Precision-Engineered Construction of Proton-Conducting Metal–Organic Frameworks

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 17(1)

Published: Dec. 11, 2024

Proton-conducting materials have attracted considerable interest because of their extensive application in energy storage and conversion devices. Among them, metal-organic frameworks (MOFs) present tremendous development potential possibilities for constructing novel advanced proton conductors due to special advantages crystallinity, designability, porosity. In particular, several design strategies the structure MOFs opened new doors advancement MOF conductors, such as charged network construction, ligand functionalization, metal-center manipulation, defective engineering, guest molecule incorporation, pore-space manipulation. With implementation these strategies, proton-conducting developed significantly profoundly within last decade. Therefore, this review, we critically discuss analyze fundamental principles, methods targeted at improving conductivity through representative examples. Besides, structural features, conduction mechanism behavior are discussed thoroughly meticulously. Future endeavors also proposed address challenges practical research. We sincerely expect that review will bring guidance inspiration further motivate research enthusiasm materials.

Language: Английский

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Metal‐Organic Frameworks (MOFs): Classification, Synthesis, Modification, and Biomedical Applications

Small, Journal Year: 2024, Volume and Issue: 20(47)

Published: Aug. 16, 2024

Abstract Metal‐organic frameworks (MOFs) are a new variety of solid crystalline porous functional materials. As an extension inorganic materials, it has made important progress in preparation and application. MOFs widely used various fields such as gas adsorption storage, drug delivery, sensing, biological imaging due to their high specific surface area, porosity, adjustable pore size, abundant active sites, modification by introducing groups. In this paper, the types classified, synthesis methods mechanisms materials summarized. Finally, application prospects challenges metal‐organic framework biomedical field discussed, hoping promote multidisciplinary fields.

Language: Английский

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Enhancing phosphate and As(V) adsorption through interfacial electron distribution and chemical reactivity modulation in Nd-doped MOFs

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 351, P. 128034 - 128034

Published: May 21, 2024

Language: Английский

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Synergistic effects in simultaneous photocatalytic removal of Cr(VI) and As(III) by bimetallic NH2-MOF(InxFe1x)

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162659 - 162659

Published: Feb. 1, 2025

Language: Английский

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Nano-photosensitizers with gallic acid-involved Fe–O–Cu “electronic storage station” bridging ligand-to-metal charge transfer for efficient catalytic theranostics

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 676, P. 974 - 988

Published: July 24, 2024

Language: Английский

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Dipole moment modulation of perylene diimide to promote degradation and antibacterial properties

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162373 - 162373

Published: April 1, 2025

Language: Английский

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Detection and degradation of phenolic compounds based on metal-organic complexes

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 538, P. 216721 - 216721

Published: April 23, 2025

Language: Английский

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A highly-efficient peroxymonosulfate activator using a sewage sludge derived biochar supported cobalt oxide: mechanism and characteristics

Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 192, P. 1319 - 1329

Published: Nov. 4, 2024

Language: Английский

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A Portable Electrochemical Biosensor Based on an Amino-Modified Ionic Metal–Organic Framework for the One-Site Detection of Multiple Organophosphorus Pesticides

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 3, 2024

Constructing stable, portable sensors and revealing their mechanisms is challenging. Ion metal-organic frameworks (IMOFs) are poised to serve as highly effective electrochemical for detecting organophosphorus pesticides (OPs), leveraging unique charge properties. In this work, an amino-modified IMOF was constructed combined with near-field communication (NFC) technology develop a portable, touchless, battery-free biosensor

Language: Английский

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pH-Responsive MOF Nanoparticles Equipped with Hydrophilic “Armor” Assist Fungicides in Controlling Peanut Southern Blight

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(44), P. 59962 - 59978

Published: Oct. 25, 2024

The development of novel, safe, and efficient pest disease control technologies for agricultural crops remains a pivotal area research. In this study, by combining ZIF-8 ZIF-90, water-stable, pH-responsive bilayer MOF nanoparticle (NP) named Z8@Z90 was created, tebuconazole (TEB) added to form T@Z8@Z90, used controlling peanut southern blight. loading efficiency TEB within the T@Z8@Z90 reached 26.15%, enabling rapid release in acidic environments triggered oxalic acid (OA) secreted Sclerotium rolfsii. vitro experiments showed that can regulate secretion S. rolfsii destroy its cell membrane structure. Additional revealed reduced sclerotial formation, decreased total protein content sclerotia, influenced their sensitivity pesticides, thereby mitigating risk reinfection Notably, exhibited translocation seedlings, being absorbed through roots transported leaves. At concentration 200 mg/L, high safety profiles seedling growth compared suspension. Moreover, is safer earthworms than SC. Overall, study offers valuable insights management soil-borne diseases agriculture contributes advancement sustainable practices.

Language: Английский

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