Heterogenization of Porphyrin as Single Molecular Heterogeneous Catalyst for Highly Recyclable and Selective Photocatalytic Oxidation of Sulfides DOI
Liangchun Li,

Guocai Wu,

Hui Duan

et al.

Published: Jan. 1, 2024

Language: Английский

Bimetallic covalent-organic frameworks (BMCOFs): Fundamentals and applications DOI
Maryam Tohidi, Ahmad Amiri, Alireza Badiei

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 530, P. 216465 - 216465

Published: Jan. 31, 2025

Language: Английский

Citations

2
Π‐Bridge Modulations in D–π–A Conjugated Microporous Polymers to Facilitate Charge Separation and Transfer Kinetics for Efficient Photocatalysis DOI
Chunlei Li,

Hetao Xu,

Hao Xiong

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(44)

Published: May 16, 2024

Abstract The burgeoning field of conjugated microporous polymers (CMPs) has generated widespread interest due to their potential as photocatalysts for hydrogen production from water. Nevertheless, photocatalytic performance is sometimes hindered by inadequate charge separation and transfer, coupled with rapid recombination. Herein, a strategy enhance via the customization π ‐bridges through modulation heteroatoms in series donor‐ ‐acceptor (D‐ ‐A) CMPs proposed. This affords optimized energy levels improved thus boosting efficiency. Among various heteroatom substitutions, S‐doped CMP (10 mg) demonstrates highest evolution rate 203 µmol h −1 (AQY 450nm = 7.4%) under visible light irradiation. Subsequent experimental analysis reveals its superior can be largely related minimized exciton binding energy, facilitated transfer efficiency, impeded recombination among these heteroatom‐doped D‐ ‐A CMPs. research paves way rational design modification organic semiconductors advanced solar‐driven photocatalysis promoting transfer.

Language: Английский

Citations

15
Heterogenization of porphyrin as single molecular heterogeneous catalyst for highly recyclable and selective photocatalytic oxidation of sulfides DOI

Guocai Wu,

Hui Duan, Hui Xu

et al.

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 574, P. 114868 - 114868

Published: Feb. 4, 2025

Language: Английский

Citations

1
Two-dimensional porphyrin-based covalent organic frameworks for heterogeneous photocatalysis: Influence of pore size on photocatalytic performance DOI

Houchao Shan,

Ziyi Zhang, Yunfei Jiang

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132102 - 132102

Published: Feb. 1, 2025

Language: Английский

Citations

1
Tailoring β-ketoenamine covalent organic framework with azo for blue light-driven selective oxidation of amines with oxygen DOI

Kanghui Xiong,

Yuexin Wang,

Fengwei Huang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 252 - 262

Published: March 11, 2024

Language: Английский

Citations

8
Unveiling the influence of hydrophobicity on inhibiting hydrogen dissociation for enhanced photocatalytic hydrogen evolution of covalent organic frameworks DOI
Xiaoli Fan, Xin Song, Yangpeng Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 673, P. 836 - 846

Published: June 10, 2024

Language: Английский

Citations

7
Two-Dimensional Porphyrin-Based Covalent Organic Frameworks for Heterogeneous Photocatalysis: Importance of Pore Structure Engineering DOI

Houchao Shan,

Ziyi Zhang, Yunfei Jiang

et al.

Published: Jan. 1, 2025

Covalent organic frameworks (COFs), with well-designed structure and molecular functionality materials, showed great promising as metal-free catalysts for heterogeneous photocatalysis. Nevertheless, the influence of pore COFs on photocatalytic performances is always neglected in ever reports. Herein, by rational designation topology diagrams, two-dimensional porphyrin-based (ETBA-por COF ETBC-por COF) different sizes were synthesized first time. Both as-synthesized exhibited outstanding crystallinity, rich micropores high surface area. Moreover, also have similar photoelectrochemical efficaciously production superoxide radical anions under visible irradiation. To test effect performances, two typical characteristic reactions organics transformation, including selective aerobic oxidation sulfides oxidative amine coupling evaluated. Interestingly, although both good recyclability stability, ETBA-por smaller size has higher conversion (94 %) sulfoxides selectivity (>99 %), while things reversed imines (99 % substrate 96 yield that larger size). Mechanisms activity revealed combing experiments simulation, which infers suitable molecules accesses critical to ensure photocatalysis performances. This study confirmed importance efficient transformation organics.

Language: Английский

Citations

0
Porphyrin-based Covalent Organic Polymers with Bimetallic Active Sites for Boosting Photocatalytic CO2 Cycloaddition DOI

Shengrong Yan,

Lan Zhang,

Songhu Shi

et al.

Chemical Research in Chinese Universities, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Language: Английский

Citations

0
Donor-acceptor mixed-ligand MOF with energy transfer-mediated high-efficiency singlet oxygen generation for boosted organic photosynthesis DOI
Hong‐Guang Jin, Wei Lin, Pengcheng Zhao

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137231 - 137231

Published: March 6, 2025

Language: Английский

Citations

0
Visible-light-induced C2-selective trifluoromethylation of indoles catalyzed by copper-containing covalent organic frameworks DOI
Zhicheng Chen,

Mengqi Zou,

Xianghui Zhu

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116077 - 116077

Published: March 1, 2025

Language: Английский

Citations

0