Sulfate radicals-based advanced oxidation processes for the degradation of pharmaceuticals and personal care products: A review on relevant activation mechanisms, performance, and perspectives

Environmental Research, Journal Year: 2022, Volume and Issue: 217, P. 114789 - 114789

Published: Nov. 11, 2022

Language: Английский

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Remediation of environmentally persistent organic pollutants (POPs) by persulfates oxidation system (PS): A review

The Science of The Total Environment, Journal Year: 2022, Volume and Issue: 863, P. 160818 - 160818

Published: Dec. 8, 2022

Language: Английский

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Construction of a novel S-scheme heterojunction piezoelectric photocatalyst V-BiOIO3/FTCN and immobilization with floatability for tetracycline degradation

Journal of Hazardous Materials, Journal Year: 2022, Volume and Issue: 443, P. 130251 - 130251

Published: Oct. 26, 2022

Language: Английский

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The application of transition metal-modified biochar in sulfate radical based advanced oxidation processes

Environmental Research, Journal Year: 2022, Volume and Issue: 212, P. 113340 - 113340

Published: April 19, 2022

Language: Английский

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Were Persulfate-Based Advanced Oxidation Processes Really Understood? Basic Concepts, Cognitive Biases, and Experimental Details

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(24), P. 10415 - 10444

Published: June 7, 2024

Persulfate (PS)-based advanced oxidation processes (AOPs) for pollutant removal have attracted extensive interest, but some controversies about the identification of reactive species were usually observed. This critical review aims to comprehensively introduce basic concepts and rectify cognitive biases appeals pay more attention experimental details in PS-AOPs, so as accurately explore reaction mechanisms. The scientifically summarizes character, generation, different species. It then highlights complexities analysis electron paramagnetic resonance, uncertainties use probes scavengers, necessities determination scavenger concentration. importance choice buffer solution, operating mode, terminator, filter membrane is also emphasized. Finally, we discuss current challenges future perspectives alleviate misinterpretations toward mechanisms PS-AOPs.

Language: Английский

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Covalent–Organic Framework (COF)‐Core–Shell Composites: Classification, Synthesis, Properties, and Applications

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(45)

Published: Aug. 27, 2023

Abstract Core–shell structures, where the “guest” material is encapsulated within a protective shell, integrate advantages of different materials to enhance overall properties composite. Covalent–organic frameworks (COFs) are favorable candidates for composing core–shell structures due their inherent porosity, good activity, excellent stability, and other advantages. In particular, COFs as shells encapsulate functional becoming increasingly popular in fields environmental remediation energy conversion. However, there lack reviews on COF‐based materials. this context, review provides systematic summary current research composites. First, simple classification made The second part describes main synthesis methods. changes brought about by COF shell composites applications photocatalysis, electrocatalysis, adsorption, sensing, supercapacitors then emphasized. Finally, new perspectives future development challenges presented. purpose study provide insights into design application

Language: Английский

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Porphyrin‐Based Metal‐Organic Framework Photocatalysts: Structure, Mechanism and Applications

Small Methods, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 5, 2025

In recent years, porphyrins have been frequently reported as photocatalysts due to their fascinating photochemical properties. However, the same shortcomings other homogeneous photocatalysts, such poor stability and difficulty in recovering. To solve this problem, it is a good strategy form porphyrin-based metal-organic framework (PMOF) by modifying porphyrin functional groups adding metals nodes connect control arrangement of porphyrins. The metal rigidity connectivity modules order them MOF, which improves porphyrins, avoids aggregation folding, increases active sites for photocatalytic reactions. This review summarized research progress PMOF last ten years analyzed effects spatial structure, ligands, central metals, on performance. applications PMOF-based H

Language: Английский

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Carbonaceous materials in structural dimensions for advanced oxidation processes

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Catalytic active sites and mechanisms of various dimensional carbonaceous materials in activation oxidants towards advanced oxidant processes for wastewater/water treatment were reviewed.

Language: Английский

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Catalytic oxidation of acetaminophen through pristine and surface-modified nitrogen-doped carbon-nanotube-catalyzed peroxydisulfate activation

Journal of environmental chemical engineering, Journal Year: 2022, Volume and Issue: 10(5), P. 108257 - 108257

Published: July 14, 2022

Language: Английский

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Electron-transfer-based peroxymonosulfate activation on defect-rich carbon nanotubes: Understanding the substituent effect on the selective oxidation of phenols

Journal of Hazardous Materials, Journal Year: 2022, Volume and Issue: 442, P. 130108 - 130108

Published: Oct. 7, 2022

Language: Английский

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