
Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: unknown, P. 106764 - 106764
Published: Sept. 1, 2024
Language: Английский
Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: unknown, P. 106764 - 106764
Published: Sept. 1, 2024
Language: Английский
Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: unknown, P. 136730 - 136730
Published: Oct. 1, 2024
Language: Английский
Citations
2Environmental Pollution, Journal Year: 2023, Volume and Issue: 343, P. 123173 - 123173
Published: Dec. 16, 2023
Language: Английский
Citations
4ACS ES&T Engineering, Journal Year: 2024, Volume and Issue: 4(9), P. 2274 - 2283
Published: July 24, 2024
Low-temperature thermal degradation of PCDD/Fs in incineration fly ash (IFA) has attracted widespread attention with the advantages low energy consumption and high efficiency. However, process industrialization, inevitable O2 leakage system always been a technical bottleneck. Based on characteristics IFA mechanism PCDD/F regeneration, this study first proposes dual-strategy LTTD predechlorination reduction atmosphere-keeping. Predechlorination removes soluble chlorine metals while hydrolyzing CaClOH into Ca(OH)2 to accelerate detoxication PCDD/Fs, deep atmosphere-keeping is created by introducing activated carbon inhibit possible regeneration. Compared typical LTTD, synergistic application can obtain 99.4 97.4% detoxification efficiencies presence 1 2% O2, respectively. identification congener distribution density functional theory calculations, dechlorination acid chloride group-containing intermediates participation CO was proposed. Finally, reproducibility after optimization working parameters well verified proposed dual strategies are expected provide new direction for industrialization LTTD.
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155534 - 155534
Published: Sept. 6, 2024
Language: Английский
Citations
1Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: unknown, P. 106764 - 106764
Published: Sept. 1, 2024
Language: Английский
Citations
1