Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(24), P. 14508 - 14516
Published: Jan. 1, 2024
The
introduction
of
CoP
could
efficiently
facilitate
the
electron
transfer
from
CN
towards
O
2
and
enrich
production
·O
−
,
which
was
indispensable
in
photocatalytic
H
S
oxidation.
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(3), P. 3071 - 3081
Published: Jan. 30, 2024
Advanced
oxidation
processes
(AOPs),
especially
high-efficiency
activation
of
peroxymonosulfate
(PMS),
have
aroused
great
attention
based
on
their
excellent
performance
along
with
low
toxicity
in
the
degradation
organic
pollutants.
Although
covalent
frameworks
(COFs)
been
explored
for
PMS-activated
AOPs,
intrinsic
photocatalytic
properties
are
rarely
studied
this
field.
Herein,
we
designed
and
prepared
a
fully
conjugated
carbon
framework
(TFPT-TCPB
COF),
which
features
sp2
C═C
linkages,
triazine
units,
nitrile
groups,
showing
potential
to
PMS
as
an
photocatalyst.
Olefin-linked
TFPT-TCPB
COF
showed
much
higher
removal
efficiency
(k
=
0.048
min–1),
3.5
times
value
rate
constant
k
TFPT-TAPB
0.014
min–1).
Meanwhile,
photoactive
units
endowed
2.5
enhancement
than
TFPB-TCPB
embedding
only
benzene
rings
0.013
Furthermore,
reaction
COF-COOH
reached
0.081
min–1,
was
69%
that
27
g-C3N4,
proving
positive
effects
introducing
hydrophilic
carboxyl
groups.
Also,
high
chemical
stability,
reusability,
biotoxicity
offered
it
opportunity
marvelous
metal-free
photocatalyst
environment
remediation.
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(33), P. 12653 - 12691
Published: Jan. 1, 2024
Iron
based
nanomaterials/complexes/alloys/MOFs
have
been
discussed
for
CO
2
reduction,
N
fixation,
pollutants
degradation
and
OER/HER
via
type
II,
Z-scheme
S-scheme
heterojunctions.
Materials Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Metal–organic
frameworks
(MOFs)
have
become
a
research
hotspot
for
effective
adsorption
and
degradation
of
chemical
warfare
agents
(CWAs)
toxic
industrial
chemicals
(TICs).