The Effects of Polyolefin Structure and Source on Pyrolysis-Derived Plastic Oil Composition DOI
Jiayang Wu, Zhen Jiang, Victor S. Cecon

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Seven types of plastics, from varied structures and sources, were pyrolyzed in a fluidized bed reactor. The resulting oils analyzed by GC×GC, NMR, ICP, while theory experiments combined to explore the degradation mechanism.

Language: Английский

Recent advances in polyolefinic plastic pyrolysis to produce fuels and chemicals DOI
Leilei Dai, Suman Lata,

Kirk Cobb

et al.

Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 180, P. 106551 - 106551

Published: May 22, 2024

Language: Английский

Citations

13
Parametric Study of Polyethylene Primary Decomposition Using a Micropyrolyzer Coupled with Two-Dimensional Gas Chromatography DOI

J.V. Jayarama Krishna,

Barbara Alejandra Perez,

Hilal Ezgi Toraman

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(19), P. 7508 - 7518

Published: April 30, 2024

A deeper understanding of pyrolysis reaction pathways under an isothermal, reaction-controlled regime is essential for studying the kinetics and optimizing design reactors. This work methodically studied effect various variables on product distribution high-density polyethylene (HDPE) to validate conditions that minimize transport effects secondary gas-phase reactions. The primary decomposition HDPE was performed using a Box–Behnken evaluate role such as particle size, sample carrier gas flow rate, temperature. Pyrolysis experiments used micropyrolyzer connected two-dimensional chromatography with flame ionization time-of-flight spectrometer detectors (Py–GC × GC–FID/TOF–MS). Principal component analysis data showed statistical differences in yield C3 C28 hydrocarbons temperature varied between 480 600 °C. Furthermore, larger size 1000 μg resulted different compared smaller sizes 50–150 μg. At °C, yields cyclodiolefins, cycloolefins, aromatics increased by approximately 355, 67, 62%, respectively, when from 50 μg, rate decreased 100 mL min–1.

Language: Английский

Citations

8
Tailored HZSM-5 catalyst modification via phosphorus impregnation and mesopore introduction for selective catalytic conversion of polypropylene into light olefins DOI
Oğuzhan Akin, Qing He, Parviz Yazdani

et al.

Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 181, P. 106592 - 106592

Published: June 19, 2024

Language: Английский

Citations

4
Thermal and catalytic pyrolysis of automotive plastic wastes to diesel range fuel DOI Creative Commons
Elly Olomo,

Stephen M. Talai,

Joseph Kiplagat

et al.

Heliyon, Journal Year: 2024, Volume and Issue: 10(20), P. e39576 - e39576

Published: Oct. 1, 2024

Language: Английский

Citations

4
Enhancing plastic pyrolysis for carbon nanotubes synthesis through machine learning integration: A review DOI

K. Loke,

Xuan Han Lim,

M.A. Osman

et al.

Journal of Analytical and Applied Pyrolysis, Journal Year: 2025, Volume and Issue: unknown, P. 106989 - 106989

Published: Jan. 1, 2025

Language: Английский

Citations

0
High Density Polyethylene Thermal Pyrolysis: Kinetic and Volatilization Modeling DOI
Laura Pires da Mata Costa, Oğuzhan Akin,

J.A. García

et al.

Journal of Analytical and Applied Pyrolysis, Journal Year: 2025, Volume and Issue: unknown, P. 107168 - 107168

Published: May 1, 2025

Language: Английский

Citations

0
Effect of pyrolysis operating conditions on the catalytic co‐pyrolysis of low‐density polyethylene and polyethylene terephthalate with zeolite catalysts DOI Creative Commons
Sean Timothy Okonsky,

Neil Robert Hogan,

Hilal Ezgi Toraman

et al.

AIChE Journal, Journal Year: 2024, Volume and Issue: 70(12)

Published: Aug. 6, 2024

Abstract In this study, the catalytic (co‐)pyrolysis of low‐density polyethylene (LDPE) and terephthalate (PET) with HZSM‐5 HY zeolite catalysts was conducted in a micro‐pyrolysis reactor coupled to two‐dimensional gas chromatography system. Pyrolysis operating conditions, such as pyrolysis temperature, catalyst feedstock (CF) ratio, LDPE:PET were varied. It found that for co‐pyrolysis LDPE PET, led higher yields C2‐C4 olefins monoaromatic products. Lower CF ratios increased yield pyrolysis, but decreased benzene PET concomitant an benzoic acid. A lower temperature 400°C which sufficient LDPE, incomplete conversion PET. Surface response diagrams used visualize impact various conditions on BTEX, serve target products circular economy.

Language: Английский

Citations

3
Comparative analysis of additive decomposition using one-dimensional and two-dimensional gas chromatography: Part I - Irganox 1010, Irganox 1076, and BHT DOI

Rowfi Khan,

Barbara Alejandra Perez,

Hilal Ezgi Toraman

et al.

Journal of Chromatography A, Journal Year: 2024, Volume and Issue: 1732, P. 465243 - 465243

Published: Aug. 8, 2024

Language: Английский

Citations

2
Comparative analysis of additive decomposition using one-dimensional and two–dimensional gas chromatography: Part II - Irgafos 168 and zinc stearate DOI

Rowfi Khan,

Barbara Alejandra Perez,

Hilal Ezgi Toraman

et al.

Journal of Chromatography A, Journal Year: 2024, Volume and Issue: 1732, P. 465244 - 465244

Published: Aug. 9, 2024

Language: Английский

Citations

2
Characterization of polyolefins-based pyrolysis oils: A comparison between one-dimensional gas chromatography and two-dimensional gas chromatography DOI

Barbara Alejandra Perez,

J.V. Jayarama Krishna,

Hilal Ezgi Toraman

et al.

Journal of Chromatography A, Journal Year: 2024, Volume and Issue: 1739, P. 465510 - 465510

Published: Nov. 8, 2024

Language: Английский

Citations

2