.57
Cr3+.
content
adsorbents,
prepared
under
these
specified
conditions,
was
verified,
measured
using
EDX
(Energy
Dispersive
X-ray)
analysis.
Further,
BET
(Brunauer-Emmett-Teller)
measurements
revealed
impact
ratios
on
surface
area
CNAs/Al2O3,
where
18
%
ratio
led
176
m2/g,
diminishing
125
m2/g
110
20%
22%
ratios,
respectively.
Predicted
capacity
estimated
83.154
mg/g,
aligning
closely
observed
while
estimate
97.80
nearly
matched
actual
mg/g.
A
validation
evaluated
predicted
contaminants,
finding
that
86.79
99.79
noted
acceptable
error
margin
about
4.5%
2%
optimized
integration
metal
oxides
CNAs
through
significantly
enhances
their
pollutants,
particularly
when
oxide
is
used
purifying
wastewater
by
extracting
heavy
Catalysts,
Journal Year:
2025,
Volume and Issue:
15(2), P. 123 - 123
Published: Jan. 27, 2025
This
research
presents
a
green
approach
to
synthesizing
zirconium
oxide
(ZrO2)
nanoparticles
using
an
Asphodelus
fistulosus
plant
extract
as
reducing
and
stabilizing
agent.
The
synthesized
ZrO2
were
characterized
various
advanced
techniques.
XRD
pattern
provides
different
forms
of
ZrO2,
like
tetragonal
cubic
forms,
the
results
confirmed
successful
formation
crystalline
with
definite
morphology.
XPS
data
exhibit
that
bioactive
chemicals
present
in
extract,
including
polyphenols,
flavonoids,
sugars,
perform
functions
capping
agents.
Additionally,
CR
dye
molecules
may
create
hydrogen
bonds
these
surface
moieties,
which
are
approved
by
FTIR.
These
interactions
assist
aligning
catalytically
active
regions
on
surfaces
interact
photogenerated
species.
catalytic
activity
was
evaluated
for
degradation
Congo
red
under
ultraviolet
irradiation.
exhibited
excellent
photocatalytic
activity,
degrading
significant
amount
within
short
period.
Various
parameters
investigated
optimize
photodegradation
process,
irradiation
time,
catalyst
dosage,
pH,
initial
concentration.
optimal
conditions
determined
be
pH
7,
loading
20
mg/L,
time
75
min,
resulting
remarkable
≈92%
efficiency.
synthesis
method
offers
sustainable
eco-friendly
alternative
conventional
chemical
methods
producing
nanoparticles,
have
potential
applications
environmental
remediation.