MXene‐Based Composites: Synthesis and Applications in Rechargeable Batteries and Supercapacitors DOI Creative Commons
Jian Yang, Weizhai Bao, Pauline Jaumaux

et al.

Advanced Materials Interfaces, Journal Year: 2019, Volume and Issue: 6(8)

Published: March 18, 2019

Abstract The family of 2D transition metal carbides, nitrides, and carbonitrides (collectively called MXenes) is rapidly studied since the initial synthesis Ti 3 C 2 T x (MXene). surface MXenes etched by hydrofluoric acid has hydrophilic groups (F, OH, O), which leads to be negatively charged. Consequently, charged can facilitate compounding with other positively materials prevent from aggregating some substances, thus promoting formation a stable dispersion. MXene‐based composites have better electrochemical performance than both precursors due synergistic effects. This review elaborates discusses development composites. It aimed summarize various methods fabricating applications in batteries supercapacitors are presented along analysis their excellent performances. Finally, authors propose approach for further enhancing performances composite electrode materials.

Language: Английский

Cocatalysts for Selective Photoreduction of CO2into Solar Fuels DOI
Xin Li, Jiaguo Yu, Mietek Jaroniec

et al.

Chemical Reviews, Journal Year: 2019, Volume and Issue: 119(6), P. 3962 - 4179

Published: Feb. 14, 2019

Photoreduction of CO2 into sustainable and green solar fuels is generally believed to be an appealing solution simultaneously overcome both environmental problems energy crisis. The low selectivity challenging multi-electron photoreduction reactions makes it one the holy grails in heterogeneous photocatalysis. This Review highlights important roles cocatalysts selective photocatalytic reduction using semiconductor catalysts. A special emphasis this review placed on key role, design considerations modification strategies for photoreduction. Various cocatalysts, such as biomimetic, metal-based, metal-free, multifunctional ones, their are summarized discussed, along with recent advances area. provides useful information highly photo(electro)reduction electroreduction complements existing reviews various photocatalysts.

Language: Английский

Citations

1925

Product selectivity of photocatalytic CO2 reduction reactions DOI
Junwei Fu,

Kexin Jiang,

Xiaoqing Qiu

et al.

Materials Today, Journal Year: 2019, Volume and Issue: 32, P. 222 - 243

Published: July 18, 2019

Language: Английский

Citations

972

2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity DOI

Fei He,

Bicheng Zhu, Bei Cheng

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2020, Volume and Issue: 272, P. 119006 - 119006

Published: April 19, 2020

Language: Английский

Citations

784

Two-dimensional MXenes: From morphological to optical, electric, and magnetic properties and applications DOI Creative Commons
Xiantao Jiang, Artem V. Kuklin, Alexander Baev

et al.

Physics Reports, Journal Year: 2020, Volume and Issue: 848, P. 1 - 58

Published: Jan. 22, 2020

MXenes, generally referring to two-dimensional (2D) transition-metal carbides, nitrides, and carbonitrides, have received tremendous attention since the first report in 2011. Extensive experimental theoretical studies unveiled their enormous potential for applications optoelectronics, photonics, catalysis, many other areas. Because of intriguing mechanical electronic properties, together with richness elemental composition chemical decoration, MXenes are poised provide a new 2D nanoplatform advanced optoelectronics. This comprehensive review, intended broad multidisciplinary readership, highlights state-of-the-art progress on MXene theory, materials synthesis techniques, morphology modifications, opto-electro-magnetic applications. The efforts exploring device performance limits, steric configurations, physical mechanisms, novel application boundaries comprehensively discussed. review is concluded compelling perspective, outlook as well non-trivial challenges future investigation MXene-based nano-optoelectronics.

Language: Английский

Citations

769

Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites: Insights into Electro- and Photocatalysis DOI Creative Commons

Jiahe Peng,

Xingzhu Chen,

Wee‐Jun Ong

et al.

Chem, Journal Year: 2018, Volume and Issue: 5(1), P. 18 - 50

Published: Sept. 27, 2018

Language: Английский

Citations

714

Ag3PO4/Ti3C2 MXene interface materials as a Schottky catalyst with enhanced photocatalytic activities and anti-photocorrosion performance DOI
Tao Cai, Longlu Wang, Yutang Liu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2018, Volume and Issue: 239, P. 545 - 554

Published: Aug. 22, 2018

Language: Английский

Citations

562

Toward Nanotechnology-Enabled Approaches against the COVID-19 Pandemic DOI Creative Commons
Carsten Weiß, Marie Carrière, Laura Fusco

et al.

ACS Nano, Journal Year: 2020, Volume and Issue: 14(6), P. 6383 - 6406

Published: June 10, 2020

The COVID-19 outbreak has fueled a global demand for effective diagnosis and treatment as well mitigation of the spread infection, all through large-scale approaches such specific alternative antiviral methods classical disinfection protocols. Based on an abundance engineered materials identifiable by their useful physicochemical properties versatile chemical functionalization, nanotechnology offers number to cope with this emergency. Here, multidisciplinary Perspective encompassing diverse fields virology, biology, medicine, engineering, chemistry, science, computational we outline how nanotechnology-based strategies can support fight against COVID-19, infectious diseases in general, including future pandemics. Considering what know so far about life cycle virus, envision key steps where could counter disease. First, nanoparticles (NPs) offer protocols used healthcare settings, thanks intrinsic antipathogenic and/or ability inactivate viruses, bacteria, fungi, or yeasts either photothermally via photocatalysis-induced reactive oxygen species (ROS) generation. Nanotechnology tools SARS-CoV-2 patients also be explored. In case, nanomaterials deliver drugs pulmonary system inhibit interaction between angiotensin-converting enzyme 2 (ACE2) receptors viral S protein. Moreover, concept "nanoimmunity design" help us design immune modulation, stimulating suppressing response, which would find applications context vaccine development counteracting cytokine storm, respectively. addition disease prevention therapeutic potential, important roles diagnostics, potential simple, fast, cost-effective assays monitor presence related biomarkers. summary, is critical will vital when preparing

Language: Английский

Citations

555

Solar fuels: research and development strategies to accelerate photocatalytic CO2 conversion into hydrocarbon fuels DOI Creative Commons
Eunhee Gong, Shahzad Ali, Chaitanya B. Hiragond

et al.

Energy & Environmental Science, Journal Year: 2021, Volume and Issue: 15(3), P. 880 - 937

Published: Nov. 16, 2021

Photocatalytic CO 2 conversion is vital technology to realize global carbon neutrality and generate future energy supplies. This review proposes fundamentals, challenges, strategies, prospects for photocatalytic research.

Language: Английский

Citations

546

2D/2D Ti3C2 MXene/g-C3N4 nanosheets heterojunction for high efficient CO2 reduction photocatalyst: Dual effects of urea DOI
Chao Yang,

Qiuyan Tan,

Qin Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2020, Volume and Issue: 268, P. 118738 - 118738

Published: Feb. 7, 2020

Language: Английский

Citations

534

Rational Design of Two-Dimensional Transition Metal Carbide/Nitride (MXene) Hybrids and Nanocomposites for Catalytic Energy Storage and Conversion DOI
Kang Rui Garrick Lim, Albertus D. Handoko, Srinivasa Kartik Nemani

et al.

ACS Nano, Journal Year: 2020, Volume and Issue: 14(9), P. 10834 - 10864

Published: Aug. 12, 2020

Electro-, photo-, and photoelectrocatalysis play a critical role toward the realization of sustainable energy economy. They facilitate numerous redox reactions in storage conversion systems, enabling production chemical feedstock clean fuels from abundant resources like water, carbon dioxide, nitrogen. One major obstacle for their large-scale implementation is scarcity cost-effective, durable, efficient catalysts. A family two-dimensional transition metal carbides, nitrides, carbonitrides (MXenes) has recently emerged as promising earth-abundant candidates large-area catalytic due to unique properties hydrophilicity, high metallic conductivity, ease by solution processing. To take full advantage these desirable properties, MXenes have been combined with other materials form MXene hybrids significantly enhanced performances beyond sum individual components. hybridization tunes electronic structure optimal binding active species improve intrinsic activity while increasing density accessibility sites. This review outlines recent strategies design industrially relevant electrocatalytic, photocatalytic, photoelectrocatalytic applications such water splitting, metal-air/sulfur batteries, dioxide reduction, nitrogen reduction. By clarifying roles material components hybrids, we provide synergistically couple associated highly durable applications. We conclude highlighting key gaps current understanding guide future hybrid designs

Language: Английский

Citations

456