RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(3), P. 2205 - 2216
Published: Jan. 1, 2025
This
study
investigates
Bi-MOFs
and
their
derivatives
(Ag
+
/Bi-MOF,
NH
4
/Ag
/Bi-MOF)
for
photocatalytic
degradation
of
tetracycline
sulfamethoxazole
under
visible
light,
demonstrating
efficiency
potential
environmental
applications.
Heliyon,
Journal Year:
2024,
Volume and Issue:
10(13), P. e32861 - e32861
Published: June 13, 2024
Increasing
water
pollution
and
decreasing
energy
reserves
have
emerged
as
growing
concerns
for
the
environment.
These
pollutions
are
due
to
dangerous
effects
of
numerous
pollutants
on
humans
aquatic
organisms,
such
hydrocarbons,
biphenyls,
pesticides,
dyes,
pharmaceuticals,
metal
ions.
On
other
hand,
need
a
clean
environment,
finding
alternatives
fossil
renewable
fuels
is
very
important.
Hydrogen
(H2)
regarded
viable
promising
substitute
fuels,
range
methodologies
been
devised
generate
this
particular
source
energy.
Metal-organic
frameworks
(MOFs)
new
generation
nanoporous
coordination
polymers
whose
crystal
structure
composed
juxtaposition
organic
inorganic
constituent
units.
Due
their
flexible
nature,
regular
structure,
high
surface
area,
these
materials
attracted
much
attention
removing
various
from
wastewater,
splitting.
MOFs
Z-scheme
heterojunctions
identified
an
economical
eco-friendly
method
eliminating
wastewater
systems,
produce
H2.
Their
low-cost
synthesis
unique
properties
increase
application
in
environment
fields.
The
possess
diverse
properties,
exceptional
making
them
ideal
degradation
separation.
development
formulation
photocatalytic
system
using
MOFs,
which
stable
potent
redox
capability,
has
successful
approach
addressing
environmental
shortages
recent
times.
Through
utilization
benefits
offered
by
photocatalysts,
efficient
separation
migration
charge
carriers,
extensive
spectrum
light
absorption,
among
advantages,
notable
enhancements
can
be
attained.
This
review
encompasses
techniques,
heterojunctions,
use
treating
wastewaters,
including
heavy
metals,
Also,
it
provides
overview
mechanisms,
pathways,
theoretical
practical
aspects
heterojunctions.
Finally,
thoroughly
assesses
existing
challenges
suggests
further
research
applications
industrial-scale
treatment.
Inorganic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(8), P. 2212 - 2245
Published: Jan. 1, 2024
This
review
highlights
the
recent
advances
in
photocatalytic
applications
of
porphyrin-based
MOFs
aqueous
environments
for
solar
fuel
generation
and
water
remediation.
Water,
Journal Year:
2024,
Volume and Issue:
16(8), P. 1128 - 1128
Published: April 16, 2024
Human
exposure
to
p-phenylenediamine
derivatives
(PPDs)
may
induce
hepatotoxicity
and
altered
glycolipid
metabolism.
Recent
studies
have
demonstrated
the
wide
presence
of
PPDs
in
environmental
matrixes.
However,
until
now,
occurrence
tap
water
has
not
been
well
known.
This
study
analyzed
nine
collected
from
Hangzhou
Taizhou,
China.
The
results
showed
that
seven
were
detected
samples
(n
=
131),
with
concentration
total
ranging
0.29
7.9
ng/L
(mean:
1.6
ng/L).
N-(1,
3-dimethylbutyl)-N′-phenyl-p-phenylenediamine
(6PPD;
mean:
0.79
ng/L,
<LOD−5.7
ng/L)
was
predominant
PPD
Hangzhou,
followed
by
N,
N′-di-2-butyl-p-phenylenediamine
(44PD;
0.39
<LOD−2.2
N-isopropyl-N′-phenyl-1,
4-phenylenediamine
(IPPD;
0.31
<LOD−1.4
Five
Taizhou
30).
N-phenyl-N′-cyclohexyl-p-phenylenediamine
(CPPD;
1.0
<LOD−4.2
6PPD
(0.93
<LOD−2.6
44PD
(0.78
<LOD−1.8
mean
daily
intake
(DI)
for
adults
children
estimated
be
4.9–24
6.4–32
pg/kg
bw/day,
respectively.
Meanwhile,
DI
living
11–31
14–40
To
our
knowledge,
this
provides
first
data
on
water,
which
is
vital
human
risk
assessment.
npj Clean Water,
Journal Year:
2024,
Volume and Issue:
7(1)
Published: Feb. 8, 2024
Abstract
The
need
for
antifouling
membranes
is
substantial
due
to
fouling’s
negative
impact
on
the
effectiveness
and
durability
of
ultrafiltration
membranes.
In
recent
times,
Metal-Organic
Frameworks
(MOFs)
have
emerged
as
effective
additives
crafting
(UF)
However,
harness
their
benefits
mitigate
drawbacks,
a
well-considered
approach
imperative.
this
work,
polyethersulfone
(PES)
UF
were
tailored
with
polydopamine
(PDA)-modified
cerium
(Ce)-MOF
(PDA@Ce-MOF)
achieve
satisfactory
properties
remove
biological
macromolecules
such
bovine
serum
albumin
(BSA)
humic
acid
(HA)
from
wastewater.
non-solvent
induced
phase
separation
(NIPS)
method
was
used
simultaneously
fabricate
membrane
modify
it
different
PDA@Ce-MOF
concentrations
ranging
0.05
0.50
wt.%.
Results
showed
significant
improvements
membrane’s
morphology,
hydrophilicity,
porosity
pore
size
at
0.10
wt.%
loading
PDA@Ce-MOF.
synergistic
effect
PDA
Ce-MOF
improved
pure
water
flux
(337
L
m
−2
h
−1
)
filtration
performance
in
Bovine
reporting
145
98%
rejection,
164
88%
rejection;
respectively.
Further,
water-attracting
functional
moieties
hindered
deposition
BSA
protein
surface,
resulting
an
excellent
recovery
ratio
(FRR)
~87%,
alongside
mitigated
irreversible
fouling.